P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 11/11/2014 Supersedes:08/28/2014 Version: 2.1 11/11/2014 EN (English US) 1/5 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Product code : P46-32D 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Polyalkylene Glycol based lubricant with ultraviolet leak detection dye to help detect leaks in air conditioning systems. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street 33461 Lake Worth, Florida - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 3.2. Mixture SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 2/5 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2,6-di-tert-butyl-p-cresol (128-37-0) USA ACGIH ACGIH TWA (mg/m?) 2 mg/m? 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : The use of gloves impervious to the specific material handled is advised to prevent skin contact. Suggested protective material: Nitrile, 4.5 mil thickness, tested at 3.5 ml and above with no breakthrough time after 240 minutes. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Where there is potential for airborne exposure above the exposure limit an approved air purifying respirator equipped with Type P2 - Medium efficiency particle filters may be used. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear. Color : Reddish Green Tint. Odor : Characteristic. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 3/5 Melting point : No data available Freezing point : No data available Boiling point : > 200 ?C Calculated Flash point : 174 ?C Closed Cup Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 41.4 - 50.6 cSt @40?C Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon Dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2,6-di-tert-butyl-p-cresol (128-37-0) LD50 oral rat 890 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; >6000 mg/kg bodyweight; Rat) LD50 dermal rat > 2000 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg bodyweight; Rat; Experimental value) ATE (oral) 890.000 mg/kg body weight Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Based on available data, the classification criteria are not met Carcinogenicity : Not classified 2,6-di-tert-butyl-p-cresol (128-37-0) IARC group 3 Reproductive toxicity : Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 4/5 Aspiration hazard : Based on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Toxic to aquatic life. 2,6-di-tert-butyl-p-cresol (128-37-0) LC50 fish 1 0.199 mg/l (96 h; Pisces) EC50 Daphnia 1 0.48 mg/l (48 h; Daphnia magna; GLP) Threshold limit algae 1 > 0.4 mg/l (72 h; Scenedesmus subspicatus; GLP) Threshold limit algae 2 0.363 mg/l (Algae; Chronic) 12.2. Persistence and degradability P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Persistence and degradability Not established. tricresyl phosphates, mixture of isomers, conc o-tricresyl phosphate>95% (1330-78-5) Persistence and degradability Readily biodegradable in water. 2,6-di-tert-butyl-p-cresol (128-37-0) Persistence and degradability Not readily biodegradable in water. Biodegradable in the soil. Adsorbs into the soil. Low potential for mobility in soil. Photooxidation in the air. Biochemical oxygen demand (BOD) 0.51 g O?/g substance Chemical oxygen demand (COD) 2.27 g O?/g substance ThOD 2.977 g O?/g substance BOD (% of ThOD) 0.17 % ThOD 12.3. Bioaccumulative potential P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Bioaccumulative potential Not established. tricresyl phosphates, mixture of isomers, conc o-tricresyl phosphate>95% (1330-78-5) Log Pow 5.11 (Experimental value) 2,6-di-tert-butyl-p-cresol (128-37-0) BCF fish 1 230 - 2500 (56 days; Cyprinus carpio) Log Pow 5.1 (Experimental value) Bioaccumulative potential Potential for bioaccumulation (500 ? BCF ? 5000). 12.4. Mobility in soil 2,6-di-tert-butyl-p-cresol (128-37-0) Ecology - soil May be harmful to plant growth, blooming and fruit formation. 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number Not applicable 14.2. UN proper shipping name Not applicable 14.3. Additional information Other information : No supplementary information available. Overland transport Not regulated Transport by sea Not regulated P46-32D PAG Refrigeration Lubricant 46 + U/V Dye Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN (English US) 5/5 Air transport Not regulated SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA P46-32D PAG Refrigeration Lubricant 46 + U/V Dye WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC 15.2.2. National regulations No additional information available 15.3. US State regulations P46-32D PAG Refrigeration Lubricant 46 + U/V Dye() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No tricresyl phosphates, mixture of isomers, conc o-tricresyl phosphate>95% (1330-78-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No 2,6-di-tert-butyl-p-cresol (128-37-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No SECTION 16: Other information NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) - TSI This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.