16310 R-134a REFRIGERANT PLUS PAG OIL Safety Data Sheet This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Date of issue: 08/25/2014 Revision date: 08/25/2014 Supersedes: 05/13/2013 Version: 2.0 2014/08/25 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : 16310 R-134a REFRIGERANT PLUS PAG OIL Product code : 16310 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Polyalkylene Glycol based lubricant plus refrigerant charge. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac SDS Preparer Paul J. Erdek 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified WHMIS Classification Class A - Compressed Gas Class D Division 2 Subdivision B - Toxic material causing other toxic effects 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS04 GHS08 GHS09 Signal word (GHS-US) : Warning 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may burst if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification PPG-3 METHYL ETHER (CAS No) 37286-64-9 40 - 55 Not classified 1,1,1,2-tetrafluoroethane (CAS No) 811-97-2 25 - 40 Not classified tricresyl phosphates, mixture of isomers, conc o-tricresyl phosphate>95% (CAS No) 1330-78-5 0.1 - 0.5 Not classified 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexylcarboxylate (CAS No) 2386-87-0 0.1 - 0.5 Not classified 2,6-di-tert-butyl-p-cresol (CAS No) 128-37-0 0.1 - 0.5 Acute Tox. 4 (Oral), H302 16310 R-134a REFRIGERANT PLUS PAG OIL Safety Data Sheet This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products 2014 /08/25 EN (English) 2/6 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Content under pressure. "Frostbite-like" effects may occur if the liquid or escaping vapors contact the eyes or skin. Gross inhalation over exposure may cause: Central nervous system depression with dizziness, confusion, incoordination, drowsiness or unconsciousness or death. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to- mouth. If breathing is difficult give oxygen. Get medical attention. Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and shoes, and launder before reuse. Use approved skin lotions or creams to replace lost skin oils. Treat for frostbite if necessary by gently warming affected area. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : DO NOT INDUCE VOMITING. Give nothing by mouth. Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : Central nervous system depression. Dizziness. Mental confusion. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water fog, carbon dioxide, foam, dry chemical. Use water spray to keep containers cool that are exposed to heat or flames. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Warning!! Contents under pressure. Container may rupture under fire conditions. Decomposition may occur. Wear approved positive-pressure self-contained breathing apparatus and protective clothing. 6.1.1. For non-emergency personnel Protective equipment : Wear appropriate protective clothing and equipment to prevent skin and eye contact. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Increase area ventilation. Do not puncture or incinerate container. Contents under pressure. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store aways from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. 16310 R-134a REFRIGERANT PLUS PAG OIL Safety Data Sheet This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products 2014 /08/25 EN (English) 3/6 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : CAUTION: COMPRESSED GAS. Do not puncture, incinerate or store above 120?F. Do not store in passenger compartment of automobile. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Should not be mixed with air for leak testing or used for any other purpose above atmospheric pressure. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Do not store above 120?F. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage temperature : < 49 ?C Do not store in passenger compartment of automobiles. Storage area : Store in a dry area. Store in a cool area. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2,6-di-tert-butyl-p-cresol (128-37-0) ACGIH ACGIH TWA (mg/m?) 2 mg/m? 8.2. Exposure controls Appropriate engineering controls : Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Showers. Eyewash stations. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Insulated gloves. Wear protective gloves. Eye protection : Wear safety glasses or goggles to protect against exposure. Chemical goggles or safety glasses. Skin and body protection : Avoid skin contact. Wear protective clothing and gloves. Respiratory protection : Use in a well ventilated area. Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid or gas at ambient temperatures. Colour : Clear to Yellowish. Odour : Characteristic. Odour threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : -26.5 ?C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 ?C : No data available Relative density : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available 16310 R-134a REFRIGERANT PLUS PAG OIL Safety Data Sheet This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products 2014 /08/25 EN (English) 4/6 Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. Stable under normal temperatures and pressures. Not established. 10.3. Possibility of hazardous reactions Hazardous Polymerization: WILL NOT OCCUR. Not established. 10.4. Conditions to avoid Do not expose to heat or store at temperatures above 120 F. Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. This material can be decomposed by high temperatures forming hydrofluoric acid and possibly carbonyl fluoride. fume. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2,6-di-tert-butyl-p-cresol (128-37-0) LD50 oral rat 890 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; >6000 mg/kg bodyweight; Rat) LD50 dermal rat > 2000 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg bodyweight; Rat; Experimental value) ATE (oral) 890.000 mg/kg bodyweight Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Based on available data, the classification criteria are not met Carcinogenicity : (Not expected to cause cancer. This oil meets the IP-346 criteria of less than 3 percent PAH's and is not considered a carcinogen by the International Agency for Research on Cancer.) 2,6-di-tert-butyl-p-cresol (128-37-0) IARC group 3 Reproductive toxicity : Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met Aspiration hazard : Based on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Central nervous system depression. Dizziness. Mental confusion. SECTION 12: Ecological information 12.1. Toxicity 2,6-di-tert-butyl-p-cresol (128-37-0) LC50 fishes 1 0.199 mg/l (96 h; Pisces) EC50 Daphnia 1 0.48 mg/l (48 h; Daphnia magna; GLP) Threshold limit algae 1 > 0.4 mg/l (72 h; Scenedesmus subspicatus; GLP) Threshold limit algae 2 0.363 mg/l (Algae; Chronic) 12.2. Persistence and degradability 16310 R-134a REFRIGERANT PLUS PAG OIL Persistence and degradability Not established. 16310 R-134a REFRIGERANT PLUS PAG OIL Safety Data Sheet This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products 2014 /08/25 EN (English) 5/6 2,6-di-tert-butyl-p-cresol (128-37-0) Persistence and degradability Not readily biodegradable in water. Biodegradable in the soil. Adsorbs into the soil. Low potential for mobility in soil. Photooxidation in the air. Biochemical oxygen demand (BOD) 0.51 g O?/g substance Chemical oxygen demand (COD) 2.27 g O?/g substance ThOD 2.977 g O?/g substance BOD (% of ThOD) 0.17 % ThOD 12.3. Bioaccumulative potential 16310 R-134a REFRIGERANT PLUS PAG OIL Bioaccumulative potential Not established. 2,6-di-tert-butyl-p-cresol (128-37-0) BCF fish 1 230 - 2500 (56 days; Cyprinus carpio) Log Pow 5.1 (Experimental value) Bioaccumulative potential Potential for bioaccumulation (500 ? BCF ? 5000). 12.4. Mobility in soil 2,6-di-tert-butyl-p-cresol (128-37-0) Ecology - soil May be harmful to plant growth, blooming and fruit formation. 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Disposal should be made in accordance with federal, state and local regulations. Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with TDG TDG Transport document description : 1950, 2.2 UN-No (TDG) : 1950 TDG Primary Hazard Classes : 2.2 - Class 2.2 - Non-Flammable, Non-Toxic Gas. DOT UN-No.(DOT) : 1950 DOT Proper Shipping Name : Aerosols, LTD QTY Department of Transportation (DOT) Hazard Classes : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : Limited Quantity Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available 16310 R-134a REFRIGERANT PLUS PAG OIL Safety Data Sheet This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products 2014 /08/25 EN (English) 6/6 SECTION 15: Regulatory information CANADA 16310 R-134a REFRIGERANT PLUS PAG OIL WHMIS Classification Class A - Compressed Gas Class D Division 2 Subdivision B - Toxic material causing other toxic effects 15.2. International regulations EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] No additional information available Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations No additional information available SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 ------ H302 Harmful if swallowed NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. SDS Canada (GHS) This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.