SAFETY DATA SHEET Date Prepared : 04/15/2015 SDS No : 0015-04-2015K ACDelco 88864346 ACDelco Engine Sealant 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ACDelco Engine Sealant PRODUCT DESCRIPTION: Engine Sealant PRODUCT CODE: 88864346 DISTRIBUTOR 24 HR. EMERGENCY TELEPHONE NUMBERS ThreeBond International, Inc. 6184 Schumacher Park Drive West Chester, OH 45069 Emergency Phone: (513) 779-7300 CHEMTREC (Domestic North America):(800) 424 - 9300 CHEMTREC (International):(703) 527 - 3887 2. HAZARDS IDENTIFICATION GHS CLASSIFICATIONS Health: Skin Sensitization, Category 1B Serious eye damage/Eye irritation, Category 1 Specific target organ toxicity after repeated exposure: (Hematopoietic System), Category 2 GHS LABEL Exclamation mark Health hazard Corrosion SIGNAL WORD: DANGER HAZARD STATEMENTS H318: Causes serious eye damage. H317: May cause an allergic skin reaction. H373: May cause damage to organs ( state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard). Precautionary statement(s) Prevention: P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P260: Do not breathe dust/fume/gas/mist/vapours/spray. Response: P302+P352: IF ON SKIN: Wash with plenty of soap and water P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P321: Specific treatment (see First Aid on this label). Page 1 of 8 10-2006, 88864346 - ACDelco RTV Engine Sealant P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER/Doctor/Medical Professional P314: Get medical advice/attention if you feel unwell. Disposal: P501: Dispose of contents/container to appropriate waste facility according to local regulations EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Gray paste IMMEDIATE CONCERNS: Causes irritation or damage to eyes POTENTIAL HEALTH EFFECTS EYES: Direct contact may cause slight irritation with redness and swelling. SKIN: Repeated or prolonged contact with skin may cause slight irritation leading to dermatitis. Product contains oximes which are possible skin sensitizers. SKIN ABSORPTION: Remove product from skin. INGESTION: Small amounts should not cause injury. Swallowing large amounts may cause slight injury. INHALATION: Overexposure to vapors may cause drowsiness may cause drowsiness, blood and liver injury, and may irritate eyes, nose and throat. CARCINOGENICITY: Suspected of causing cancer. [MEKO]. The following materials (Crystalline silica, Titanium oxide, Carbon Black) are embedded (bound) in the product and not available as respiratory dusts. When used as intended or as supplied, the product will not pose hazards. ROUTES OF ENTRY: Eyes, skin, inhalation, ingestion or absorption SENSITIZATION: Sensitization possible through skin contact. HEALTH HAZARDS: Coughing. Dematitis. Rash. Upper respiratory tract irritation. Servere eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause an allergic skin reaction. COMMENTS: Methyl ethyl ketoxime (MEKO) is formed upon contact with water or humid air. Male rodents exposed to MEKO vapor throughout their lifetime developed liver cancer. Additional testing is being planned by the MEKO supplier to determine any relevance to humans. Until more data is known, exposure levels should be maintained as low as achievable. Also, this product contains crystalline silica, fumed silica, titanium dioxide, calcium carbonate which are considered a hazard by inhalation with dust. Crystalline silica is classified as an agent which is a probable carcinogen in humans. But, this product does not fall under the dust inhalation hazard or the carcinogen classification since it does not generate dust under normal handling conditions. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% CAS Calcium carbonate 20 - 23 1317-65-3 Crystalline silica 20 - 23 14808-60-7 Silane, dichloromethyl-,reaction products with silica 5 - 6 68611-44-9 2-Butanone, O, O', O''-(ethenylsilylidyne) trioxime 3 - 4 2224-33-1 Titanium dioxide < 1 13463-67-7 Toluene < 0.1 108-88-3 COMMENTS: Methyl ethyl ketoxime (MEKO #96-29-7): a decomposition product ACDelco Engine Sealant Page 2 of 8 4. FIRST AID MEASURES EYES: Immediately flush with water for 15 minutes. SKIN: Remove from skin and immediately flush with water for 15 minutes. Get medical attention if irritation or ill effects develop. INGESTION: Immediately rinse mouth well with water and seek medical treatment. INHALATION: Remove to fresh air. Get medical attention if ill effects occur. SIGNS AND SYMPTOMS OF OVEREXPOSURE EYES: Severe eye irritation. Symptoms may instinging, tearing, redness, sweeling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. SKIN: May cause an allergic skin reaction. INGESTION: Expected to be a low ingestion hazard. INHALATION: No adverse effects due to inhalation are expected. ACUTE TOXICITY: No data as a product CHRONIC EFFECTS: Oximes may cause skin sensitization. Overexposure to vapors may cause drowsiness, blood and liver injury, and may irritate eyes, nose, and throat. NOTES TO PHYSICIAN: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. COMMENTS: After first aid, get appropriate in-plant, paramedic, or community medical support. 