SAFETY DATA SHEET 1. Identification Product identifier Aquapel? Glass Treatment Other means of identification SDS number 01-M Product code 47100, 47101, 47102, 47103, 98990A, 98994, 98989A, 98991A, 98990FR, 98994FR, 94525, 47103, 47104, 47100 Recommended use Rain/water repellant treatment for glass surfaces. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Telephone General Assistance (8-5 M-F): +1-800-861-4999 Pittsburgh, PA 15212 US Pittsburgh Glass Works LLC. Address Emergency phone number USA +1-760-476-3962 Europe, Middle East, Africa +1-760-476-3961 Asia Pacific +1-760-476-3960 Access code 333225 Suite 500 30 Isabella Street Company name US E-mail This email address is being protected from spambots. You need JavaScript enabled to view it. Contact person - 2. Hazard(s) identification Not classified.Physical hazards Category 2Skin corrosion/irritationHealth hazards Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Causes skin irritation. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects. Precautionary statement Prevention Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing mist or vapor. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 1 / 7 10-8070, 88864552 - ACDelco Rain Repellent Treatment Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures 64742-47-8 60-100Distillates (petroleum), hydrotreated light CAS number %Chemical name Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration or give oxygen by trained personnel. Skin contact Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Use soap if available. Get medical attention if irritation develops or persists. Wash clothing separately before reuse. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids wide apart. Get medical attention if any discomfort continues. Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth thoroughly. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison control center. Most important symptoms/effects, acute and delayed Vapors may cause nausea, headache and/or dizziness. Symptoms include itching, burning, redness, and tearing of eyes. Prolonged or repeated contact may dry skin and cause irritation. Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after exposure. Indication of immediate medical attention and special treatment needed Treat symptomatically. General information Keep victim warm. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Foam. Dry powder. Carbon dioxide (CO2). Water Spray or Fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Use water spray to cool unopened containers. Move containers from fire area if you can do so without risk. General fire hazards This product is not flammable or combustible. Will burn if involved in a fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. Keep out of low areas. Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 2 / 7 Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. Environmental precautions Do not contaminate water. 7. Handling and storage Precautions for safe handling Wear protective clothing as described in Section 8 of this safety data sheet. Avoid breathing mists or vapors. Avoid contact with skin and eyes. Do not taste or swallow. Do not eat, drink or smoke when using the product. Use only with adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wash thoroughly after handling. Eliminate all sources of ignition. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in a well-ventilated place. Store in a cool place. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Store in accordance with local/regional/national/international regulation. Keep only in the original container in a cool, well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep away from food, drink and animal feedingstuffs. Do not store in open or unlabelled containers. Keep out of the reach of children. Protect from direct sunlight. 8. Exposure controls/personal protection Occupational exposure limits US. NIOSH: Pocket Guide to Chemical Hazards ValueTypeComponents TWA 100 mg/m3Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Use explosion-proof equipment. Provide adequate general and local exhaust ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable. Suitable gloves can be recommended by the glove supplier. Other Wear suitable protective clothing. Full body suit and boots are recommended when handling large volumes or in emergency situations. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Use a NIOSH/MSHA approved air purifying respirator as needed to control exposure. Consult with respirator manufacturer to determine respirator selection, use, and limitations. Use positive pressure, air-supplied respirator for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respirator use. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Do not get in eyes. Avoid contact with skin. Do not get this material on clothing. When using, do not eat, drink or smoke. Keep away from food and drink. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 3 / 7 Physical state Liquid. Form Liquid. Color Colorless. Odor Hydrocarbon-like. Odor threshold Not available. pH Not available. Melting point/freezing point -106.6 ?F (-77 ?C) Initial boiling point and boiling range 424.4 - 494.6 ?F (218 - 257 ?C) Flash point > 201.2 ?F (> 94.0 ?C) Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.6 Flammability limit - upper (%) 4.9 Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 0.791 @ 15.6 ?C (60.08 ?F) Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) No data available. Auto-ignition temperature > 392 ?F (> 200 ?C) Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity Reactivity The product is stable and non reactive under normal conditions of storage and transport. Chemical stability Stable at normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Contact with incompatible materials. Avoid high temperatures. Protect against direct sunlight. Incompatible materials Strong oxidizers, strong acids, and strong bases. Hazardous decomposition products Carbon oxides. Hydrogen chloride. 