Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 1/9 1. Product and company identification 1.1 Identification of the substance or preparation: Commercial product name: ELASTOSIL? A 2001 Use of substance / preparation Industrial. Adhesive / sealant 1.2 Company/undertaking identification: Manufacturer/distributor: Wacker Chemical Corporation 3301 Sutton Road Adrian, MI 49221-9397 USA Customer information: InfoLine: Tel (517) 264-8240, Fax (517) 264-8740 Hours of operation: Monday - Friday, 8 am to 5 pm (eastern standard time) Corporate website: www.wacker.com Emergency telephone no. (24h): (517) 264-8500 Transportation emergency: (800) 424-9300 (CHEMTREC, USA) (703) 527-3887 (CHEMTREC, international) This MSDS was prepared by the Regulatory Affairs and Product Safety Department (RAPS) of Wacker Chemical Corporation. 2. Hazards identification 2.1 Classification of the substance or mixture Classification (GHS): Class Category Route of exposure Serious eye damage / eye irritation Category 1 Skin corrosion/irritation Category 2 Acute toxicity Category 4 dermal Acute toxicity Category 4 oral 2.2 Label elements Labelling (GHS): Pictogram(s): Signal Word: Danger H-Code Hazard Statements H302+H312 Harmful if swallowed or in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. 10-2019, 12378478 - ACDelco RTV Silicone Sealant Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 2/9 P-Code Precautionary Statements P103 Read label before use. P101 If medical advice is needed, have product container or label at hand. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P330 Rinse mouth. P331 Do NOT induce vomiting. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container to waste disposal. Hazard ingredients (labelling): Methyl tricyclohexylamino silane Polydimethyl siloxane diol Polydimethyl siloxane Iron oxide Calcium carbonate Magnesium oxide 2.3 Other hazards No data available. 3. Composition/information on ingredients 3.1 Chemical characterization (preparation) Chemical characteristics Polydimethylsiloxane with functional groups and auxiliary 3.2 Information on ingredients: Type CAS No. Substance Content [wt. %] Note Lower Upper INHA 15901-40-3 Methyl tricyclohexylamino silane 6.58 Type: HYD - by-product upon hydrolysis, INHA - ingredient, NEBE - by-product, MONO - residual monomer, VERU - impurity, VUL - by-product upon vulcanization. *** Note: C1 - IARC carcinogen, C2 - NTP carcinogen, C3 - OSHA carcinogen, NH - non- hazardous, R - reproductive toxin. Substances listed in the Subsections "HAPS" and "California Proposition 65 Carcinogens / Reproductive Toxins" that are not listed in this section are only present at quantities below 0.1% for California Proposition 65 listed toxins or below 1% for non- carcinogenic HAPS or they are inextricably bound in the product. 4. First-aid measures 4.1 General information: Get medical attention if irritation or other symptoms occur. Before seeking medical attention remove contaminated clothing and shoes. Take a copy of the Safety Data Sheet when going for medical treatment. 4.2 After inhalation If inhaled curing by-product, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. 4.3 After contact with the skin For skin contact, immediately wipe away excess material. Use a waterless hand cleaner to remove as much of the remaining material as possible. Wash with soap and water. 4.4 After contact with the eyes If contact with eyes, immediately hold eyelids apart and flush with plenty of water for at least 15 min. Continue to bathe eyes during transport to medical practitioner. Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 3/9 4.5 After swallowing For ingestion, if conscious, give several glasses of water but do not induce vomiting. If vomiting does occur, give additional fluids. Get medical attention. Show label if possible. 5. Fire-fighting measures 5.1 Flammable properties: Property: Value: Method: Flash point............................................................... : not applicable Boiling point / boiling range ..................................... : not determined Lower explosion limit (LEL) ..................................... : not applicable Upper explosion limit (UEL)..................................... : not applicable Ignition temperature ................................................ : not determined 5.2 Fire and explosion hazards: Material supports combustion. Ignitable vapors may be released during processing or curing. Consider possible formation of explosive mixtures with air, for example in uncleaned containers by moisture. 5.3 Recommended extinguishing media: water-mist , carbon dioxide , dry chemical or alcohol-resistant foam . 5.4 Unsuitable extinguishing media: sharp water jet . 