SAFETY DATA SHEET Revision date 30-Jan-2015 Version 5 Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Product Code ACD415.070 Product Name 88862628 11 OZ RUST PENETRANT& INHIBITOR Other means of identification No information available Recommended use of the chemical and restrictions on use Lubricants, greases, release products Details of the supplier of the safety data sheet See section 16 for more information The Valspar Corporation PO Box 1461 Minneapolis, MN 55440 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number United States of America 1-888-345-5732 American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands Chemtel Number Section 2: HAZARDS IDENTIFICATION Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Carcinogenicity Category 2 Aspiration toxicity Category 1 Label elements Product Code ACD415.070 Page 1 / 9 Flammable aerosols Category 2 AGHS - USA OSHA SDS Gases under pressure Liquefied gas 10-4020, 88862628 - ACDelco Rust Penetrant and Inhibitor Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No weight-% Solvent naphtha, petroleum, heavy aromatic 64742-94-5 25 - 50 Diethylene glycol monobutyl ether 112-34-5 10 - 25 Naphthalene 91-20-3 5 - 10 Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 3 - 5 *The exact percentage (concentration) of composition has been withheld as a trade secret. signal word DANGER Hazard Statements flammable aerosol Contains gas under pressure; may explode if heated Causes skin irritation Causes serious eye irritation Suspected of causing cancer May be fatal if swallowed and enters airways Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Keep DZD\?IURP?KHDW?VSDUNV?RSHQ?IODPHV?KRW?VXUIDFHV????1R?VPRNLQJ??'R?QRW?VSUD\?RQ?DQ?RSHQ?IODPH?RU?RWKHU?LJQLWLRQ?VRXUFH? Pressurized container: Do not pierce or burn, even after use. Response IF exposed or concerned: Get medical advice/attention. eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Disposal Dispose of contents/containers in accordance with local regulations. Hazards not otherwise classified (HNOC) Propellant is classified as a simple asphyxiant if released in large quantities: May displace oxygen and cause rapid suffocation. Other hazards Toxic to aquatic life with long lasting effects. Toxic to aquatic life. Product Code ACD415.070 Page 2 / 9 Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity. AGHS - USA OSHA SDS Section 4: FIRST AID MEASURES First Aid Measures General advice IF exposed or concerned: Get medical advice/attention. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Section 5: FIRE FIGHTING MEASURES Suitable extinguishing media Dry chemical, CO2, water spray or alcohol-resistant foam. Not to be used for safety reasons: Never use pointed jet of water Specific hazards arising from the chemical Burning produces heavy smoke. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool closed containers exposed to fire with water. Do not allow run-off from fire-fighting to enter drains or water courses. Section 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid breathing vapors or mists. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Remove all sources of ignition. For emergency responders Use personal protection recommended in Section 8. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods and material for containment and cleaning up Product Code ACD415.070 Page 3 / 9 AGHS - USA OSHA SDS Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Dispose of waste product or used containers according to local regulations. Clean with detergents. Avoid solvent cleaners. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. Section 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Prevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal protection recommended in Section 8. Never use pressure to empty container. Comply with the health and safety at work laws. Prevent product from entering drains. Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Use only with adequate ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. General Hygiene Considerations When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Avoid contact with skin, eyes or clothing. Conditions for safe storage, including any incompatibilities Storage Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Keep container tightly closed in a dry and well-ventilated place. Protect from sunlight. Store in a well-ventilated place. Incompatible materials Strong oxidizing agents. Acids. Aluminum. Copper. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits If this section is blank, no OEL's have been established for the components of this material. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Solvent naphtha, petroleum, heavy aromatic 64742-94-5 - - - Diethylene glycol monobutyl ether 112-34-5 TWA: 10 ppm inhalable fraction and vapor - - Naphthalene 91-20-3 TWA: 10 ppm S* TWA: 10 ppm TWA: 50 mg/m3 IDLH: 250 ppm TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 - - - Legend If S* appears in the OEL table, it indicates this chemical contains a skin notation. Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Product Code ACD415.070 Page 4 / 9 AGHS - USA OSHA SDS Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Personnel should wear anti-static clothing made of natural fiber or of high temperature resistant synthetic fiber. Wear suitable protective clothing. Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Wear protective gloves. Respiratory protection If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Thermal Protection No information available Section 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Aerosol Appearance No information available Odor Solvent Color clear Odor Threshold No information available pH value No information available Melting point/freezing point No information available Boiling point / boiling range No information available ?C / ?F flash point -73 ?C / -99 ?F evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor Pressure No information available vapor density No information available Density (lbs per US gallon) 7.57 specific gravity .91 Solubility(ies) Not Determined Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Other information Section 10: STABILITY AND REACTIVITY Reactivity No information available. Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization None under normal processing. Product Code ACD415.070 Page 5 / 9 AGHS - USA OSHA SDS Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents. Acids. Aluminum. Copper. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Section 11: TOXICOLOGICAL INFORMATION Product Information The product has not been tested Information on likely routes of exposure Eye contact Causes serious eye irritation Skin Contact Causes skin irritation Ingestion May be fatal if swallowed and enters airways Inhalation Not applicable Numerical measures of toxicity - Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Solvent naphtha, petroleum, heavy aromatic 64742-94-5 > 5000 mg/kg ( Rat ) > 2 mL/kg ( Rabbit ) > 590 mg/m3 ( Rat ) 4 h Diethylene glycol monobutyl ether 112-34-5 = 3384 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) - Naphthalene 91-20-3 = 1110 mg/kg ( Rat ) = 1120 mg/kg ( Rabbit ) > 340 mg/m3 ( Rat ) 1 h Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 - - - Delayed and immediate effects as well as chronic effects from short and long-term exposure Numerical measures of toxicity - Product Information Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity. Chemical Name ACGIH IARC NTP OSHA Solvent naphtha, petroleum, heavy aromatic 64742-94-5 - - - - Diethylene glycol monobutyl ether 112-34-5 - - - - Naphthalene 91-20-3 A3 Group 2B Reasonably Anticipated X Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 - - - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen. IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans. NTP (National Toxicology Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen. OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present. Skin corrosion/irritation Causes skin irritation Serious eye damage/eye irritation Causes serious eye irritation Skin sensitization Not applicable Product Code ACD415.070 Page 6 / 9 AGHS - USA OSHA SDS Respiratory sensitization Not applicable Germ cell mutagenicity Not applicable Carcinogenicity Suspected of causing cancer Reproductive Toxicity Not applicable Specific target organ toxicity (single exposure) Not applicable Specific target organ toxicity (repeated exposure) Not applicable Aspiration hazard May be fatal if swallowed and enters airways Section 12: ECOLOGICAL INFORMATION Ecotoxicity The product has not been tested Toxic to aquatic life with long lasting effects. Environmental precautions Prevent product from entering drains. Marine pollutant This material meets the definition of a marine pollutant Persistence and degradability No information available Bioaccumulation No information available Mobility No information available Other adverse effects No information available Section 13: DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned. Section 14: TRANSPORT INFORMATION 14.5 Environmental hazard Yes Marine pollutant This material meets the definition of a marine pollutant Marine pollutant Solvent naphtha, petroleum, heavy aromatic , Naphthalene 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available Section 15: REGULATORY INFORMATION International Inventories DOT IMDG IATA 14.1 UN/ID no ORM-D UN1950 UN1950 14.2 Proper shipping name consumer commodity Aerosols Aerosols 14.3 Hazard Class 2.1 2.1 14.4 Packing Group 14.6 Special Provisions Product Code ACD415.070 Page 7 / 9 Emergency Response Guide Number 126 AGHS - USA OSHA SDS EmS-No F-D, S-U TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt from listing DSL - Canadian Domestic Substances List All components are listed or exempt from listing US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Diethylene glycol monobutyl ether - 112-34-5 1 Naphthalene - 91-20-3 0.1 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard Yes Reactive Hazard No Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Naphthalene 91-20-3 100 lb X X X Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Naphthalene 91-20-3 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ US State Regulations California Proposition 65 WARNING! This product contains a chemical known in the State of California to cause cancer Chemical Name California Proposition 65 Naphthalene - 91-20-3 Carcinogen U.S. EPA Label information EPA Pesticide registration number Not applicable U.S. State Right-to-Know Regulations SAFETY DATA SHEET Chemical Name . Solvent naphtha, petroleum, heavy aromatic 64742-94-5 . Proprietary non-hazardous Ingredient - Proprietary CAS . Diethylene glycol monobutyl ether 112-34-5 . Proprietary non-hazardous Ingredient - Proprietary CAS . Naphthalene 91-20-3 . Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 . Propane 74-98-6 . Butane 106-97-8 . Product Code ACD415.070 Page 8 / 9 AGHS - USA OSHA SDS Chemical Name . Solvent naphtha, petroleum, heavy aromatic 64742-94-5 . Water 7732-18-5 . Diethylene glycol monobutyl ether 112-34-5 . Oleic acid 112-80-1 . Naphthalene 91-20-3 . Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 . Propane 74-98-6 . Butane 106-97-8 . Section 16: OTHER INFORMATION HMIS Health hazards 3* Flammability 4 Physical hazards 0 Personal Protection X Supplier Address Prepared By Product Stewardship Revision date 30-Jan-2015 Revision Note Product Code ACD415.070 No information available Disclaimer The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Page 9 / 9 End of Safety Data Sheet AGHS - USA OSHA SDS Valspar Coatings 5400 Avenue Of The Cities Moline, IL 61265 309-762-7546