11. Toxicological information Information on likely routes of exposure Inhalation Vapors may irritate throat and respiratory system and cause coughing. In high concentrations, vapors are narcotic and may cause headache, fatigue, dizziness and nausea. Skin contact Causes skin irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion May be fatal if swallowed and enters airways. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Vapors may cause drowsiness and dizziness. Symptoms include itching, burning, redness, and tearing of eyes. Be aware that symptoms of chemical pneumonia (shortness of breath) may occur several hours after exposure. Information on toxicological effects Acute toxicity Vapors may cause drowsiness and dizziness. Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 4 / 7 Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Based on available data, the classification criteria are not met. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Contains no ingredient listed as toxic to reproduction. Specific target organ toxicity - single exposure May cause drowsiness or dizziness. Specific target organ toxicity - repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Organic solvents may be absorbed into the body by inhalation and cause permanent damage to the nervous system, including the brain. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue) and/or damage. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Persistence and degradability The product is not expected to be readily biodegradable. Bioaccumulative potential No data available. Mobility in soil No data available. Mobility in general The product is insoluble in water. The product contains organic solvents which will evaporate easily from all surfaces. Other adverse effects The product contains a substance which has a photochemical ozone creation potential. 13. Disposal considerations Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations. Hazardous waste code Not regulated. Waste from residues / unused products Dispose of in accordance with local regulations. Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near this container. 14. Transport information DOT UN3082UN number Environmentally hazardous substances, liquid, n.o.s. (DISTILLATES (PETROLEUM), HYDROTREATED LIGHT) UN proper shipping name 9Class Transport hazard class(es) -Subsidiary risk 9Label(s) IIIPacking group YesMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 8, 146, 173, 335, IB3, T4, TP1, TP29Special provisions 155Packaging exceptions 203Packaging non bulk 241Packaging bulk Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 5 / 7 IATA UN3082UN number Environmentally hazardous substance, liquid, n.o.s. (DISTILLATES (PETROLEUM), HYDROTREATED LIGHT) UN proper shipping name 9Class Transport hazard class(es) -Subsidiary risk 9Label(s) IIIPacking group YesEnvironmental hazards 9LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IMDG UN3082UN number ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DISTILLATES (PETROLEUM), HYDROTREATED LIGHT) UN proper shipping name 9Class Transport hazard class(es) -Subsidiary risk 9Label(s) IIIPacking group YesMarine pollutant Environmental hazards F-A, S-FEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user This substance/mixture is not intended to be transported in bulk.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code General information The product is eligible for Limited Quantity exemption because its unit size meets the relevant thresholds. It may be eligible for Excepted Quantity exemption, dependant on quantity of units within the outer package. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical Yes SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 6 / 7 Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List Distillates (petroleum), hydrotreated light (CAS 64742-47-8) US. New Jersey Worker and Community Right-to-Know Act Distillates (petroleum), hydrotreated light (CAS 64742-47-8) US. Pennsylvania Worker and Community Right-to-Know Law Distillates (petroleum), hydrotreated light (CAS 64742-47-8) US. Rhode Island RTK Not regulated. US. California Proposition 65 Not Listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australian Inventory of Chemical Substances (AICS) NoAustralia Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) YesJapan Existing Chemicals List (ECL) NoKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances (PICCS) NoPhilippines *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico 16. Other information, including date of preparation or last revision Issue date 06-February-2015 Revision date - Version # 01 Further information HMIS? is a registered trade and service mark of the NPCA. G - Safety Glasses, Gloves, Vapor Respirator HMIS? ratings Health: 2 Flammability: 1 Physical hazard: 0 Personal protection: G NFPA ratings 02 1 References ACGIH Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PGW, and to recommend precautionary measures for the storage and handling of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Aquapel? Glass Treatment SDS US 5257 Version #: 01 Revision date: - Issue date: 06-February-2015 7 / 7