5.5 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases Hazardous combustion products: Various hydrocarbon fragments , carbon dioxide , formaldehyde , carbon monoxide , silicon dioxide , nitrogen oxides . 5.6 Fire fighting procedures: Fire fighters should wear full protective clothing including a self-contained breathing apparatus. Cool endangered containers with water. 6. Accidental release measures 6.1 Precautions: Wear personal protection equipment (see section 8). Avoid contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate risk of slipping. HAZWOPER PPE Level: C 6.2 Containment: Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response Center's toll free phone number (800) 424-8802. 6.3 Methods for cleaning up Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. 7. Handling and storage 7.1 Handling Precautions for safe handling: Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection). Ensure adequate ventilation. Avoid contact with acids. Spilled substance increases risk of slipping. Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 4/9 Precautions against fire and explosion: Observe the general rules for fire prevention. Cool endangered containers with water. 7.2 Storage Conditions for storage rooms and vessels: none known Advice for storage of incompatible materials: not applicable Further information for storage: Keep container tightly closed and store in a cool, well ventilated place. 8. Exposure controls and personal protection 8.1 Engineering controls Ventilation: Use only with adequate ventilation. Local exhaust: In case of potential decomposition products: Local exhaust ventilation which meets the requirements of ANSI Z9.2 is recommended to control airborne contaminants at the point of use. (to maintain concentration below TLV) 8.2 Associate substances with specific control parameters such as limit values Maximum airborne concentrations at the workplace: CAS No. Material Type mg/m 3 ppm Dust fract. 108-91-8 Cyclohexylamine ACGIH TWA 10.0 8.3 Personal protection equipment (PPE) Respiratory protection: Recommendation in case of long or strong exposure: A NIOSH approved air purifying respirator equipped with universal multi- contaminant multi-gas/vapor cartridges is recommended if overexposure to chemical vapors could occur. If eye-irritating dusts or vapors are present, a full-face respirator should be worn. Hand protection: butyl rubber protective gloves . Eye protection: Safety glasses with side shields. Additional eye and face protection, splash-proof goggles, hood, full-faced respirator, or face shield is recommended if splashing could occur. Other protective clothing or equipment: Any standard or disposable coveralls. Provide eye bath and safety shower. 8.4 General hygiene and protection measures: Avoid breathing dust/vapor/mist/gas/aerosol. Avoid contact with eyes, skin and clothing. When handling do not eat, drink, smoke or apply cosmetics. Wash thoroughly after handling. 9. Physical and chemical properties 9.1 Appearance Physical state / form ................................................ : semi-solid paste Colour ..................................................................... : red Odour ...................................................................... : ammoniacal, fishy 9.2 Safety parameters Property: Value: Method: Melting point / melting range ................................... : not determined Boiling point / boiling range ..................................... : not determined Flash point............................................................... : not applicable Ignition temperature ................................................ : not determined Lower explosion limit (LEL) ..................................... : not applicable Upper explosion limit (UEL)..................................... : not applicable Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 5/9 Vapour pressure ...................................................... : 0.000000 hPa at 20 ?C (68 ?F) (Estimated Value) Density .................................................................... : 1.55 g/cm? Water solubility / miscibility...................................... : insoluble pH-Value ................................................................. : not applicable Viscosity (dynamic) ................................................. : not determined 9.3 Further information Re 9.2 pH Value: Product displays basic reaction with water. Percent Volatiles .................................................... : 3 % VOC ....................................................................... : < 4 g/l (calculated value) VOC Released During Cure ................................... : 87.6 g/l Corrosive to Steel or Aluminum ............................... : Not corrosive to steel or aluminum. 