AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Product code : ACAB53 (GM # 88865164, AC Delco # 10-5049) [1 Gallon] 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Automotive Engine Antifreeze & Coolant 1.3. Details of the supplier of the safety data sheet Old World Industries, LLC 4065 Commercial Ave. Northbrook, IL 60062 - USA T (847) 559-2000 www.oldworldind.com 1.4. Emergency telephone number Emergency number : (800) 424-9300; (703) 527 3887 (International) Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Acute Tox. 4 (Oral) H302 STOT RE 2 H373 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H302 - Harmful if swallowed H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure (oral) Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe mist, spray, vapors P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear personal protective equipment as required P301+P310 - If swallowed: Immediately call doctor/physician or poison center P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available 01/28/2015 EN (English) Page 1 10-5049, 88865164 -ACDelco Classic Coolant Prediluted 50/50 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % by wt GHS-US classification ethylene glycol (CAS No) 107-21-1 <= 50 Acute Tox. 4 (Oral), H302 water (CAS No) 7732-18-5 < 50 Not classified diethylene glycol (CAS No) 111-46-6 < 3 Acute Tox. 4 (Oral), H302 STOT RE 2, H373 denatonium benzoate (CAS No) 3734-33-6 30 -50 ppm Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Seek immediate medical advice. Allow the victim to rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. First-aid measures after skin contact : Remove contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Rinse immediately with plenty of water (for at least 15 minutes). Get medical advice/attention. Specific treatment (see supplemental first aid instructions on this label). First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse immediately with plenty of water for 15 minutes, lifting lower and upper lids. If eye irritation persists: Rinse immediately with plenty of water. Get medical advice/attention. First-aid measures after ingestion : Obtain emergency medical attention. Rinse mouth. If the person is fully conscious, make him/her drink two glasses of water. Never give an unconscious person anything to drink. Do NOT induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whiskey. For children, give proportionally less liquor, according to weight. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes damage to organs (kidneys) (oral). Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. The lethal dose in humans is estimated to be 100 mL (3 oz). 4.3. Indication of any immediate medical attention and special treatment needed A more effective intravenous antidote for physician uses is 4-methylpyrazaole, a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occured. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water fog. Fine water spray. Alcohol-resistant foam. Foam. Carbon dioxide. Dry chemical powder. Sand. Dry powder. Unsuitable extinguishing media : Do not use a heavy water stream. May spread fire. 5.2. Special hazards arising from the substance or mixture Fire hazard : During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide. Reactivity : No dangerous reactions known under normal conditions of use. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. 01/28/2015 EN (English) 2/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Special protective equipment for fire fighters : Wear positive pressure self-contained breathing apparatus (SCBA). Protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Refer to section 8.2. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. Product may become solid at temperatures below -37 ?C (-34 ?F). Do not store near food, foodstuffs, drugs or potable water supplies. Do not cut, drill, weld, use a blowtorch on, etc. containers even when empty. Incompatible products : Keep away from strong acids, strong bases and oxidizing agents. Incompatible materials : Sources of ignition. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters ethylene glycol (107-21-1) USA ACGIH ACGIH Ceiling (mg/m?) 100.00 mg/m? USA ACGIH Remark (ACGIH) Upper Respiratory Tract (URT) & Eye irritant 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Gloves. Safety glasses. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : If exposed to levels above exposure limits wear appropriate respiratory protection. Other information : Do not eat, drink or smoke during use. 01/28/2015 EN (English) 3/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Green Odor : Mild Odor threshold : No data available pH : 10.5 - 11 Relative evaporation rate (butylacetate=1) : Nil Freezing point : -37 ?C (-34 ?F) Boiling point : 106 - 108 ?C (224 - 227 ?F) Flash point : 116 ?C (241 ?F) [100% Ethylene Glycol] ASTM D56 Auto-ignition temperature : 400 ?C (752 ?F) [100% Ethylene Glycol] Literature Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.1 mm Hg @ 20 ?C Relative vapor density at 20 ?C : < 2.1 Specific Gravity : 1.07 Density : 1.06 kg/l (8.9 lbs/gal) Solubility : Water: Complete Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 0.00 % SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Keep away from any flames or sparking source. Extremely high or low temperatures. 10.5. Incompatible materials Keep away from strong acids, strong bases and oxidizing agents. 10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide. Fume. Alcohols. Aldehydes. Ethers. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. denatonium benzoate (3734-33-6) LD50 oral rat 584 mg/kg (Rat) LD50 dermal rabbit > 2,000 mg/kg (Rabbit) 01/28/2015 EN (English) 4/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations denatonium benzoate (3734-33-6) ATE US (oral) 584 mg/kg bodyweight ethylene glycol (107-21-1) LD50 oral rat > 5,000 mg/kg (Rat) ATE US (oral) 500 mg/kg bodyweight diethylene glycol (111-46-6) LD50 oral rat 12,565 mg/kg (Rat) LD50 dermal rabbit 11,890 mg/kg (Rabbit) ATE US (oral) 500 mg/kg bodyweight ATE US (dermal) 11,890 mg/kg bodyweight Skin corrosion/irritation : Not classified pH: 10.5 - 11 Serious eye damage/irritation : Not classified pH: 10.5 - 11 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : May cause damage to organs (kidneys) through prolonged or repeated exposure (oral). Aspiration hazard : Not classified Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Harmful if swallowed. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. The lethal dose in humans is estimated to be 100 mL (3 oz). SECTION 12: Ecological information 12.1. Toxicity denatonium benzoate (3734-33-6) LC50 fish 1 > 1,000 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 13 mg/l (48 h; Daphnia magna) ethylene glycol (107-21-1) LC50 fish 1 53,000 mg/l (96 h; Pimephales promelas; Static system) EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna) LC50 fish 2 40,761 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Static system) Threshold limit algae 1 > 10,000 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 2,000 mg/l (192 h; Microcystis aeruginosa) diethylene glycol (111-46-6) LC50 fish 1 > 5,000 ppm (24 h; Carassius auratus) LC50 other aquatic organisms 1 1,174 mg/l (Xenopus laevis) EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna) LC50 fish 2 61,072 ppm (168 h; Poecilia reticulata) TLM fish 1 > 32,000 mg/l (96 h; Gambusia affinis) TLM other aquatic organisms 1 > 1,000 ppm (96 h) Threshold limit other aquatic organisms 1 1,174 mg/l (72 h; Xenopus laevis; Toxicity test) Threshold limit other aquatic organisms 2 10,745 mg/l (16 h; Protozoa; Toxicity test) Threshold limit algae 1 2,700 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 100 mg/l (Selenastrum capricornutum) 12.2. Persistence and degradability 01/28/2015 EN (English) 5/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations denatonium benzoate (3734-33-6) Persistence and degradability Biodegradability in water: no data available. No (test) data on mobility of the substance available. ethylene glycol (107-21-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established. Biochemical oxygen demand (BOD) 0.47 g O2/g substance Chemical oxygen demand (COD) 1.24 g O2/g substance ThOD 1.29 g O2/g substance BOD (% of ThOD) 0.36 % ThOD diethylene glycol (111-46-6) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Biochemical oxygen demand (BOD) 0.02 g O2/g substance Chemical oxygen demand (COD) 1.51 g O2/g substance ThOD 1.51 g O2/g substance BOD (% of ThOD) 0.015 % ThOD 12.3. Bioaccumulative potential denatonium benzoate (3734-33-6) Log Pow 1.78 (Estimated value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). ethylene glycol (107-21-1) BCF fish 1 10 (72 h; Leuciscus idus) BCF other aquatic organisms 1 0.21 - 0.6 (Procambarus sp.; Chronic) BCF other aquatic organisms 2 190 (24 h; Algae) Log Pow -1.34 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. diethylene glycol (111-46-6) Log Pow -1.98 Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil ethylene glycol (107-21-1) Surface tension 0.048 N/m (20 ?C / 68 ?F) diethylene glycol (111-46-6) Surface tension 0.0485 N/m 12.5. Other adverse effects Effect on ozone layer : No known effect on the ozone layer Effect on global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Transport document description : UN3082 Environmentally hazardous substances, liquid, n.o.s., 9, III UN-No.(DOT) : 3082 DOT NA no. : UN3082 Proper Shipping Name (DOT) : Environmentally hazardous substances, liquid, n.o.s. 01/28/2015 EN (English) 6/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Department of Transportation (DOT) Hazard Classes : 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140 Hazard labels (DOT) : 9 - Class 9 (Miscellaneous dangerous materials) DOT Symbols : G - Identifies PSN requiring a technical name Packing group (DOT) : III - Minor Danger DOT Packaging Exceptions (49 CFR 173.xxx) : 155 DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 DOT Packaging Bulk (49 CFR 173.xxx) : 241 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : No limit DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : No limit DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. Other information : Non Bulk: Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package). ADR No additional information available Transport by sea UN-No. (IMDG) : Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package) Air transport UN-No.(IATA) : Not regulated by IATA (in quantities under 5,000 lbs in any one inner package) SECTION 15: Regulatory information 15.1. US Federal regulations AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant EPA TSCA Regulatory Flag Toxic Substances Control Act (TSCA): The intentional ingredients of this product are listed ethylene glycol (107-21-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) 5,000 lb(s) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Ethylene glycol is subject to Tier 1 and/or Tier II annual inventory reporting. SARA Section 313 - Emission Reporting Ethylene glycol is subject to Form R Reporting requirements. 15.2. International regulations CANADA WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects 01/28/2015 EN (English) 7/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant DSL (Canada): The intentional ingredients of this product are listed ECL (South Korea): The intentional ingredients of this product are listed. EINECS (Europe): The intentional ingredients of this product are listed ENCS (Japan): The intentional ingredients of this product are listed 15.3. US State regulations AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No denatonium benzoate (3734-33-6) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No ethylene glycol (107-21-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No diethylene glycol (111-46-6) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No water (7732-18-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No ethylene glycol (107-21-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information 01/28/2015 EN (English) 8/9 AC Delco Classic Coolant Green 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Full text of H-phrases ------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 ------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------ Skin Irrit. 2 Skin corrosion/irritation, Category 2 ------ STOT RE 2 Specific target organ toxicity ? Repeated exposure, Category 2 ------ STOT SE 3 Specific target organ toxicity ? Single exposure, Category 3, Respiratory tract irritation ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H335 May cause respiratory irritation ------ H373 May cause damage to organs through prolonged or repeated exposure NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS GHS US (GHS HazCom 2012) OWI Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. 01/28/2015 EN (English) 9/9