SAFETY DATA SHEET 10-4066, 88861426 - ACDelco Multi-Purpose Synthetic Lubricant Synxtreme HD-2, Synxtreme HD-1, Synxtreme HD-0 GHS product identifier Other means of identification Product type Synxtreme HD-2, Synxtreme HD-1, Synxtreme HD-0 Not available. Solid. Relevant identified uses of the substance or mixture and uses advised against Product use Synthetic lubricating grease Area of application Industrial applications. Supplier/Manufacturer LUBRIPLATE? Lubricants Co. 129 Lockwood St. Newark, NJ 07105 Telephone no.: 1-973-589-9150 e-mail address of person responsible for this SDS This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number (with hours of operation) CHEM-TEL 1-800-255-3924 (24 hour) OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture EYE IRRITATION - Category 2B Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 100% GHS label elements Signal word Warning Hazard statements Causes eye irritation. Precautionary statements Prevention Wear eye or face protection. Wash hands thoroughly after handling. Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage Not applicable. Disposal Not applicable. Hazards not otherwise classified None known. Section 2. Hazards identification Section 1. Identification Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 1111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 3. Composition/information on ingredients Substance/mixture Other means of identification Mixture Not available. CAS number/other identifiers CAS number Not applicable. Product code Not available. Ingredient name Other names % CAS number zinc oxide zinc oxide 10-30 1314-13-2 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Description of necessary first aid measures Eye contact Inhalation Skin contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. If irritation persists, get medical attention. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Causes eye irritation. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion May be irritating to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact Adverse symptoms may include the following: irritation watering redness Inhalation No specific data. Section 4. First aid measures Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 2111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 4. First aid measures Skin contact Ingestion No specific data. No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. Do not use water jet. Specific hazards arising from the chemical Hazardous thermal decomposition products No specific fire or explosion hazard. Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides sulfur oxides Special protective actions for fire-fighters Special protective equipment for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Personal precautions, protective equipment and emergency procedures For non-emergency personnel No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Section 6. Accidental release measures Section 5. Fire-fighting measures Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 3111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 6. Accidental release measures Large spill Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Control parameters Occupational exposure limits Ingredient name Exposure limits zinc oxide NIOSH REL (United States, 10/2013). CEIL: 15 mg/m3 Form: Dust TWA: 5 mg/m3 10 hours. Form: Dust and fumes STEL: 10 mg/m3 15 minutes. Form: Fume OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m3 8 hours. Form: Fume STEL: 10 mg/m3 15 minutes. Form: Fume TWA: 5 mg/m3 8 hours. Form: Respirable fraction TWA: 10 mg/m3 8 hours. Form: Total dust OSHA PEL (United States, 2/2013). TWA: 5 mg/m3 8 hours. Form: Fume TWA: 5 mg/m3 8 hours. Form: Respirable fraction TWA: 15 mg/m3 8 hours. Form: Total dust ACGIH TLV (United States, 4/2014). TWA: 2 mg/m3 8 hours. Form: Respirable fraction STEL: 10 mg/m3 15 minutes. Form: Respirable fraction Appropriate engineering controls Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Section 8. Exposure controls/personal protection Section 7. Handling and storage Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 4111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 8. Exposure controls/personal protection Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Appearance Physical state Color Odor Odor threshold pH Melting point Solid. Tan. Mineral oil. Not available. Not available. Not available. Boiling point >288?C (>550.4?F) Flash point Evaporation rate Open cup: 180 to 232?C (356 to 449.6?F) <0.01 (butyl acetate = 1) Flammability (solid, gas) Not available. Lower and upper explosive (flammable) limits Lower: 0.9% Upper: 7% Vapor pressure Vapor density Relative density Solubility Not available. Not available. 0.96 Insoluble in the following materials: cold water and hot water. Section 9. Physical and chemical properties Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 5111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 9. Physical and chemical properties Solubility in water Not available. Partition coefficient n- octanol/water Auto-ignition temperature Not available. Not available. Decomposition temperature Not available. SADT Viscosity Not available. Not available. Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical stability The product is stable. Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions to avoid No specific data. Incompatible materials Reactive or incompatible with the following materials: oxidizing materials. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 - milligrams Skin - Mild irritant Rabbit - 24 hours 500 - milligrams Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Section 11. Toxicological information Section 10. Stability and reactivity Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 6111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 11. Toxicological information Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure Potential acute health effects Routes of entry anticipated: Oral, Dermal, Inhalation. Eye contact Causes eye irritation. