6984 Evaporator Odor Eliminator Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 11/12/2014 Supersedes:08/27/2014 Version: 2.1 12/11/2014 EN (English US) 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : 6984 Evaporator Odor Eliminator Aerosol Product code : 6984 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Aerosol foaming cleanser used to eliminate air conditioning evaporator odors. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 2 H225 Carc. 1A H350 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS08 GHS04 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor H350 - May cause cancer Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P280 - Wear protective gloves/protective clothing/eye protection/face protection P303 + P361 + P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P308 + P313 - If exposed or concerned: Get medical advice/attention P370+P378 - In case of fire: Use BC powder, Foam, Carbon dioxide to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents / container in accordance with local / regional / national / international regulations. 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may burst if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 6984 Evaporator Odor Eliminator Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 2/6 3.2. Mixture Name Product identifier % Classification (GHS-US) ethanol (CAS No) 64-17-5 1 - 5 Flam. Liq. 2, H225 Carc. 1A, H350 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to- mouth. If breathing is difficult give oxygen. Get medical attention. First-aid measures after skin contact : Remove contaminated clothing. Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. First-aid measures after eye contact : Move to fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; Remove any contact lenses if present. Seek immediate medical attention. First-aid measures after ingestion : Do not give anything by mouth. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : BC powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Do not store above 120?F. Avoid Extreme heat, open flames or sparks. Incompatible materials : Strong oxidizers. 7.3. Specific end use(s) No additional information available 6984 Evaporator Odor Eliminator Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 3/6 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : The use of gloves impervious to the specific material handled is advised to prevent skin contact. Suggested protective material: Nitrile, 4.5 mil thickness, tested at 3.5 ml and above with no breakthrough time after 240 minutes. Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear-hazy liquid. Color : Colorless. Odor : Citrus odor. Odor threshold : No data available pH : 10.2 - 10.6 Relative evaporation rate (butyl acetate=1) : < 1 Melting point : No data available Freezing point : No data available Boiling point : > 93 ?C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Density : 0.98 - 1 g/ml Solubility : Soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 10.51 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Do not expose to heat or store at temperatures above 120?F (49?C). 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Carbon monoxide. Carbon Dioxide. 6984 Evaporator Odor Eliminator Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 4/6 SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified diethyleneglycolmonoethyl ether (111-90-0) LD50 oral rat 5445 mg/kg (Rat) LD50 dermal rat 5940 mg/kg (Rat) LD50 dermal rabbit > 5000 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 5.2 mg/l/4h (Rat) ATE (oral) 5445.000 mg/kg body weight ATE (dermal) 5940.000 mg/kg body weight Skin corrosion/irritation : Not classified pH: 10.2 - 10.6 Serious eye damage/irritation : Not classified pH: 10.2 - 10.6 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Based on available data, the classification criteria are not met Carcinogenicity : May cause cancer. Reproductive toxicity : Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met Aspiration hazard : Based on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity diethyleneglycolmonoethyl ether (111-90-0) LC50 fish 1 12900 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Flow-through system) EC50 Daphnia 1 3940 mg/l (48 h; Daphnia magna) EC50 other aquatic organisms 1 10661 mg/l (Echinoidea; Growth) LC50 fish 2 9650 mg/l (96 h; Pimephales promelas; Flow-through system) 12.2. Persistence and degradability 6984 Evaporator Odor Eliminator Aerosol Persistence and degradability Not established. diethyleneglycolmonoethyl ether (111-90-0) Persistence and degradability Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.20 g O?/g substance Chemical oxygen demand (COD) 1.85 g O?/g substance ThOD 1.9078849 g O?/g substance BOD (% of ThOD) 0.11 % ThOD 12.3. Bioaccumulative potential 6984 Evaporator Odor Eliminator Aerosol Bioaccumulative potential Not established. diethyleneglycolmonoethyl ether (111-90-0) Log Pow -1.19 - -0.08 Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil diethyleneglycolmonoethyl ether (111-90-0) Surface tension 0.032 N/m (25 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. 6984 Evaporator Odor Eliminator Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 5/6 Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No.(DOT) : 1950 14.2. UN proper shipping name DOT Proper Shipping Name : Aerosols, LTD QTY Department of Transportation (DOT) Hazard Classes : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 Hazard labels (DOT) : Limited Quantity 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA 6984 Evaporator Odor Eliminator Aerosol WHMIS Classification Class A - Compressed Gas Class B Division 1 - Flammable Gas Class B Division 2 - Flammable Liquid EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Eye Irrit. 2 H319 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC 15.2.2. National regulations No additional information available 15.3. US State regulations 6984 Evaporator Odor Eliminator Aerosol() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No 6984 Evaporator Odor Eliminator Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 6/6 diethyleneglycolmonoethyl ether (111-90-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: ------ Carc. 1A Carcinogenicity Category 1A ------ Flam. Liq. 2 Flammable liquids Category 2 ------ H225 Highly flammable liquid and vapor ------ H350 May cause cancer NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.