14378 Odor Buster New Car Scent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 11/12/2014 Supersedes:08/26/2014 Version: 2.1 12/11/2014 EN (English US) 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : 14378 Odor Buster New Car Scent Product code : 14378 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Automotive interior odor neutralizer. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 2 H225 Carc. 1A H350 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS08 GHS04 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor H350 - May cause cancer Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting/? equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P280 - Wear protective gloves/protective clothing/eye protection/face protection P303 + P361 + P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P308 + P313 - If exposed or concerned: Get medical advice/attention P370+P378 - In case of fire: Use BC powder, Foam, Carbon dioxide to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents / container in accordance with local / regional / national / international regulations. 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may burst if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 14378 Odor Buster New Car Scent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 2/6 3.2. Mixture Name Product identifier % Classification (GHS-US) ethanol (CAS No) 64-17-5 60 - 100 Flam. Liq. 2, H225 Carc. 1A, H350 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to- mouth. If breathing is difficult give oxygen. Get medical attention. First-aid measures after skin contact : Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated clothing before reuse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth with water. Give nothing to drink. Do NOT induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Do not store above 120?F. Avoid Extreme heat, open flames or sparks. 14378 Odor Buster New Car Scent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 3/6 Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-propanol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 200 ppm 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : The use of gloves impervious to the specific material handled is advised to prevent skin contact. Suggested protective material: Nitrile, 4.5 mil thickness, tested at 3.5 ml and above with no breakthrough time after 240 minutes. Eye protection : Chemical goggles or safety glasses. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear. Color : Colorless. Odor : Fruity. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : < 1 Melting point : No data available Freezing point : No data available Boiling point : > 38 ?C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 97.25 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 14378 Odor Buster New Car Scent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 4/6 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5. Incompatible materials Avoid contact with strong oxidizers. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide and hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2-propanol (67-63-0) LD50 oral rat 5045 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; 5840 mg/kg bodyweight; Rat) LD50 dermal rabbit 12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit) LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat) ATE (oral) 5045.000 mg/kg body weight ATE (dermal) 12870.000 mg/kg body weight ATE (vapors) 73.000 mg/l/4h ATE (dust, mist) 73.000 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Based on available data, the classification criteria are not met Carcinogenicity : May cause cancer. 2-propanol (67-63-0) IARC group 3 Reproductive toxicity : Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met Aspiration hazard : Based on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity 2-propanol (67-63-0) LC50 fish 1 4200 mg/l (96 h; Rasbora heteromorpha; Flow-through system) EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna) LC50 fish 2 9640 mg/l (96 h; Pimephales promelas; Lethal) EC50 Daphnia 2 13299 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 1000 mg/l (72 h; Scenedesmus subspicatus; Growth rate) Threshold limit algae 2 1800 mg/l (72 h; Algae; Cell numbers) 12.2. Persistence and degradability 14378 Odor Buster New Car Scent Persistence and degradability Not established. 2-propanol (67-63-0) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) 1.19 g O?/g substance Chemical oxygen demand (COD) 2.23 g O?/g substance ThOD 2.40 g O?/g substance BOD (% of ThOD) 0.49 % ThOD 12.3. Bioaccumulative potential 14378 Odor Buster New Car Scent Bioaccumulative potential Not established. 14378 Odor Buster New Car Scent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 5/6 2-propanol (67-63-0) Log Pow 0.05 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil 2-propanol (67-63-0) Surface tension 0.021 N/m (25 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No.(DOT) : 1950 14.2. UN proper shipping name DOT Proper Shipping Name : Aerosols, LTD QTY Department of Transportation (DOT) Hazard Classes : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 Hazard labels (DOT) : Limited Quantity 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA 14378 Odor Buster New Car Scent WHMIS Classification Class A - Compressed Gas Class B Division 1 - Flammable Gas Class B Division 2 - Flammable Liquid EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Muta. 1B H340 Carc. 1A H350 Full text of H-phrases: see section 16 14378 Odor Buster New Car Scent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 6/6 Classification according to Directive 67/548/EEC or 1999/45/EC 15.2.2. National regulations 14378 Odor Buster New Car Scent All components of this product are listed or are not regulated U.S. Toxic Substance Control Act (TSCA) Chemical Substance Inventory. 15.3. US State regulations 14378 Odor Buster New Car Scent() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No 2-propanol (67-63-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No Petroleum gases, liquefied, sweetened (68476-86-8) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: ------ Carc. 1A Carcinogenicity Category 1A ------ Flam. Liq. 2 Flammable liquids Category 2 ------ H225 Highly flammable liquid and vapor ------ H350 May cause cancer NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.