5. FIRE FIGHTING MEASURES FLAMMABLE CLASS: Combustible solid GENERAL HAZARD: By heating and fire, harmful vapors/gases may be formed. Nitrogen oxides. (corrosive) EXTINGUISHING MEDIA: Use carbon dioxide, dry chemical powder, foam or water fog. OTHER CONSIDERATIONS: By heating and fire, harmful vapors/gases may be formed. Nitrogen oxides. (corrosive) FIRE FIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. FIRE FIGHTING EQUIPMENT: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode/flame retardant coat/helmet/gloves/rubber boots. FIRE EXPLOSION: No unsual fire or explosion hazards noted HAZARDOUS DECOMPOSITION PRODUCTS: Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: carbon oxides and traces of incompletely burned carbon compounds, metal oxides, silicon dioxide, nitrogen oxides, and formaldehye. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Absorb with dry sand, soil, sawdust, cloth, etc., then place in a sealable container. LARGE SPILL: Dike and prevent overflow. Guide to a safe place then dispose properly. ENVIRONMENTAL PRECAUTIONS WATER SPILL: Do not allow product to flow into rivers or affect the environment GENERAL PROCEDURES: All ignition sources should be quickly removed (No smoking in the vicinity, prohibit sparks or fire sources) RELEASE NOTES: Keep spilled material from entering storm drains, sewers, or other environmental mediums. ACDelco Engine Sealant Page 3 of 8 SPECIAL PROTECTIVE EQUIPMENT: Wear appropriate personal protection equipment to avoid contact to eyes, skin, and inhalation. COMMENTS: Disposal of clean-up materials may be governmentally regulated. Observe all applicable local, state, and federal waste management regulations. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Take precaution against fire. HANDLING: Avoid contact with eyes and skin. Wear appropriate personal protection. Wash thoroughly after handling. Avoid prolonged exposure. STORAGE: Keep container closed and away from water or moisture STORAGE TEMPERATURE: 0?C Minimum to 30?C Maximum COMMENTS: Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. Do not mix this product with other cleaning agents. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV Chemical Name ppm mg/m3 ppm mg/m3 Calcium carbonate TWA 15T 5R NIC (10) mg/m 3 (total dust) Crystalline silica TWA 0.3 mg/m3 (total dust) 0.025 mg/m3 Respiratory fraction Silane, dichloromethyl-,reaction products with silica TWA mg/m3 (total dust) mg/m3 STEL NotEstablished Not Established 2-Butanone, O, O', O''-(ethenylsilylidyne) trioxime TWA [1] [1] Titanium dioxide TWA ppm (totaldust) 15 T mg/m3 (total dust) ppm 10 Toluene TWA 100 ppm 50 ppm STEL 150 ppm 375 mg/m3 OSHA TABLE COMMENTS: 1. See: Methyl Ethyl Ketoxime (MEKO) data. ACDelco Engine Sealant Page 4 of 8 ENGINEERING CONTROLS: Provide general or local ventilation systems to maintain airborne concentrations below OSHA PELs. Local ventilation is preferred because contaminant dispersion into the work area by controlling it at its source. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Safety glasses. Wear splash goggles if the potential for splashing or spraying exists. SKIN: Wear personal protection aprons, boots, Gloves (impervious) if necessary. Do not work with short sleeve shirts. RESPIRATORY: Respiration protection must be worn whenever the WEL levels have been exceeded. Use filter type A according to EN 14387. PROTECTIVE CLOTHING: Wear solvent resistant or other impervious gloves WORK HYGIENIC PRACTICES: Wash hands before eating, smoking, or using restroom. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Paste ODOR: Oxime APPEARANCE: Gray paste. pH: Not Available PERCENT VOLATILE: Not Applicable FLASHPOINT AND METHOD: > 40?C (104?F) Closed Cup Notes: Does not sustain combustion. AUTOIGNITION TEMPERATURE: Not determined. VAPOR PRESSURE: Negligible (25? C) VAPOR DENSITY: > 1 (Air = 1) BOILING POINT: Not Applicable FREEZING POINT: Not Determined MELTING POINT: Not Determined SOLUBILITY IN WATER: Not soluble EVAPORATION RATE: less than 1 (Butyl acetate=1) DENSITY: Relative Density (at 23 deg C):1.49 SPECIFIC GRAVITY: at 4?C VISCOSITY #1: to 240 Pa?s at 23?C (VOC): < 2.500 % EPA Method 24, Weight Loss Determination 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIZATION: Polymerization will not occur STABILITY: Stable at room temperature in closed containers under normal storage and handling conditions. CONDITIONS TO AVOID: Contact with water or moisture until ready for use POSSIBILITY OF HAZARDOUS REACTIONS: Contact with water, moisture, or humid air causes curing and MEKO vapors to form gradually. HAZARDOUS DECOMPOSITION PRODUCTS: Water, moisture, or humid air can cause Methyl ethyl ketoxime. ACDelco Engine Sealant Page 5 of 8 Thermal breakdown of this product during fire or very high heat condition may evolve the following hazardous decomposition product: Carbon oxides and traces of incompletely burned carbon compounds. Silicone dioxide, Nitrogen, Formaldehyde. INCOMPATIBLE MATERIALS: Strong oxidizing agents. Water, moisure 11. TOXICOLOGICAL INFORMATION ACUTE Chemical Name ORAL LD50(rat) DERMAL LD50 (rabbit) INHALATION LC50 (rat) Titanium dioxide 6450 rat(mg/kg) Toluene 5580 rat(mg/kg) 12198 Rabbit/mg/kg 12500 to 28800 mg/m3 (rat) DERMAL LD50: > 1000 mg/kg (MEKO) rabbit male and female ORAL LD50: > 900 ml/kg (rat) (MEKO Decomposition product) INHALATION LC50: > 4.83 mg/l (rat)(MEKO decomposition product) EYE EFFECTS: Causes serious eye damage SKIN EFFECTS: Contains material which causes damage to skin. CHRONIC: No data as a product CARCINOGENICITY Chemical Name IARCStatus Titanium dioxide 2B IARC: Overall Evaluation of Carcinogenicity: Carbon black dust (CAS# 1333-86-4) 2B Possibly carginogenic to humans Crystalline silica dust (68611-44-9) 1 Carcinogenic to humans Titanium oxide dust (CAS# 13463-67-7) 2B Possibly carcingenic to humans Toluene (CAS# 108-86-3) 3 Not classified as to carcinogenicity to humans NTP: Crystalline silica dust (CAS# 14808-60-7) Known to be human carcinogenic OSHA: Not Listed REPRODUCTIVE EFFECTS: Not available 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: No information available ECOTOXICOLOGICAL INFORMATION: No information available BIOACCUMULATION/ACCUMULATION: No information available AQUATIC TOXICITY (ACUTE): Titanium oxide (CAS# 13463-67-7) 96-HOUR LC50: > 1000 mg/L (Mummicing) ACDelco Engine Sealant Page 6 of 8 48-HOUR EC50: > 1000 mg/L (Water flea) 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your licensed waste contractor for detailed recommendations. PRODUCT DISPOSAL: ThreeBond1217F-GM is a non-hazardous substance per DOT and EPA EMPTY CONTAINER: All containers should be thoroughly emptied before disposal. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not restricted by DOT OTHER SHIPPING INFORMATION: This product is not intended to be transported in bulk. AIR (ICAO/IATA): Not an IATA controlled material VESSEL (IMO/IMDG): Not an IMDG controlled material. 15. REGULATORY INFORMATION UNITED STATES CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) Chemical Name Wt.% Toluene < 0.1 TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. TSCA STATUS: All ingredients are in compliance with the TSCA OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) 29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: Not Listed ACDelco Engine Sealant Page 7 of 8 STATES WITH SPECIAL REQUIREMENTS Chemical Name Requirements Calcium carbonate This product contains a component or components listed on the Massachusetts Right to Know list of hazardous substances. This product contains a component or components listed on the Pennsylvania Right to Know list of hazardous substances. Titanium dioxide This product contains a component or components listed on the Massachusetts Right to Know list of hazardous substances. This product contains a component or components listed on the Pennsylvania Right to Know list of hazardous substances. Toluene This product contains a component or components listed on the Massachusetts Right to Know list of hazardous substances. This product contains a component or components listed on the Michigan Critical Materials list. This product contains a component or components listed on the New Jersey Right to Know list of hazardous chemicals. This product contains a component or components listed on the Pennsylvania Right to Know list of hazardous substances. CALIFORNIA PROPOSITION 65: WARNING: This product contains chemicals known to the state of California to cause cancer and birth defects or other reproductive harm. Titanium dioxide (bound), Silica (bound), Toluene Chemical Name Wt.% Listed Toluene < 0.1 Developmental Toxicity 16. OTHER INFORMATION Date Prepared: 04/15/2015 HMIS RATING HEALTH * 3 FLAMMABILITY 1 PHYSICAL HAZARD 0 PERSONAL PROTECTION C NFPA CODES 1 3 0 [WR] MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. ACDelco Engine Sealant Page 8 of 8