PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 06/11/2014 Revision date: 06/11/2014 Version: 1.0 06/11/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY WINDSHIELD SPRAY DE-ICER Product code : 5216 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Spray de-icer. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Aerosol 1 Gases Under Pressure Compressed Gas Acute toxicity 3 (Oral) Acute toxicity 3 (Dermal) Acute toxicity 3 (Inhalation) Eye irritation 2A Specific target organ toxicity - Single exposure 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS04 GHS06 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Toxic if swallowed, in contact with skin or if inhaled. Causes serious eye irritation. Causes damage to eyes. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wear protective gloves/protective clothing/eye protection/face protection. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well- ventilated area. Do not breathe gas/mist/vapors/spray. If exposed: Call a poison center/doctor. If swallowed: Immediately call a poison center/doctor. Rinse mouth. If on skin: Wash with plenty of water. Take off immediately all contaminated clothing and wash it before reuse. Call a poison center/doctor if you feel unwell. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Do not expose to temperatures exceeding 50 ?C/122 ?F. Protect from sunlight. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 6 percent of the mixture consists of ingredient(s) of unknown acute toxicity PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 2/7 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Methanol (CAS No) 67-56-1 60 - 100 Flam. Liq. 2 Acute Tox. 3 (Oral, Dermal, Inhalation) Eye Irrit. 2B STOT SE 1 Carbon dioxide (CAS No) 124-38-9 5 - 10 Compressed gas 2-Butoxyethanol (CAS No) 111-76-2 1 - 5 Flam. Liq. 3 Acute Tox. 4 (Oral, Dermal, Inhalation) Skin Irrit. 2 Eye Irrit. 2A Morpholine (CAS No) 110-91-8 0.1 - 1 Flam. Liq. 3 Acute Tox. 3 (Dermal) Acute Tox. 4 (Oral, Inhalation) Skin Corr. 1B 2-Methoxyethanol (CAS No) 109-86-4 < 0.1 Flam. Liq. 3 Acute Tox. 4 (Oral, Dermal, Inhalation) Repr. 1B * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical advice/attention. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical advice/attention if you feel unwell. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Rinse mouth. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Toxic if inhaled. May cause respiratory tract irritation. Vapors may cause narcosis with headache, difficulty breathing, lightheadedness, drowsiness, unconsciousness and possibly death. Symptoms/injuries after skin contact : Toxic in contact with skin. May cause skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Other symptoms are similar to those experienced through inhalation and ingestion. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : Toxic if swallowed. May be fatal or cause blindness if swallowed. May cause stomach distress, nausea or vomiting. Ingestion may cause headache, dizziness, drowsiness, metabolic acidosis, coma, seizures. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon, formaldehyde. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Firefighting instructions : Burns with a colourless invisible flame. In case of fire and/or explosion do not breathe fumes. PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 3/7 Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not get in eyes, on skin, or on clothing. Do not breathe gas, fumes, vapour or spray. Do not swallow. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof equipment. Storage conditions : Keep locked up and out of reach of children. Do not expose ot temperatures exceeding 50?C/ 122?F. Store away from direct sunlight or other heat sources. Store in a well-ventilated place. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Methanol (67-56-1) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 260 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm Carbon dioxide (124-38-9) USA ACGIH ACGIH TWA (ppm) 5000 ppm USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm 2-Butoxyethanol (111-76-2) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 240 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm Morpholine (110-91-8) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 70 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 20 ppm PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 4/7 2-Methoxyethanol (109-86-4) USA ACGIH ACGIH TWA (ppm) 0.1 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 80 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 25 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Hand protection : Neoprene or nitrile rubber gloves. Eye protection : Wear approved eye (properly fitted dust- or splash-proof chemical safety goggles) / face (face shield) protection. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid. Appearance : Clear. Colour : Colourless. Odour : Solvent. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.8255 - 0.8308 Solubility : Soluble. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Extremely flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 5/7 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. 10.5. Incompatible materials Acids. Bases. Metals. Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, formaldehyde. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Toxic if swallowed, in contact with skin or if inhaled. 5216 LD50 oral rat >50 but ?300 mg/kg (Calculated using ATE values) LD50 dermal rabbit >200 but ?1000 mg/kg (Calculated using ATE values) LC50 inhalation rat (mg/l) >2.0 but ?10.0 mg/l/4h (Calculated using ATE values) Methanol (67-56-1) LD50 oral rat 5628 mg/kg LD50 dermal rabbit 15800 mg/kg LC50 inhalation rat (mg/l) 83.2 mg/l/4h 2-Butoxyethanol (111-76-2) LD50 oral rat 470 mg/kg LC50 inhalation rat (ppm) 450 ppm/4h Morpholine (110-91-8) LD50 oral rat 1050 mg/kg LD50 dermal rabbit 310 mg/kg LC50 inhalation rat (ppm) 8000 ppm/8h 2-Methoxyethanol (109-86-4) LD50 oral rat 2370 mg/kg LD50 dermal rabbit 2000 mg/kg LD50 dermal rabbit 1280 mg/kg Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. 2-Butoxyethanol (111-76-2) IARC group 3 - Not classifiable National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity Morpholine (110-91-8) IARC group 3 - Not classifiable Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Causes damage to eyes. Inhalation, ingestion or skin absorption of methanol can cause significant disturbances in vision, including blindness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Toxic if inhaled. May cause respiratory tract irritation. Vapors may cause narcosis with headache, difficulty breathing, lightheadedness, drowsiness, unconsciousness and possibly death. Symptoms/injuries after skin contact : Toxic in contact with skin. May cause skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Other symptoms are similar to those experienced through inhalation and ingestion. PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 6/7 Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : Toxic if swallowed. May be fatal or cause blindness if swallowed. May cause stomach distress, nausea or vomiting. Ingestion may cause headache, dizziness, drowsiness, metabolic acidosis, coma, seizures. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 5216 Persistence and degradability Product is biodegradable. 12.3. Bioaccumulative potential 5216 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapours may accumulate in the container. Do not incinerate closed containers. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : UN1950 14.2. UN proper shipping name Proper Shipping Name : Aerosols flammable, containing substances in Class 6.1, packing group II Department of Transportation Hazard Classes : 2.1 (6.1) Hazard labels : 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Methanol (67-56-1) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % 2-Methoxyethanol (109-86-4) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag S - S - indicates a substance that is identified in a proposed or final Significant New Uses Rule. PENRAY WINDSHIELD SPRAY DE-ICER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 7/7 2-Methoxyethanol (109-86-4) SARA Section 313 - Emission Reporting 1.0 % 15.2. US State regulations 5216 State or local regulations This product contains chemicals known to the State of California to cause birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 06/11/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 4 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product