24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 11/12/2014 Supersedes:08/25/2014 Version: 4.1 12/11/2014 EN (English US) 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP CAS No : 811-97-2 Product code : 24049 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : R-134a With Leak Stop is used as an R-134a Refrigerant charge and Leak Stop in R-134a refrigeration systems. Use of the substance/mixture : Refrigerant gas 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may burst if heated. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 3.2. Mixture Name Product identifier % Classification (GHS-US) 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (CAS No) 68515-49-1 5 - 13 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Content under pressure. "Frostbite-like" effects may occur if the liquid or escaping vapors contact the eyes or skin. Gross inhalation over exposure may cause: Central nervous system depression with dizziness, confusion, incoordination, drowsiness or unconsciousness or death. Vomiting: prevent asphyxia/aspiration pneumonia. First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to- mouth. If breathing is difficult give oxygen. Get medical attention. 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 2/6 First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and shoes, and launder before reuse. Use approved skin lotions or creams to replace lost skin oils. Treat for frostbite if necessary by gently warming affected area. First-aid measures after eye contact : In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. First-aid measures after ingestion : DO NOT INDUCE VOMITING. Give nothing by mouth. Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Central nervous system depression. Dizziness. Mental confusion. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. BC powder. Water fog, carbon dioxide, foam, dry chemical. Use water spray to keep containers cool that are exposed to heat or flames. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters No additional information available SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Warning!! Contents under pressure. Container may rupture under fire conditions. Decomposition may occur. Wear approved positive-pressure self-contained breathing apparatus and protective clothing. 6.1.1. For non-emergency personnel Protective equipment : Wear appropriate protective clothing and equipment to prevent skin and eye contact. 6.1.2. For emergency responders No additional information available 6.2. Environmental precautions No additional information available 6.3. Methods and material for containment and cleaning up For containment : Increase area ventilation. Do not puncture or incinerate container. Contents under pressure. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : CAUTION: COMPRESSED GAS. Do not puncture, incinerate or store above 120?F. Do not store in passenger compartment of automobile. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Should not be mixed with air for leak testing or used for any other purpose above atmospheric pressure. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Do not store above 120?F. Storage temperature : < 49 ?C Do not store in passenger compartment of automobiles. Storage area : Store in a dry area. Store in a cool area. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Showers. Eyewash stations. Hand protection : Insulated gloves. Eye protection : Safety glasses. Safety glasses. Wear safety glasses or goggles to protect against exposure. Skin and body protection : Avoid skin contact. Wear protective clothing and gloves. 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 3/6 Respiratory protection : Use in a well ventilated area. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid or gas at ambient temperatures. Color : Colorless to Yellowish. Odor : Ether-like odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : -26.5 ?C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information Gas group : Liquefied gas SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. Stable under normal temperatures and pressures. 10.3. Possibility of hazardous reactions Hazardous Polymerization: WILL NOT OCCUR. 10.4. Conditions to avoid Do not expose to heat or store at temperatures above 120?F. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Carbon monoxide. Carbon Dioxide. This material can be decomposed by high temperatures forming hydrofluoric acid and possibly carbonyl fluoride. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) LD50 oral rat 2000 mg/kg (Rat) LD50 dermal rabbit 2000 mg/kg (Rabbit) ATE (oral) 2000.000 mg/kg body weight ATE (dermal) 2000.000 mg/kg body weight 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 4/6 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) Additional information Di-isodecyl phthalate (DIDP) has been tested in reproductive toxicology studies in laboratory rats (two-generation studies). There were no effects on fertility, reproductive performance, or evidence of alteration of endocrine processes. A small, statistically significant decrease in offspring survival was observed. In evaluating these and related studies, the EU Risk Assessment for DIDP has concluded that classification and labeling is not required for any effect including reproductive and developmental effects. In addition the NTP Center for Evaluation of Risks to Human Reproduction has concluded that there is negligible concern for reproductive effects in adults and minimal concern for developmental effects in fetuses and children due to DIDP exposure. Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : (Not expected to cause cancer. This oil meets the IP-346 criteria of less than 3 percent PAH's and is not considered a carcinogen by the International Agency for Research on Cancer.) Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Symptoms/injuries after inhalation : Central nervous system depression. Dizziness. Mental confusion. SECTION 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) Persistence and degradability Expected to be readily biodegradable. 12.3. Bioaccumulative potential 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) Bioaccumulative potential No bioaccumulation data available. 12.4. Mobility in soil 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) Surface tension 0.033 N/m 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Disposal should be made in accordance with federal, state and local regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No.(DOT) : 3159 14.2. UN proper shipping name DOT Proper Shipping Name : 1,1,1,2-Tetrafluorethane Department of Transportation (DOT) Hazard Classes : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : 2.2 - Non-flammable gas 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 5/6 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP (811-97-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP (811-97-2) Listed on the Canadian DSL (Domestic Substances List) inventory. WHMIS Classification Class A - Compressed Gas Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC 15.2.2. National regulations No additional information available 15.3. US State regulations 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP(811-97-2) U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No Yes No No 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1) State or local regulations This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 24049 SUPERCOOL R-134a REFRIGERANT PLUS LEAK STOP Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/11/2014 EN (English US) 6/6 SECTION 16: Other information Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.