10. Stability and reactivity 10.1 General information: If stored and handled in accordance with standard industrial practices no hazardous reactions are known. 10.2 Conditions to avoid moisture . 10.3 Materials to avoid Reacts with: acids and Water. Reaction causes the formation of: amines . 10.4 Hazardous decomposition products Under the effect of humidity, water and protic agents: amines . Measurements have shown the formation of small amounts of formaldehyde at temperatures above about 150 ?C (302 ?F) through oxidation. . 10.5 Further information: Hazardous polymerization cannot occur. 11. Toxicological information 11.1 Information on toxicological effects 11.1.1 Acute toxicity Assessment: For this endpoint no toxicological test data is available for the whole product. Acute toxicity estimate (ATE): ATE mix (oral): > 10000 mg/kg ATE mix (dermal): > 25000 mg/kg 11.1.2 Skin corrosion/irritation Assessment: Irritation of the skin must be expected. Due to a strong adherence to the skin symptoms of skin corrosion cannot be excluded after removing the substance mechanically. Product details: Result/Effect Species/Test system Source not corrosive Corrositex Conclusion by analogy 11.1.3 Respiratory or skin sensitization Assessment: For this endpoint no toxicological test data is available for the whole product. 11.1.4 Germ cell mutagenicity Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 6/9 Assessment: For this endpoint no toxicological test data is available for the whole product. 11.1.5 Carcinogenicity Assessment: For this endpoint no toxicological test data is available for the whole product. 11.1.6 Reproductive toxicity Assessment: For this endpoint no toxicological test data is available for the whole product. 11.1.7 Specific target organ toxicity (single exposure) Assessment: For this endpoint no toxicological test data is available for the whole product. 11.1.8 Specific target organ toxicity (repeated exposure) Assessment: For this endpoint no toxicological test data is available for the whole product. 11.1.9 Aspiration hazard Assessment: Based on the physical-chemical properties of the product no aspiration hazard must be expected. 11.1.10 Further toxicological information Other information: Hydrolysis product / impurity: Cyclohexylamine (CAS RN 108-91-8) is corrosive to skin and eyes and shows moderate toxic effects after oral administration as well as distinct toxic effects after dermal administration. Exposure to vapour causes irritation of the upper respiratory tract and the eyes. In animal experiments reproductive effects were observed (EU: Repr. 2; H361). 12. Ecological information 12.1 Toxicity Assessment: According to current knowledge adverse effects on water purification plants are not expected. 12.2 Persistence and degradability Assessment: Silicone content: biologically not degradable. Separation by sedimentation. 12.3 Bioaccumulative potential Assessment: Bioaccumulation is not expected to occur. 12.4 Mobility in soil Assessment: Insoluble in water. 12.5 Other adverse effects none known 13. Disposal considerations Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 7/9 13.1 Product disposal Recommendation: Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations. 13.2 Packaging disposal Recommendation: Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations. 14. Transport information 14.1 US DOT & CANADA TDG SURFACE Valuation ................................................ : Not regulated for transport 14.2 Transport by sea IMDG-Code Valuation ................................................ : Not regulated for transport 14.3 Air transport ICAO-TI/IATA-DGR Valuation ................................................ : Not regulated for transport 15. Regulatory information 15.1 U.S. Federal regulations TSCA inventory status and TSCA information: This material or its components are listed on or are in compliance with the requirements of the TSCA Chemical Substance Inventory. TSCA 12(b) Export Notification: This material does not contain any TSCA 12(b) regulated chemicals. CERCLA Regulated Chemicals: This material does not contain any CERCLA regulated chemicals. SARA 302 EHS Chemicals: This material does not contain any SARA extremely hazardous substances. SARA 311/312 Hazard Class: Immediate (acute) health hazard. SARA 313 Chemicals: This material does not contain any SARA 313 chemicals above de minimus levels. HAPS (Hazardous Air Pollutants): CAS No. Chemical Upper limit wt. % 108-88-3 Toluene 0.0675 15.2 U.S. State regulations California Proposition 65 Carcinogens: This material does not contain any chemicals known to the