7295 R-134a REFRIGERANT PLUS 46 PAG OIL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 11/11/2014 Supersedes:08/07/2014 Version: 2.0 11/11/2014 EN (English US) 1/5 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Product code : 7295 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Low Viscosity Polyalkylene Glycol based lubricant plus refrigerant charge. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may burst if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 3.2. Mixture Name Product identifier % Classification (GHS-US) 2,6-di-tert-butyl-p-cresol (CAS No) 128-37-0 < 0.5 Acute Tox. 4 (Oral), H302 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Content under pressure. "Frostbite-like" effects may occur if the liquid or escaping vapors contact the eyes or skin. Gross inhalation over exposure may cause: Central nervous system depression with dizziness, confusion, incoordination, drowsiness or unconsciousness or death. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to- mouth. If breathing is difficult give oxygen. Get medical attention. Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and shoes, and launder before reuse. Use approved skin lotions or creams to replace lost skin oils. Treat for frostbite if necessary by gently warming affected area. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 2/5 First-aid measures after eye contact : In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : DO NOT INDUCE VOMITING. Give nothing by mouth. Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : Central nervous system depression. Dizziness. Mental confusion. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water fog, carbon dioxide, foam, dry chemical. Use water spray to keep containers cool that are exposed to heat or flames. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Warning!! Contents under pressure. Container may rupture under fire conditions. Decomposition may occur. Wear approved positive-pressure self-contained breathing apparatus and protective clothing. 6.1.1. For non-emergency personnel Protective equipment : Wear appropriate protective clothing and equipment to prevent skin and eye contact. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Increase area ventilation. Do not puncture or incinerate container. Contents under pressure. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : CAUTION: COMPRESSED GAS. Do not puncture, incinerate or store above 120?F. Do not store in passenger compartment of automobile. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Should not be mixed with air for leak testing or used for any other purpose above atmospheric pressure. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Do not store above 120?F. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage temperature : < 49 ?C Do not store in passenger compartment of automobiles. Storage area : Store in a dry area. Store in a cool area. 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 3/5 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Showers. Eyewash stations. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Insulated gloves. Wear protective gloves. Eye protection : Wear safety glasses or goggles to protect against exposure. Chemical goggles or safety glasses. Skin and body protection : Avoid skin contact. Wear protective clothing and gloves. Respiratory protection : Use in a well ventilated area. Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid or gas at ambient temperatures. Color : Clear to Yellowish. Odor : Characteristic. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : -26.5 ?C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 41.4 - 50.6 cSt @40?C Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. Stable under normal temperatures and pressures. Not established. 10.3. Possibility of hazardous reactions Hazardous Polymerization: WILL NOT OCCUR. Not established. 10.4. Conditions to avoid Do not expose to heat or store at temperatures above 120 F. Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 4/5 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. This material can be decomposed by high temperatures forming hydrofluoric acid and possibly carbonyl fluoride. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Based on available data, the classification criteria are not met Carcinogenicity : (Not expected to cause cancer. This oil meets the IP-346 criteria of less than 3 percent PAH's and is not considered a carcinogen by the International Agency for Research on Cancer.) Reproductive toxicity : Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met Aspiration hazard : Based on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Central nervous system depression. Dizziness. Mental confusion. SECTION 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Persistence and degradability Not established. 12.3. Bioaccumulative potential 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Disposal should be made in accordance with federal, state and local regulations. Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No.(DOT) : 1950 14.2. UN proper shipping name DOT Proper Shipping Name : Aerosols LTD QTY Department of Transportation (DOT) Hazard Classes : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : Limited Quantity 7295 R-134a REFRIGERANT PLUS 46 PAG OIL Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 5/5 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC 15.2.2. National regulations No additional information available 15.3. US State regulations 7295 R-134a REFRIGERANT PLUS 46 PAG OIL() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ H302 Harmful if swallowed NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.