PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 06/11/2014 Revision date: 06/11/2014 Version: 1.0 06/11/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY ENGINE CLEANER & DEGREASER Product code : 4220 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Engine degreaser. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Aerosol 1 Gases Under Pressure - Liquefied gas Acute toxicity 4 (Inhalation) Skin irritation 2 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS04 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if inhaled. Causes skin irritation. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas/mist/vapors/spray. Use only outdoors or in a well- ventilated area. Wash hands thoroughly after handling. Wear protective gloves. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 10 percent of the mixture consists of ingredient(s) of unknown acute toxicity SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 2/7 3.2. Mixture Name Product identifier % GHS-US classification Distillates, petroleum, solvent-refined heavy paraffinic (CAS No) 64741-88-4 30 - 60 Asp. Tox. 1 Distillates, petroleum, hydrotreated light naphthenic (CAS No) 64742-53-6 15 - 40 Acute Tox. 4 (Inhalation) Asp. Tox. 1 Propane (CAS No) 74-98-6 7 - 13 Flam. Gas 1 Liquefied gas Kerosene, petroleum (CAS No) 8008-20-6 7 - 13 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 Asp. Tox. 1 Butane (CAS No) 106-97-8 7 - 13 Flam. Gas 1 Liquefied gas 2-Butoxyethanol (CAS No) 111-76-2 1 - 5 Flam. Liq. 3 Acute Tox. 4 (Oral, Dermal, Inhalation) Skin Irrit. 2 Eye Irrit. 2A Nonylphenol ethoxylates (CAS No) 9016-45-9 1 - 5 Acute Tox. 4 (Oral) Skin Irrit. 2 Eye Irrit. 2A Naphthalene (CAS No) 91-20-3 < 0.1 Acute Tox. 4 (Oral) Carc. 2 Ethylene oxide (CAS No) 75-21-8 < 0.1 Flam. Gas 1 Liquefied gas Acute Tox. 3 (Inhalation) Skin Irrit. 2 Eye Irrit. 2A Muta. 1B Carc. 1B STOT SE 3 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Harmful if inhaled. Vapours may cause drowsiness and dizziness. May cause respiratory tract irritation.Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 3/7 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid contact with skin and eyes. Do not swallow. Avoid breathing gas/mist/vapors/spray. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep locked up and out of reach of children. Do not expose ot temperatures exceeding 50?C/ 122?F. Store away from direct sunlight or other heat sources. Store in a well-ventilated place. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) USA ACGIH ACGIH TWA (ppm) 5 mg/m? (mist) USA OSHA OSHA PEL (TWA) (ppm) 5 mg/m? (mist) Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) USA ACGIH ACGIH TWA (ppm) 5 mg/m? (mist) USA OSHA OSHA PEL (TWA) (ppm) 5 mg/m? (mist) Propane (74-98-6) USA ACGIH ACGIH TWA (ppm) 1000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 1800 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Kerosene, petroleum (8008-20-6) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? Butane (106-97-8) USA ACGIH ACGIH STEL (ppm) 1000 ppm 2-Butoxyethanol (111-76-2) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 240 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 4/7 Nonylphenol ethoxylates (9016-45-9) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 50 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Ethylene oxide (75-21-8) USA ACGIH ACGIH TWA (ppm) 1 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid. Appearance : Clear. Colour : Colourless. Odour : Solvent. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.863 - 0.871 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 5/7 Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Extremely flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. Direct sunlight. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if inhaled. 4220 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) >1.0 but ?5.0 mg/l/4h Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Propane (74-98-6) LC50 inhalation rat (mg/l) 658 mg/l/4h Kerosene, petroleum (8008-20-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5.28 mg/l/4h Butane (106-97-8) LC50 inhalation rat (mg/l) 658 mg/l/4h 2-Butoxyethanol (111-76-2) LD50 oral rat 470 mg/kg LC50 inhalation rat (ppm) 450 ppm/4h Nonylphenol ethoxylates (9016-45-9) LD50 oral rat 1310 mg/kg LD50 dermal rabbit 2 mL/kg Naphthalene (91-20-3) LD50 oral rat 490 mg/kg PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 6/7 Naphthalene (91-20-3) LD50 dermal rat > 2500 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat (mg/l) > 340 mg/m?/1h Ethylene oxide (75-21-8) LD50 oral rat 72 mg/kg LC50 inhalation rat (ppm) 800 ppm/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. 2-Butoxyethanol (111-76-2) IARC group 3 - Not classifiable National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Ethylene oxide (75-21-8) IARC group 1 - Carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 2 - Known Human Carcinogens In OSHA Specifically Regulated Carcinogen list Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : Harmful if inhaled. Vapours may cause drowsiness and dizziness. May cause respiratory tract irritation.Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 4220 Persistence and degradability Not established. 12.3. Bioaccumulative potential 4220 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. PENRAY ENGINE CLEANER & DEGREASER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 7/7 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapours may accumulate in the container. Do not incinerate closed containers. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : UN1950 14.2. UN proper shipping name Proper Shipping Name : Aerosols flammable Department of Transportation Hazard Classes : 2.1 Hazard labels : 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Naphthalene (91-20-3) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % Ethylene oxide (75-21-8) Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 302 Threshold Planning Quantity (TPQ) 1000 SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations 4220 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 06/11/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 4 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product