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion May be irritating to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following: irritation watering redness Inhalation Skin contact Ingestion No specific data. No specific data. No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Not available. Potential delayed effects Not available. Long term exposure Potential immediate effects Not available. Potential delayed effects Not available. Potential chronic health effects Not available. General Carcinogenicity Mutagenicity Teratogenicity No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 7111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 12. Ecological information Toxicity Product/ingredient name Result Species Exposure zinc oxide Acute EC50 0.042 mg/l Fresh water Algae - Pseudokirchneriella 72 hours subcapitata - Exponential growth phase Acute LC50 98 ?g/l Fresh water Daphnia - Daphnia magna - 48 hours Neonate Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours Chronic NOEC 0.017 mg/l Fresh water Algae - Pseudokirchneriella 72 hours subcapitata - Exponential growth phase Persistence and degradability Not available. Bioaccumulative potential Product/ingredient name LogPow BCF Potential zinc oxide - 60960 high Mobility in soil Soil/water partition coefficient (KOC) Not available. Other adverse effects No known significant effects or critical hazards. Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information DOT Classification IMDG IATA UN number Not regulated. UN3077 UN3077 UN proper shipping name - ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc oxide). Marine pollutant (zinc oxide) Environmentally hazardous substance, solid, n.o.s. (zinc oxide) Section 13. Disposal considerations Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 8111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 14. Transport information Transport hazard class(es) - 9 9 Packing group - III III Environmental hazards No. Yes. Yes. Additional information - The marine pollutant mark is not required when transported in sizes of s;5 L or s;5 kg. Emergency schedules (EmS) F-A, S-F Special provisions 274, 335, 966, 967, 969 The environmentally hazardous substance mark is not required when transported in sizes of s;5 L or s;5 kg. Passenger and Cargo Aircraft Quantity limitation: 400 kg Packaging instructions: 956 Cargo Aircraft OnlyQuantity limitation: 400 kg Packaging instructions: 956 Limited Quantities - Passenger AircraftQuantity limitation: 30 kg Packaging instructions: Y956 Special provisions A97, A158, A179, A197 Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Transport within user's premises always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Not available. U.S. Federal regulations TSCA 8(a) PAIR: naphthalene United States inventory (TSCA 8b): Not determined. Clean Water Act (CWA) 307: naphthalene; zinc oxide Clean Water Act (CWA) 311: naphthalene; benzoic acid Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 Not listed Not listed Not listed Not listed Not listed Section 15. Regulatory information Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 9111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 15. Regulatory information Composition/information on ingredients No products were found. SARA 304 RQ Not applicable. SARA 311/312 Classification Immediate (acute) health hazard Composition/information on ingredients Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard zinc oxide 10-30 No. No. No. Yes. No. SARA 313 Product name CAS number % Form R - Reporting requirements zinc oxide 1314-13-2 10-30 Supplier notification zinc oxide 1314-13-2 10-30 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. State regulations Massachusetts The following components are listed: ZINC OXIDE FUME New York None of the components are listed. New Jersey The following components are listed: ZINC OXIDE Pennsylvania The following components are listed: ZINC OXIDE (ZNO) California Prop. 65 WARNING This product contains less than 0.1% of a chemical known to the State of California to cause cancer. None of the components are listed. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level naphthalene Yes. No. Yes. No. Hazardous Material Information System (U.S.A.) Health * 1 Flammability 1 Physical hazards 0 Caution HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Section 16. Other information Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 10111 Synxtreme H0-2, Synxtreme H0-1, Synxtreme H0-0 Section 16. Other information Health 1 Flammability 1 0 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue/Date of revision Date of previous issue Version Prepared by 03/05/2015 No previous validation 1 IHS Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations References HCS (U.S.A.)- Hazard Communication Standard International transport regulations Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue!Date of revision 0310512015 Date of previous issue : No previous validation Version : 1 11111 GHS product identifier e-mail address of person responsible for this SDS Emergency telephone number (with hours of operation) Classification of the substance or mixture GHS label elements Precautionary statements Hazards not otherwise classified Substance/mixture CAS number/other identifiers There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Ingestion Most important symptoms/effects, acute and delayed Potential acute health effects Ingestion Over-exposure signs/symptoms Inhalation Skin contact Ingestion Indication of immediate medical attention and special treatment needed, if necessary See toxicological information (Section 11) Specific hazards arising from the chemical Special protective actions for fire-fighters Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Large spill Precautions for safe handling Protective measures Control parameters Occupational exposure limits Environmental exposure controls Individual protection measures Hygiene measures Eye/face protection Respiratory protection Appearance Physical state Color Flash point Evaporation rate Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Partition coefficient n- octanol/water SADT Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Information on toxicological effects Acute toxicity Irritation/Corrosion Mutagenicity Carcinogenicity Reproductive toxicity Teratogenicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Information on the likely routes of exposure Eye contact Ingestion Inhalation Skin contact Ingestion Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Long term exposure Potential chronic health effects General Numerical measures of toxicity Acute toxicity estimates Toxicity Bioaccumulative potential Disposal methods Special precautions for user U.S. Federal regulations Clean Air Act Section 112 Composition/information on ingredients SARA 311/312 Composition/information on ingredients State regulations Hazardous Material Information System (U.S.A.) Health Indicates information that has changed from previously issued version.