11/04/2014Revision: 01/16/2015Printed: Page: 1 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: FD GHS 101693Product Code: WHITEWALL TIRE CLEANERProduct Name: Excelda ManufacturingCompany Name: 12785 Emerson Dr. Brighton, MI 48116 MEDICAL EMERGENCYEmergency Contact: (888)314-4052 DOT EMERGENCY (800)424-9300 INFORMATIONInformation: (248)486-3800 (248)486-3800 Phone Number: Automotive Cleaning or PolishingIntended Use: Synonyms: 1. PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION P280: Wear protective gloves/protective clothing/eye protection/face protection. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P264: Wash hands and skin thoroughly after handling. P362+364: Take off contaminated clothing and wash it before reuse. GHS Precaution Phrases: P370+378: In case of fire, use CO2, dry chemical or alcohol resistant foam to extinguish. P302+352: IF ON SKIN: Wash with plenty of soap and water. P321: Specific treatment see first aid section on the product cotainerlabel. P332+313: If skin irritation occurs, get medical advice/attention. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER/doctor. GHS Response Phrases: P403+235: Store in cool/well-ventilated place. P501: Dispose of contents/container to licensed disposal facility. GHS Storage and Disposal Phrases: H227: Combustible liquid. H315: Causes skin irritation. H318: Causes serious eye damage. GHS Hazard Phrases: Flammable Liquids, Category 4 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 1 Danger Because of its irritating properties, repeated skin contact may aggravate an existingMedical Conditions Generally EYES: Can cause severe eye irritation or chemical burns. SKIN: Frequent or prolonged contact may irritate the skin and cause a skin rash (dermatitis). INGESTION: May cause burns, ulceration or, in extreme cases, perforation. INHALATION: Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations generated from spraying, heating the material or as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, drowsiness, cough, discomfort or difficulty in breathing. Potential Health Effects (Acute and Chronic): Licensed to Excelda Manufacturing, Inc. GHS format 10-8034, 1050175 - ACDelco White Sidewall Tire Cleaner 11/04/2014Revision: 01/16/2015Printed: Page: 2 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: dermatitis.Aggravated By Exposure: CAS # Chemical Name 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration RTECS # Molecular Formula 7732-18-5 Water 90.0 -92.0 % ZC0110000 H2O 6834-92-0 Silicic acid (H2SiO3), Disodium salt 2.0 -4.0 % VV9275000 Na2O3Si 7758-29-4 Sodium phosphate, Tribasic 2.0 -4.0 % YK4570000 Na5O10P3 127087-87-0 Poly(oxy-1,2-ethanediyl),.alpha.-(4-nonylphenyl)- .omega.-hydroxy-,branched 2.0 -4.0 % RB2451000 C9H19C6H4(OCH2CH2)9OH 67-63-0 Isopropyl alcohol 2.0 -4.0 % NT8050000 (CH3)2CHOH 34590-94-8 Propanol, (2-Methoxymethylethoxy)- 0.5 -0.75 % JM1575000 CH3OC3H6OC3H6OH 25322-68-3 Polyethylene glycol 0.0 -0.1 % TQ3500000 H(OCH2CH2)nOH 9014-93-1 Dinonylphenyl polyoxyethylene 0.05 -0.075 % NA (C2H4O)nC24H42O 7785-84-4 Sodium phosphate, tribasic 0.0 -0.05 % OY4025000 H3O9P3.3Na 7722-88-5 Diphosphoric acid, Tetrasodium salt 0.0 -0.05 % UX7350000 Na4O7P2 14233-37-5 1,4-Bis(isopropylamino)anthraquinone 0.0 -0.001 % NA C20H22N2O2 75-21-8 Ethylene oxide < 0.75 PPM KX2450000 C2H4O 123-91-1 1,4-Dioxane < 0.5 PPM JG8225000 C4H8O2 4. FIRST AID MEASURES EYES: Flush eye with water for 15 minutes. Get medical attention. SKIN: Wash with soap and water. Get medical attention if irritation develops or persists. INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of water. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. INHALATION: If inhaled, remove from exposure. Emergency and First Aid Procedures: EYES: Irritation, redness, and/or burning sensation. SKIN: Irritation, redness, itching, and/or discomfort. INHALATION: Irritation, cough, discomfort, drowsiness, or difficulty in breathing. INGESTION: Irritation, burning sensation, or other discomfort of the mouth, throat and stomach. Signs and Symptoms Of Exposure: Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 3 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: 5. FIRE FIGHTING MEASURES Flash Pt: 144.00 F (62.2 C) Method Used: Pensky-Marten Closed Cup As with all fires involving chemicals, responders should wear full bunker gear including a self-contained breathing apparatus. Cool containers to keep them from bursting, and remove from high heat areas if possible. Do not direct a solid stream of water at pools of released liquid that are burning since it may cause spattering of the burning