PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 Date of issue: 12/05/2014 Revision date: 12/05/2014 Version: 1.0 12/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY RUBBERIZED UNDERCOAT Product code : 4424 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Rubberized undercoat. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Aerosol 1 Gases Under Pressure - Liquefied gas Skin irritation 2 Eye irritation 2A Skin sensitization 1 Carcinogenicity 1A Reproductive toxicity 2 (developmental) Specific target organ toxicity - Single exposure 3 Specific target organ toxicity - Repeated exposure 2 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS04 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause cancer. Suspected of damaging the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/ vapors/spray. If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 2/8 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 8 percent of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Acetone (CAS No) 67-64-1 40 - 70 Flam. Liq. 2 Eye Irrit. 2A STOT SE 3 Propane (CAS No) 74-98-6 10 - 30 Flam. Gas 1 Liquefied gas Butane (CAS No) 106-97-8 7 - 13 Flam. Gas 1 Liquefied gas Solvent 1 Proprietary 1 - 5 Asp. Tox. 1 Filler 1 Proprietary 1 - 5 Not classified Solvent 2 Proprietary 1 - 5 Flam. Liq. 2 Skin Irrit. 2 Repr. 2 (developmental) STOT SE 3 STOT RE 2 Asp. Tox. 1 Filler 2 Proprietary 1 - 5 Carc. 2 (long fibres >5?m) Not classified (short fibres <5?m) Thickener Proprietary 1 - 5 Not classified Rust Inhibitor Proprietary 0.1 - 1 Acute Tox. 4 (Oral) Skin Corr. 1C Skin Sens. 1 Filler 3 Proprietary 0.1 - 1 Acute Tox. 4 (Oral) Carc. 1A STOT RE 1 Colorant Proprietary 0.1 - 1 Carc. 2 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. May cause drowsiness, dizziness and central nervous system depression. Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 3/8 Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon, oxides of sulphur, hydrocarbons. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid contact with skin and eyes. Do not swallow. Do not breathe gas, fumes, vapor or spray. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep locked up and out of reach of children. Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Store away from direct sunlight or other heat sources. Store in a well-ventilated place. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Acetone (67-64-1) USA ACGIH ACGIH TWA (ppm) 500 ppm USA ACGIH ACGIH STEL (ppm) 750 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 2400 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Propane (74-98-6) USA ACGIH ACGIH TWA (ppm) 1000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 1800 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Butane (106-97-8) USA ACGIH ACGIH STEL (ppm) 1000 ppm Solvent 1 (Proprietary) ACGIH Not applicable OSHA Not applicable PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 4/8 Filler 1 (Proprietary) USA ACGIH ACGIH TWA (mg/m?) 10 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 15 mg/m? (total) 5 mg/m? (resp) Solvent 2 (Proprietary) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Filler 2 (Proprietary) USA ACGIH ACGIH TWA (mg/m?) 10 mg/m? (total) 3 mg/m? (resp) USA OSHA OSHA PEL (TWA) (mg/m?) 15 mg/m? (total) 5 mg/m? (resp) Thickener (Proprietary) USA ACGIH ACGIH TWA (mg/m?) 2 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 15 mg/m3 (total dust) 5 mg/m3 (respirable fraction) Rust Inhibitor (Proprietary) ACGIH Not applicable OSHA Not applicable Filler 3 (Proprietary) USA ACGIH ACGIH TWA (mg/m?) 0.025 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) ((10 mg/m3)/(%SiO2+2) TWA (resp)) ((30 mg/m3)/(%SiO2+2) TWA (total)) ((250)/(%SiO2+5) mppcf TWA (resp)) Colorant (Proprietary) USA ACGIH ACGIH TWA (mg/m?) 3 mg/m3 USA OSHA OSHA PEL (TWA) (mg/m?) 3.5 mg/m3 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Wear eye protection. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid Appearance : Opaque Color : Black Odor : Solvent PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 5/8 Odor threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : Flammable Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Extremely flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. 10.5. Incompatible materials Acids. Amines. Bases. Oxidizers. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, oxides of sulphur, hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified. 4424 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5 mg/l/4h Acetone (67-64-1) LD50 oral rat 5800 mg/kg LC50 inhalation rat 50100 mg/m?/8h Propane (74-98-6) LC50 inhalation rat 658 mg/l/4h PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 6/8 Butane (106-97-8) LC50 inhalation rat 658 mg/l/4h Filler 1 (Proprietary) LD50 oral rat 6450 mg/kg Solvent 2 (Proprietary) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit 8390 mg/kg LD50 dermal rat 12124 mg/kg LC50 inhalation rat 28.1 mg/l/4h Filler 3 (Proprietary) LD50 oral rat 500 mg/kg Colorant (Proprietary) LD50 oral rat > 15400 mg/kg LD50 dermal rabbit > 3 g/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : May cause cancer. Solvent 2 (Proprietary) IARC group 3 - Not classifiable Filler 2 (Proprietary) IARC group 2B - Possibly carcinogenic to humans (long fibres >5?m); 3 - Not classifiable (short fibres <5?m) Filler 3 (Proprietary) IARC group 1 - Carcinogenic to humans National Toxicology Program (NTP) Status 2 - Known Human Carcinogens Colorant (Proprietary) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Suspected of damaging the unborn child. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause respiratory tract irritation. May cause drowsiness, dizziness and central nervous system depression. Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 4424 Persistence and degradability Not established. 12.3. Bioaccumulative potential 4424 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 7/8 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapors may accumulate in the container. Do not incinerate closed containers. SECTION 14: Transport information In accordance with DOT UN-No.(DOT) : UN1950 Proper Shipping Name (DOT) : Aerosols flammable Department of Transportation (DOT) Hazard Classes : 2.1 Hazard labels (DOT) : Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Filler 2 Proprietary Acetone (67-64-1) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. Solvent 2 (Proprietary) Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 1.0 % 15.2. US State regulations 4424 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. PENRAY RUBBERIZED UNDERCOAT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/05/2014 EN (English) 8/8 SECTION 16: Other information Indication of changes : None. Date of issue : 11/24/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 4 NFPA reactivity : 0 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.