22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 10/29/2014 Supersedes:08/25/2014 Version: 2.1 29/10/2014 EN (English US) 1/7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : 22779 Flash Flush Gallon Product code : 22779 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Supercool Flash Flush is used as a flushing fluid to clean the internal components of air conditioning systems. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 2 H225 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor Precautionary statements (GHS-US) : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P280 - Wear protective gloves/protective clothing/eye protection/face protection P303 + P361 + P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 - In case of fire: Use Foam, Dry powder, Carbon dioxide, Water spray, Sand to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents / container in accordance with local / regional / national / international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 3.2. Mixture Name Product identifier % Classification (GHS-US) heptane (CAS No) 142-82-5 80 - 100 Flam. Liq. 2, H225 2-propanol (CAS No) 67-63-0 10 - 20 Flam. Liq. 2, H225 22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 29/10/2014 EN (English US) 2/7 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : No naked lights. No smoking. Use only non-sparking tools. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Storage conditions : Keep in fireproof place. Store in original container. Avoid Extreme heat, open flames or sparks. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Heat sources. Sources of ignition. Direct sunlight. 22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 29/10/2014 EN (English US) 3/7 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters heptane (142-82-5) USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm 2-propanol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 200 ppm 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless. Odor : Characteristic. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : > 1 Melting point : No data available Freezing point : No data available Boiling point : > 38 ?C Flash point : -3.8 ?C ASTM D-56 Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : Insoluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 100 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. Not established. 10.3. Possibility of hazardous reactions Not established. 22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 29/10/2014 EN (English US) 4/7 10.4. Conditions to avoid Open flame. Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products May release flammable gases. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified heptane (142-82-5) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) ATE (gases) 25000.000 ppmV/4h ATE (vapors) 103.000 mg/l/4h ATE (dust, mist) 103.000 mg/l/4h 2-propanol (67-63-0) LD50 oral rat 5045 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; 5840 mg/kg bodyweight; Rat) LD50 dermal rabbit 12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit) LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat) ATE (oral) 5045.000 mg/kg body weight ATE (dermal) 12870.000 mg/kg body weight ATE (vapors) 73.000 mg/l/4h ATE (dust, mist) 73.000 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Based on available data, the classification criteria are not met Carcinogenicity : Not classified 2-propanol (67-63-0) IARC group 3 Reproductive toxicity : Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met Aspiration hazard : Based on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Toxic to aquatic life. heptane (142-82-5) LC50 fish 1 375 mg/l (96 h; Tilapia mosambica; Nominal concentration) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) EC50 Daphnia 1 1.5 mg/l (48 h; Daphnia magna) LC50 fish 2 > 100 mg/l (96 h; Oncorhynchus kisutch) TLM fish 1 4924 mg/l (48 h; Gambusia affinis) Threshold limit other aquatic organisms 1 > 1000 mg/l (96 h) Threshold limit algae 1 > 200 mg/l (Scenedesmus quadricauda; Toxicity test) Threshold limit algae 2 1.5 mg/l (8 h; Algae; Photosynthesis) 2-propanol (67-63-0) LC50 fish 1 4200 mg/l (96 h; Rasbora heteromorpha; Flow-through system) 22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 29/10/2014 EN (English US) 5/7 heptane (142-82-5) EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna) LC50 fish 2 9640 mg/l (96 h; Pimephales promelas; Lethal) EC50 Daphnia 2 13299 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 1000 mg/l (72 h; Scenedesmus subspicatus; Growth rate) Threshold limit algae 2 1800 mg/l (72 h; Algae; Cell numbers) 12.2. Persistence and degradability 22779 Flash Flush Gallon Persistence and degradability Not established. heptane (142-82-5) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Adsorbs into the soil. Biochemical oxygen demand (BOD) 1.92 g O?/g substance Chemical oxygen demand (COD) 0.06 g O?/g substance ThOD 3.52 g O?/g substance BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5 2-propanol (67-63-0) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) 1.19 g O?/g substance Chemical oxygen demand (COD) 2.23 g O?/g substance ThOD 2.40 g O?/g substance BOD (% of ThOD) 0.49 % ThOD 12.3. Bioaccumulative potential 22779 Flash Flush Gallon Bioaccumulative potential Not established. heptane (142-82-5) BCF other aquatic organisms 1 552 Log Pow 4.66 (Experimental value; 4.5; Literature) Bioaccumulative potential Potential for bioaccumulation (4 ? Log Kow ? 5). 2-propanol (67-63-0) Log Pow 0.05 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil heptane (142-82-5) Surface tension 0.020 N/m (20 ?C) 2-propanol (67-63-0) Surface tension 0.021 N/m (25 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No.(DOT) : 1993 14.2. UN proper shipping name DOT Proper Shipping Name : FLAMMABLE LIQUID, N.O.S. (Heptanes, Isopropanol) Department of Transportation (DOT) Hazard Classes : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 29/10/2014 EN (English US) 6/7 Hazard labels (DOT) : 3 - Flammable liquid Packing group (DOT) : II - Medium Danger 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA 22779 Flash Flush Gallon WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC 15.2.2. National regulations No additional information available 15.3. US State regulations 22779 Flash Flush Gallon() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No heptane (142-82-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No 2-propanol (67-63-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No 22779 Flash Flush Gallon Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 29/10/2014 EN (English US) 7/7 SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of H-phrases: see section 16: ------ Flam. Liq. 2 Flammable liquids Category 2 ------ H225 Highly flammable liquid and vapor NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 4 Severe Hazard Physical : 0 Minimal Hazard SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.