SAFETY DATA SHEET Regulation (EC) No 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version 1 Issue Date 14-Nov-2014 Product Name Jincool? HFC-134a Revision date 14- Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 1 / 7 SECTION 1: Identification of the substance /mixture and of the company/undertaking 1.1. Product identifier Product Name Jincool? HFC-134a CAS No 811-97-2 EC No 212-377-0 REACH registration number 01-2119459374-33-0006 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Refrigerant Foaming agent Aerosol Uses advised against No information available 1.3. Details of the supplier of the safety data sheet Only representative REACH24H CONSULTING GROUP Address Suite 1E, Paramount Court, Corrig Road, Sandyford, Dublin 18, Ireland E-mail This email address is being protected from spambots. You need JavaScript enabled to view it. Supplier Sinochem Environmental Protection Chemicals (Taicang) Co., Ltd Address No.18, Binjiang Road, Shihua Park, Taicang, Jiangsu, PR of China Postal Code 215433 Phone +86-0512-53713136 FAX +86-0512-53713177 E-mail This email address is being protected from spambots. You need JavaScript enabled to view it. Importer Address Postal Code Phone FAX E-mail 1.4. Emergency telephone number +86-0512-53713126, +86-0512-53713105 (Only office hours available.) +86-0512-53713125 (outside office hours) 24-hour Emergency telephone:+86-13306223219 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Gases under pressure Liquefied gas - (H280) Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 2.2. Label elements 15-119, 12356150, 10-9097, 88863968 - ACDelco Refrigerant - 134a Product Name Jincool? HFC-134a Revision date 14-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 7 Symbols/Pictograms Signal word Warning Hazard Statements Not applicable H280 - Contains gas under pressure; may explode if heated Precautionary Statements P410 + P403 - Protect from sunlight. Store in a well-ventilated place 2.3. Other hazards No information available SECTION 3: Composition/information on ingredients 3.1 Substances Chemical Name EC No CAS No Weight-% Classification according to Directive 67/548/EEC or 1999/45/EC Classification according to Regulation (EC) No. 1272/2008 [CLP] 1,1,1,2-Tetrafluoroethane 212-377-0 811-97-2 ?99.5 Not classified Liq. Gas (H280) SECTION 4: First aid measures 4.1. Description of first aid measures General advice In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin Contact Wash with plenty of water. Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts with lukewarm water. If skin irritation persists, call a physician. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Not an expected route of exposure. Do NOT induce vomiting. Rinse mouth. Get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms may include tightness in the chest, flushing, headache, nausea, vomiting, respiratory depression, weakness, irregular heartbeat, abdominal pain, convulsions, and shock 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media No information available. Product Name Jincool? HFC-134a Revision date 14-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 7 5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to release of toxic/corrosive gases and vapors. Hydrogen fluoride. 5.3. Advice for firefighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation, especially in confined areas. Remove all sources of ignition. Do not touch damaged packages or spilled material. Stop leak if you can do it without risk. 6.2. Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. 6.3. Methods and material for containment and cleaning up Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. 6.4. Reference to other sections See Section 7 for more information See section 8 for more information See section 13 for more information SECTION 7: Handling and storage 7.1. Precautions for safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation, especially in confined areas. Remove all sources of ignition. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. 7.2. Conditions for safe storage, including any incompatibilities Protect from sunlight. Store in a well-ventilated place. Keep cool. 7.3. Specific end use(s) Apart from the uses mentioned in SECTION 1.2 no other specific uses are stipulated. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Chemical Name Austria United Kingdom Switzerland Spain Germany 1,1,1,2-Tetrafluoroethane 811-97-2 STEL 4000 ppm STEL 16800 mg/m3 TWA: 1000 ppm TWA: 4200 mg/m3 TWA: 1000 ppm TWA: 4200 mg/m3 TWA: 1000 ppm TWA: 4200 mg/m3 - STEL 8000 ppm STEL 33600 mg/m3 TWA: 1000 ppm TWA: 4200 mg/m3 Derived No Effect Level (DNEL) Inhalation Worker - inhalative, long-term - systemic Consumer - inhalative, long-term - systemic 13936 mg/m? mg/m? Product Name Jincool? HFC-134a Revision date 14-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 7 Predicted No Effect Concentration (PNEC) Fresh Water 0.1 mg/L Sea Water 0.01 mg/L Freshwater sediment 0.75 mg/kg sediment dw Impact on Sewage Treatment 73 mg/L 8.2. Exposure controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) Hand Protection Wear protective gloves Skin and body protection Suitable protective clothing Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Liquefied gas Color colorless Odor Slight Odor Threshold No information available pH 7.0 Melting point/freezing point -101 - 103?C at 1013 hPa Boiling point / boiling range -26.1?C at 1013 hPa Flash point No information available Evaporation rate CL4 = 1 (Greater than 1) Flammability (solid, gas) Not flammable Flammability Limit in Air Not flammable Vapor Pressure 5.74 Bar Vapor density 3.52 (25?C air=1) Density 1.21 g/cm? (25?C-liquid density) Relative density No information available Bulk density No information available Specific gravity No information available Water solubility 1 g/L (25?C pH=7) Partition coefficient Log Pow = 1.06 (25?C) Autoignition temperature >743?C (1atm) Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties Not an explosive Oxidizing properties Not applicable 9.2. Other information No information available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under recommended storage conditions. Product Name Jincool? HFC-134a Revision date 14-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 7 10.2. Chemical stability Stable under normal conditions. Hazardous polymerization does not occur. 10.3. Possibility of hazardous reactions None under normal processing. 10.4. Conditions to avoid Extremes of temperature and direct sunlight. Heat, flames and sparks. 10.5. Incompatible materials Alkali metal alloys. Finely powdered metals. 10.6. Hazardous decomposition products Thermal decomposition can lead to release of toxic/corrosive gases and vapors. Hydrogen fluoride. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 1,1,1,2-Tetrafluoroethane - - 1500000 mg/m3/4h (Rat) Skin corrosion/irritation Non-irritating to the skin. Serious eye damage/eye irritation No eye irritation. Sensitization No sensitization responses were observed. Germ cell mutagenicity Not classified. Carcinogenicity Not classified Reproductive toxicity Not classified. STOT - single exposure Not classified. STOT - repeated exposure Not classified. Aspiration hazard Not classified. SECTION 12: Ecological information 12.1. Toxicity Chemical Name Algae/aquatic plants EC50 Fish LC50 Crustacea EC50 1,1,1,2-Tetrafluoroethane 142 mg/L/96h (green algae)(weight of evidence) 450 mg/L/96h (Oncorhynchus mykiss) 980 mg/L/48h (Daphnia magna) 12.2. Persistence and degradability Not readily biodegradable. Product Name Jincool? HFC-134a Revision date 14-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 7 12.3. Bioaccumulative potential Material does not bioaccumulate. 12.4. Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). 12.6. Other adverse effects No information available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste from residues/unused products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal. SECTION 14: Transport information 14.1 UN Number UN 3159 14.2 Proper shipping name 1,1,1,2-Tetrafluoroethane 14.3 Hazard Class 2.2 14.4 Packing Group Not applicable 14.5 Environmental hazards Not applicable 14.6 Special precautions No information available 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture European Union Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Take note of Directive 94/33/EC on the protection of young people at work Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work International Inventories Component TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS 1,1,1,2-Tetrafluoroet hane 811-97-2 ( 99.5 ) X X X X X X X X "-" Not Listed "X" Listed 15.2. Chemical safety assessment A Chemical Safety Assessment has been carried out for this substance Product Name Jincool? HFC-134a Revision date 14-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 7 SECTION 16: Other information This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Issue Date 13-Mar-2014 Revision date 13-Mar-2014 Revision Note Not applicable Key or legend to abbreviations and acronyms used in the safety data sheet TWA - TWA (time-weighted average) STEL - STEL (Short Term Exposure Limit) Ceiling - Maximum limit value TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances Full text of H-Statements referred to under section 3 H280 - Contains gas under pressure; may explode if heated Full text of R-phrases referred to under sections 2 and 3 Not classified Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. -------- End of Safety Data Sheet --------