state of California to cause cancer. California Proposition 65 Reproductive Toxins: 108-88-3 Toluene Massachusetts Substance List: 1309-37-1 Iron oxide New Jersey Right-to-Know Hazardous Substance List: 1309-37-1 Iron oxide 1309-48-4 Magnesium oxide Pennsylvania Right-to-Know Hazardous Substance List: 1309-37-1 Iron oxide 1309-48-4 Magnesium oxide Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 8/9 15.3 Canadian regulations This product has been classified in accordance with the Hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS Hazard Classes: D2B DSL Status: This material or its components are listed on the Canadian Domestic Substances List. Non-DSL Chemicals: This material does not contain any non-DSL chemicals. Canadian Ingredient Disclosure List: 1309-37-1 Iron oxide 15.4 Details of international registration status Relevant information about individual substance inventories, where available, is given below. Canada ....................................................... : DSL (Domestic Substance List): This product is listed in, or complies with, the substance inventory. South Korea (Republic of Korea) ................ : ECL (Existing Chemicals List): This product is listed in, or complies with, the substance inventory. Japan .......................................................... : ENCS (Handbook of Existing and New Chemical Substances): This product is listed in, or complies with, the substance inventory. Philippines ................................................... : PICCS (Philippine Inventory of Chemicals and Chemical Substances): This product is listed in, or complies with, the substance inventory. United States of America (USA) .................. : TSCA (Toxic Substance Control Act Chemical Substance Inventory): This product is listed in, or complies with, the substance inventory. People's Republic of China ......................... : IECSC (Inventory of Existing Chemical Substances in China): This product is listed in, or complies with, the substance inventory. European Economic Area (EEA) ................. : REACH (Regulation (EC) No 1907/2006): General note: the registration obligations for substances imported into the EEA or manufactured within the EEA by the supplier mentioned in section 1 are fulfilled by the said supplier. The registration obligations for substances imported into the EEA by customers or other downstream users must be fulfilled by the latter. 16. Other information 16.1 Additional information: This Material Safety Data Sheet (MSDS) meets the requirements of the Federal OSHA Hazard Communication Standard (29 CFR 1910.1200). This product has been classified according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee expressed or implied, is made as to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license under valid patents. This MSDS provides selected regulatory information on this product, including its components. This is not intended to include all regulations. It is the responsibility of the user to know and comply with all applicable rules, regulations and laws relating to the product being used. Vertical lines in the left-hand margin indicate changes compared with the previous version. All deliveries are subject to the WACKER SILICONES Health Care Policy, which is available at www.wacker.com. Material Safety Data Sheet Material: ELASTOSIL? A 2001 Version: 0.0 (US) Date of print: 03/23/2015 Date of last alteration: 00/00/0000 Page: 9/9 16.2 Glossary of Terms: ACGIH - American Conference of Governmental Industrial Hygienists DOT - Department of Transportation hPa - Hectopascals mPa*s - Milli Pascal-Seconds OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limit ppm - Parts per Million SARA - Superfund Amendments and Reauthorization Act STEL - Short Term Exposure Limit TSCA - Toxic Substances Control Act TWA - Time Weighted Average WHMIS - Canadian Workplace Hazardous Materials Identification System Flash point determination methods ........................................ Common name ASTM D56................................................................................... Tagliabue (Tag) closed cup ASTM D92, DIN 51376, ISO 2592 .............................................. Cleveland open cup ASTM D93, DIN 51758, ISO 2719 .............................................. Pensky-Martens closed cup ASTM D3278, DIN 55680, ISO 3679 .......................................... Setaflash or Rapid closed cup DIN 51755 ................................................................................... Abel-Pensky closed cup 16.3 Conversion table: Pressure: .................... : 1 hPa * 0.75 = 1 mm Hg = 1 torr; 1 bar = 1000 hPa Viscosity: .................... : 1 mPa*s = 1 centipoise (cP)