TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 05/05/2015 05/05/2015 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : TR84718 - Liquid Product code : T84718 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Supplemental Coolant Additive 1.3. Details of the supplier of the safety data sheet Dober Chemical Corp 11230 Katherine's Crossing Suite 100 Woodridge, IL 60517 - US T 630-410-7300 - F 630-410-7444 This email address is being protected from spambots. You need JavaScript enabled to view it. - www.dobergroup.com 1.4. Emergency telephone number Emergency number : 1-800-255-3924 / 1-813-248-0585 ChemTel SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Repr. 1B H360 Aquatic Acute 2 H401 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H360 - May damage fertility or the unborn child H401 - Toxic to aquatic life Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 2/8 Name Product identifier % GHS-US classification Sodium Nitrite (CAS No) 7632-00-0 1 - 5 Ox. Sol. 3, H272 Acute Tox. 3 (Oral), H301 Aquatic Acute 1, H400 Sodium Mercaptobenzothiazole (CAS No) 2492-26-4 1 - 5 Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Disodium Tetraborate, Anhydrous (CAS No) 1330-43-4 < 1 Repr. 1B, H360 Aquatic Acute 3, H402 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. May damage fertility or the unborn child. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapours. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 3/8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Hygiene measures : Wash hands, forearms and face thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well-ventilated place. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters TR84718 - Liquid ACGIH Not applicable OSHA Not applicable Disodium Tetraborate, Anhydrous (1330-43-4) ACGIH ACGIH TWA (mg/m?) 2 mg/m? ACGIH ACGIH STEL (mg/m?) 6 mg/m? OSHA Not applicable Sodium Mercaptobenzothiazole (2492-26-4) ACGIH Not applicable OSHA Not applicable Sodium Nitrite (7632-00-0) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves/protective clothing/eye protection/face protection protective gloves. Eye protection : Chemical goggles or face shield. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : red Odour : mild Odour threshold : No data available pH : 10.8 - 11.8 Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : 0 ?C TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 4/8 Boiling point : No data available Flash point : Not Applicable. Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 2.4 kPa Relative vapour density at 20 ?C : ? 1 Relative density : No data available Density : 1.042 - 1.064 g/ml Solubility : Water: 100 % Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : Not Available. Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapours. 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Disodium Tetraborate, Anhydrous (1330-43-4) LD50 oral rat 2660 mg/kg LD50 dermal rabbit > 2000 mg/kg ATE US (oral) 2660.000 mg/kg bodyweight Sodium Mercaptobenzothiazole (2492-26-4) LD50 oral rat 750 mg/kg LD50 dermal rabbit > 1250 mg/kg ATE US (oral) 750.000 mg/kg bodyweight Sodium Nitrite (7632-00-0) LD50 oral rat 85 mg/kg LC50 inhalation rat (mg/l) 5.5 mg/l/4h ATE US (oral) 85.000 mg/kg bodyweight ATE US (vapours) 5.500 mg/l/4h ATE US (dust,mist) 5.500 mg/l/4h TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 5/8 Skin corrosion/irritation : Not classified pH: 10.8 - 11.8 Serious eye damage/irritation : Not classified pH: 10.8 - 11.8 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : May damage fertility or the unborn child. Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Toxic to aquatic life. Disodium Tetraborate, Anhydrous (1330-43-4) LC50 fishes 1 340 mg/l (Exposure time: 96 h - Species: Limanda limanda) EC50 Daphnia 1 1085 - 1402 mg/l (Exposure time: 48 h - Species: Daphnia magna) EC50 other aquatic organisms 1 158 mg/l (Exposure time: 96 h - Species: Desmodesmus subspicatus) EC50 other aquatic organisms 2 2.6 - 21.8 mg/l (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata [static]) Sodium Mercaptobenzothiazole (2492-26-4) LC50 fishes 1 0.3 - 1.1 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) EC50 Daphnia 1 1.9 - 5.1 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) EC50 other aquatic organisms 1 0.3 mg/l (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata) LC50 fish 2 3.8 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) Sodium Nitrite (7632-00-0) LC50 fishes 1 0.19 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through]) LC50 fish 2 0.092 - 0.13 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through]) 12.2. Persistence and degradability TR84718 - Liquid Persistence and degradability Not established. 12.3. Bioaccumulative potential TR84718 - Liquid Bioaccumulative potential Not established. Disodium Tetraborate, Anhydrous (1330-43-4) BCF fish 1 (no evidence of bioaccumulation) Sodium Mercaptobenzothiazole (2492-26-4) Log Pow -0.46 Sodium Nitrite (7632-00-0) Log Pow -3.7 (at 25 ?C) 12.4. Mobility in soil No additional information available TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 6/8 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information UN-No.(DOT) : UN3082 UN-No. (IMDG) : Non Regulated UN-No.(IATA) : Non Regulated 14.2. UN proper shipping name Proper Shipping Name (DOT) : Environmentally Hazardous Substances, Liquid, N.O.S. (Sodium Nitrite) RQ of 2400 kg Proper Shipping Name (IMDG) : Not applicable Proper Shipping Name (IATA) : Not applicable 14.3. Transport hazard class(es) Department of Transportation (DOT) Hazard Classes : 9 - Class 9 (Miscellaneous dangerous materials) Hazard labels (DOT) : 9 : Transport hazard class(es) (IMDG) : Not applicable Transport hazard class(es) (IATA) : Not applicable 14.4. Packing group Packing group (DOT) : III Packing group (IMDG) : Not applicable Packing group (IATA) : Not applicable 14.5. Environmental hazards Marine pollutant(DOT) : No Marine pollutant(IMDG) : No Marine pollutant(IATA) : No TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 7/8 SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Sodium Nitrite CAS No 7632-00-0 1 - 5 Phenolphthalein (77-09-8) Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 0.1 % Sodium Nitrite (7632-00-0) Listed on United States SARA Section 313 EPA TSCA Regulatory Flag S - S - indicates a substance that is identified in a proposed or final Significant New Uses Rule. SARA Section 313 - Emission Reporting 1.0 % 15.2. International regulations CANADA Disodium tetraborate, anhydrous (1330-43-4) Listed on the Canadian DSL (Domestic Sustances List) Sodium Mercaptobenzothiazole (2492-26-4) Listed on the Canadian DSL (Domestic Sustances List) Sodium Nitrite (7632-00-0) Listed on the Canadian DSL (Domestic Sustances List) 15.3. US State regulations California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer and/or reproductive toxicity Phenolphthalein (77-09-8) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No SECTION 16: Other information Other information : None. Full text of H-phrases:: ------ Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 ------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 ------ Aquatic Acute 1 Hazardous to the aquatic environment ? Acute Hazard, Category 1 ------ Aquatic Acute 2 Hazardous to the aquatic environment ? Acute Hazard, Category 2 ------ Aquatic Acute 3 Hazardous to the aquatic environment ? Acute Hazard, Category 3 ------ Ox. Sol. 3 Oxidising Solids, Category 3 ------ Repr. 1B Reproductive toxicity, Category 1B ------ H272 May intensify fire; oxidiser ------ H301 Toxic if swallowed ------ H302 Harmful if swallowed ------ H360 May damage fertility or the unborn child ------ H400 Very toxic to aquatic life ------ H401 Toxic to aquatic life ------ H402 Harmful to aquatic life TR84718 - Liquid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/05/2015 EN (English) 8/8 NFPA health hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. NFPA specific hazard : NA - Not Applicable HMIS III Rating Health : 3 - Major injury likely unless prompt action is taken and medical treatment is given Flammability : 0 Physical : 0 Personal Protection : C Dober SDS US To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibil ity of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.