liquid. Fire Fighting Instructions: Material contains flammable ingredients which may cause an ignitable mixture with air at or above the flash point of the material. Flammable Properties and Hazards: Autoignition Pt: N.D. Explosive Limits: LEL: N.D. UEL: N.D. Dry Chemicals, CO2 or Alcohol Resistant Foam. Water spray may be used to keep containers cool. Suitable Extinguishing Media: Water jet.Unsuitable Extinguishing Media: 6. ACCIDENTAL RELEASE MEASURES Ventilate the area. Contain and use non-sparking equipment to collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal. Steps To Be Taken In Case Material Is Released Or Spilled: Use protective equipment as specified in Section 8 of this SDS.Protective Precautions, Protective Equipment and Emergency Procedures: Prevent product from discharging into sewers, drains, waterways, or the environment.Environmental Precautions: 7. HANDLING AND STORAGE Do not get in eyes, on skin or clothing. Avoid prolonged or repeated contact with skin. Use in ventilated area. Do not use on, or near, sources of heat, sparks or open flame. Precautions To Be Taken in Handling: Store containers in cool well ventilated area away from sources of heat, sparks, open flame, or direct sunlight. Keep away from incompatible materials including strong acids and oxidizing agents. Precautions To Be Taken in Storing: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data. No data. 7732-18-5 Water No data. No data. No data. 6834-92-0 Silicic acid (H2SiO3), Disodium salt No data. No data. No data. 7758-29-4 Sodium phosphate, Tribasic No data. No data. No data. 127087-87-0 Poly(oxy-1,2-ethanediyl),.alpha.-(4-non ylphenyl)-.omega.-hydroxy-,branched No data. PEL: 400 ppm TLV: 200 ppm STEL: 400 ppm 67-63-0 Isopropyl alcohol No data. PEL: 100 ppm TLV: 100 ppm STEL: 150 ppm 34590-94-8 Propanol, (2-Methoxymethylethoxy)- No data. No data. No data. 25322-68-3 Polyethylene glycol No data. No data. No data. 9014-93-1 Dinonylphenyl polyoxyethylene No data. No data. No data. 7785-84-4 Sodium phosphate, tribasic No data. No data. TLV: 5 mg/m3 7722-88-5 Diphosphoric acid, Tetrasodium salt No data. No data. No data. 14233-37-5 1,4-Bis(isopropylamino)anthraquinone No data. Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 4 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: PEL: 1 ppm STEL: 5 ppm (15 min) TLV: 1 ppm 75-21-8 Ethylene oxide No data. PEL: 100 ppm TLV: 20 ppm 123-91-1 1,4-Dioxane No data. None expected to be required during normal usage. In extreme conditions where mists, or vapors are generated in high quantities or if used in confined spaces a NIOSH/OSHA approved respirator may be required. Respiratory Equipment (Specify Type): Safety glasses, chemical safety goggles. A face shield in conjunction with safety goggles is recommended to prevent eye contact when mists, vapors, or spray are generated. Eye Protection: Rubber, neoprene or other chemical resistant gloves.Protective Gloves: Sufficient to prevent skin contact.Other Protective Clothing: General ventilation is sufficient for normal usage. If used in a confined space or in such manner as generates excessive mists or vapors, local ventilation may need to be provided to maintain air concentration levels below the OSHA permitted amounts. Engineering Controls (Ventilation etc.): Do not smoke while using. Wash hands after use. Remove clothing if it becomes wetted from liquid and may come in contact with eyes or skin. Launder clothes before reuse. Use good personal hygiene at all times. Work/Hygienic/Maintenance Practices: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: N.D. Boiling Point: N.D. Decomposition Temperature: N.D. Autoignition Pt: N.D. Flash Pt: 144.00 F (62.2 C) Method Used: Pensky-Marten Closed Cup Explosive Limits: LEL: N.D. UEL: N.D. Specific Gravity (Water = 1): 1.01 - 1.03 at 25.0 C (77.0 F) Clear blue liquid alcoholic odor.Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): NA Vapor Density (vs. Air = 1): NA Evaporation Rate: NA Solubility in Water: complete at 25.0 C (77.0 F) Percent Volatile: N.D. VOC / Volume: < 3.0000 WT% Viscosity: NA Octanol/Water Partition Coefficient: Not Avail. pH: 11.5 - 13.0 10. STABILITY AND REACTIVITY Heat, sparks, open flameConditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong acids and oxidizing agents.Incompatibility - Materials To Avoid: Oxides of carbonHazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 5 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: None known.Conditions To Avoid - Hazardous Reactions: 11. TOXICOLOGICAL INFORMATION Expected routes of entry include: Eye and skin contact