24087 R134a Leak Stop Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/06/2015 Revision date: 04/06/2015 Supersedes: 08/08/2013 Version: 2.1 04/06/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : 24087 R134a Leak Stop Aerosol Product code : 24087 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Stops small leaks in R-134a air conditioning system rubber hoses, o-rings and seals. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street Lake Worth, Florida 33461 - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated Precautionary statements (GHS-US) : P102 - Keep out of reach of children P412 - Do not expose to temperatures exceeding 50 ?C/ 122 ?F 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may burst if heated. 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) 1,1,1,2-tetrafluoroethane (CAS No) 811-97-2 50 Not classified Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. 24087 R134a Leak Stop Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/06/2015 EN (English US) 2/1 First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage temperature : < 50 ?C 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 24087 R134a Leak Stop Aerosol ACGIH Not applicable 24087 R134a Leak Stop Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/06/2015 EN (English US) 3/1 24087 R134a Leak Stop Aerosol OSHA Not applicable 1,1,1,2-tetrafluoroethane (811-97-2) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : The use of gloves impervious to the specific material handled is advised to prevent skin contact. Suggested protective material: Nitrile, 4.5 mil thickness, tested at 3.5 ml and above with no breakthrough time after 240 minutes. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Where there is potential for airborne exposure above the exposure limit an approved air purifying respirator equipped with Type P2 - Medium efficiency particle filters may be used. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Red tint Odor : Characteristic Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : No data available Explosion limits : No data available Explosive properties : No data available Oxidizing properties : No data available Vapor pressure : No data available Relative density : No data available Relative vapor density at 20 ?C : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 24087 R134a Leak Stop Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/06/2015 EN (English US) 4/1 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 1,1,1,2-tetrafluoroethane (811-97-2) LC50 inhalation rat (mg/l) > 2000 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) > 359300 ppm/4h (Rat; Literature study) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified (Not expected to cause cancer. This oil meets the IP-346 criteria of less than 3 percent PAH's and is not considered a carcinogen by the International Agency for Research on Cancer.) Reproductive toxicity : Not classified Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity 1,1,1,2-tetrafluoroethane (811-97-2) LC50 fish 1 450 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 980 mg/l (48 h; Daphnia magna) 12.2. Persistence and degradability 24087 R134a Leak Stop Aerosol Persistence and degradability Not established. 1,1,1,2-tetrafluoroethane (811-97-2) Persistence and degradability Not readily biodegradable in water. 12.3. Bioaccumulative potential 24087 R134a Leak Stop Aerosol Bioaccumulative potential Not established. 1,1,1,2-tetrafluoroethane (811-97-2) BCF other aquatic organisms 1 5 - 58 (Estimated value) Log Pow 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 24087 R134a Leak Stop Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/06/2015 EN (English US) 5/1 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Proper Shipping Name (DOT) : Aerosols LTD QTY Transport hazard class(es) (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : Limited Quantity Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] No additional information available National regulations No additional information available 24087 R134a Leak Stop Aerosol Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/06/2015 EN (English US) 6/1 15.3. US State regulations 24087 R134a Leak Stop Aerosol() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No SECTION 16: Other information Revision date : 04/06/2015 NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.