Inhalation This product may cause: Eye damage Chemical burns or severe irritation to skin Toxicological Information: EYES: Irritation, redness, and/or burning sensation. Symptoms related to Toxicological Characteristics: CAS# 6834-92-0: Silicic acid (H2SiO3), Disodium salt: Acute toxicity, LD50, Oral, Rat, 1153. MG/KG. Result: Gastrointestinal:Ulceration or bleeding from stomach. Gastrointestinal:Ulceration or bleeding from duodenum. Gastrointestinal:Ulceration or bleeding from small intestine. - Toxicology Letters., Elsevier Science Pub. B.V., POB 211, 1000 AE, Amsterdam 1000 AE Netherlands, Vol/p/yr: 31(Suppl),, 1986 Standard Draize Test, Skin, Species: Rabbit, 250.0 MG, 24 H, Severe. Result: Lungs, Thorax, or Respiration:Other changes. - Toxicology and Applied Pharmacology, Academic Press, Inc., 1 E. First St., Duluth, MN 55802, Vol/p/yr: 31,481, 1975 CAS# 67-63-0: Isopropyl alcohol: Standard Draize Test, Eyes, Species: Rabbit, 100.0 MG, Severe. Result: Lungs, Thorax, or Respiration:Structural or functional change in trachea or bronchi. Lungs, Thorax, or Respiration:Acute pulmonary edema. - American Journal of Ophthalmology., Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611, Vol/p/yr: 29,1363, 1946 CAS# 7722-88-5: Diphosphoric acid, Tetrasodium salt: Acute toxicity, LD50, Oral, Rat, 4.000 GM/KG. Result: Kidney, Ureter, Bladder: Changes in liver weight. Blood:Other hemolysis with or withot anemia. Blood:Changes in spleen. - Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag,, Vol/p/yr: 7,172, 1957 Acute toxicity, LD (Lethal dose), Skin, Species: Rabbit, 300.0 MG/KG. Result: Behavioral: Convulsions or effect on seizure threshold. Behavioral: Muscle weakness. Related to Chronic Data - death. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,47, 1990 Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 6 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: CAS # Chemical Name NTP EYES: Can cause severe eye irritation or chemical burns. SKIN: Frequent or prolonged contact may irritate the skin and cause a skin rash (dermatitis). INGESTION: May cause burns, ulceration or, in extreme cases, perforation. INHALATION: Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations generated from spraying, heating the material or as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, drowsiness, cough, discomfort or difficulty in breathing. Chronic Toxicological Effects: This product does not contain any OSHA carcinogens at a level greater than 0.1%.Carcinogenicity/Other Information: IARC ACGIH OSHA SKIN: Irritation, redness, itching, and/or discomfort. INHALATION: Irritation, cough, discomfort, drowsiness, or difficulty in breathing. INGESTION: Irritation, burning sensation, or other discomfort of the mouth, throat and stomach. This product may contain trace amounts of substances known to be skin sensitizers. At the levels of the substance is present, this product is not expected to result in any sensitization in the general population. Sensitization: 7732-18-5 Water n.a. n.a. n.a. n.a. 6834-92-0 Silicic acid (H2SiO3), Disodium salt n.a. n.a. n.a. n.a. 7758-29-4 Sodium phosphate, Tribasic n.a. n.a. n.a. n.a. 127087-87-0 Poly(oxy-1,2-ethanediyl),.alpha.-(4-nonylphenyl)-.omega.-h ydroxy-,branched n.a. n.a. n.a. n.a. 67-63-0 Isopropyl alcohol n.a. 3 A4 n.a. 34590-94-8 Propanol, (2-Methoxymethylethoxy)- n.a. n.a. n.a. n.a. 25322-68-3 Polyethylene glycol n.a. n.a. n.a. n.a. 9014-93-1 Dinonylphenyl polyoxyethylene n.a. n.a. n.a. n.a. 7785-84-4 Sodium phosphate, tribasic n.a. n.a. n.a. n.a. 7722-88-5 Diphosphoric acid, Tetrasodium salt n.a. n.a. n.a. n.a. 14233-37-5 1,4-Bis(isopropylamino)anthraquinone n.a. n.a. n.a. n.a. 75-21-8 Ethylene oxide Known 1 A2 Yes 123-91-1 1,4-Dioxane Possible 2B A3 n.a. The exotoxicity of this product as a whole has not been determined. It does contain up to 3% nonylphenyl compounds. General Ecological Information: 12. ECOLOGICAL INFORMATION Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 7 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: Due to the allowable pH tolerances of this product, this product may have a pH greater than 12.5, and as such be a RCRA characteristic based hazardous waste. It is the duty of the user of this product to determine if this product is hazardous at the time of disposal. All notification, clean up and disposal should be carried out in accordance with federal, state and local regulations. Preferred methods of waste disposal are incineration or biological treatment in federal/state approved facility. Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Corrosive liquid, n.o.s. (sodium metasilicate)DOT Proper Shipping Name: 8 CORROSIVEDOT Hazard Class: UN1760UN/NA Number: IIIPacking Group: LAND TRANSPORT (US DOT): ADR/RID Shipping Name: LAND TRANSPORT (European ADR/RID): 1760UN Number: IIIPacking Group: 8 - CORROSIVEHazard Class: DOT Hazard determination may be reclassed according to 49 CFR 173.154. While this product may contain up to 3% nonylphenyl compounds, it is not considered a Marine Pollutant under 49 CFR 171.8. Note: The information provided in Section 14 is based on the rules and regulations governing the shipment of non-bulk containers and may not apply when using bulk packaging to ship this material. Additional Transport Information: CAS # Chemical Name 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 7732-18-5 Water No No No 6834-92-0 Silicic acid (H2SiO3), Disodium salt No No No 7758-29-4 Sodium phosphate, Tribasic No Yes 5000 LB No 127087-87-0 Poly(oxy-1,2-ethanediyl),.alpha.-(4-nonylphenyl)- .omega.-hydroxy-,branched No No No 67-63-0 Isopropyl alcohol No No Yes 34590-94-8 Propanol, (2-Methoxymethylethoxy)- No No No 25322-68-3 Polyethylene glycol No No No 9014-93-1 Dinonylphenyl polyoxyethylene No No No 7785-84-4 Sodium phosphate, tribasic No Yes 5000 LB No 7722-88-5 Diphosphoric acid, Tetrasodium salt No No No 14233-37-5 1,4-Bis(isopropylamino)anthraquinone No No No 75-21-8 Ethylene oxide Yes 1000 LB Yes 10 LB Yes 123-91-1 1,4-Dioxane No Yes 100 LB Yes [X] Yes [ ] No Acute (immediate) Health Hazard [ ] Yes [X] No Chronic (delayed) Health Hazard This material meets the EPA 'Hazard Categories' defined Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 8 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: [X] Yes [ ] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard for SARA Title III Sections 311/312 as indicated: CAS # Chemical Name Other US EPA or State Lists 7732-18-5 Water CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 6834-92-0 Silicic acid (H2SiO3), Disodium salt CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 7758-29-4 Sodium phosphate, Tribasic CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 127087-87-0 Poly(oxy-1,2-ethanediyl),.alpha.-(4-nonylphenyl)- .omega.-hydroxy-,branched CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory, 8A PAIR; CA PROP.65: No 67-63-0 Isopropyl alcohol CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test; CA PROP.65: No 34590-94-8 Propanol, (2-Methoxymethylethoxy)- CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory, 4 Test, 8A PAIR; CA PROP.65: No 25322-68-3 Polyethylene glycol CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 9014-93-1 Dinonylphenyl polyoxyethylene CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 7785-84-4 Sodium phosphate, tribasic CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 7722-88-5 Diphosphoric acid, Tetrasodium salt CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 14233-37-5 1,4-Bis(isopropylamino)anthraquinone CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 75-21-8 Ethylene oxide CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: Yes 123-91-1 1,4-Dioxane CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Yes - Inventory, 8A CAIR; CA PROP.65: Yes TSCA: All ingredients in this product are listed on the TSCA Inventory or are otherwise exempt. CA Prop 65: This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Regulatory Information: The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes all risk in use of the material. Regulatory Information Statement: Licensed to Excelda Manufacturing, Inc. GHS format 11/04/2014Revision: 01/16/2015Printed: Page: 9 WHITEWALL TIRE CLEANER SAFETY DATA SHEET 10/24/2007Supersedes Revision: 16. OTHER INFORMATION As the ingredient information provided in this MSDS is considered confidential by Excelda Manufacturing, this entire MSDS is considered confidential by Excelda Manufacturing. This MSDS is being provided per one or more agreements between Excelda Manufacturing and the recipient and may be used solely in conjuction with the terms and conditions of such agreemenrt(s). Any distribution, release, disclosure or use of this information beyond that listed here is prohibited by Excelda Manufacturing, except as required by law. Additional Information About This Product: THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA MANUFACTURING. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. EXCELDA MANUFACTURING ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS DATA. Company Policy or Disclaimer: 11/04/2014Revision Date: Compliance Department 248-486-3800Preparer Name: Licensed to Excelda Manufacturing, Inc. GHS format