JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 10/23/2014 : Version: 05/11/2014 EN (English US) 1/13 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Product code : 2415C 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Brake Parts Cleaner 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 2 H225 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Repr. 2 H361 STOT SE 1 H370 STOT SE 3 H336 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H370 - Causes damage to organs Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat,sparks,open flames,hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, ventilating, lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe dust,fumes,gas,mist,vapor spray P261 - Avoid breathing dust,fume,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves,protective clothing,eye protection,face protection P302+P352 - If on skin: Wash with plenty of soap and water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P307+P311 - If exposed: Call a poison center/doctor JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 2/13 P308+P313 - If exposed or concerned: Get medical advice/attention P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. P321 - Specific treatment: See section 4.1 on SDS P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P370+P378 - In case of fire: See Section 5.1 Extinguishing Media P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. 2.4. Unknown acute toxicity (GHS-US) 6.6 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral) 6.6 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal) SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Acetone (CAS No) 67-64-1 85 - 95 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Heptane, Branched Cyclic (CAS No) 426260-76-6 6.336 - 6.6 Flam. Liq. 1, H224 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 Methanol (CAS No) 67-56-1 1 - 5 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:dust,mist), H331 STOT SE 1, H370 Heptane (CAS No) 142-82-5 1.65 - 2.97 Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Toluene (CAS No) 108-88-3 0.066 - 0.264 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician. First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Fatal if swallowed. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/injuries after inhalation : Coughing. Irritation of the respiratory tract. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Itching. Red skin. Causes skin irritation. Skin rash/inflammation. JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 3/13 Symptoms/injuries after eye contact : Redness of the eye tissue. Inflammation/damage of the eye tissue. Irritation of the eye tissue. Causes serious eye irritation. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. Obtain special instructions . Do not handle until all safety precautions have been read and understood. Do not breathe dust,fumes,gas,mist,vapor spray. Hygiene measures : Wash contaminated clothing before reuse. Wash affected areas thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 4/13 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 1 ppm USA ACGIH ACGIH STEL (ppm) 5 ppm USA ACGIH ACGIH Ceiling (ppm) 25 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 5 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (mg/m?) 75 mg/m? USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Heptane (142-82-5) USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm Heptane, Branched Cyclic (426260-76-6) USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Methanol (67-56-1) USA ACGIH ACGIH TWA (mg/m?) 262 mg/m? USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (mg/m?) 328 mg/m? USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 260 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm Acetone (67-64-1) USA ACGIH ACGIH TWA (mg/m?) 1188 mg/m? USA ACGIH ACGIH TWA (ppm) 500 ppm USA ACGIH ACGIH STEL (mg/m?) 1782 mg/m? USA ACGIH ACGIH STEL (ppm) 750 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 2400 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 5/13 Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Colourless to light yellow. Odor : Acetone odour. Solvent-like odour. Odor threshold : No data available pH : 7 Relative evaporation rate (butyl acetate=1) : 6 Relative evaporation rate (ether=1) : 2 Melting point : No data available Freezing point : No data available Boiling point : 56 ?C (Lowest Component) Flash point : -18 ?C (Lowest Component) Critical temperature : 235 ?C (Lowest Component) Auto-ignition temperature : 465 ?C (Lowest Component) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.78 Solubility : Poorly soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 10 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 6/13 Benzene (71-43-2) LD50 oral rat > 930 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; > 2000 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 8240 mg/kg (Rabbit; Experimental value; 21 CFR 191.10; > 9.4; Rabbit) LC50 inhalation rat (mg/l) 43.767 mg/l/4h (Rat; Experimental value) LC50 inhalation rat (ppm) 13700 ppm/4h (Rat; Experimental value) Toluene (108-88-3) LD50 oral rat 5580 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Literature study; 5580 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 5000 mg/kg body weight LD50 quoted as 14.1 mL/kg (12267 mg/kg using density of 0.87) LC50 inhalation rat (mg/l) > 28.1 mg/l/4h (Rat; Air, Literature study) Heptane (142-82-5) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) Heptane, Branched Cyclic (426260-76-6) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) Methanol (67-56-1) LD50 oral rat >= 2528 mg/kg body weight application as 50% aqueous solution LD50 dermal rabbit 17100 mg/kg corresponding to 20 ml/kg bw according to the authors LC50 inhalation rat (mg/l) 128.2 mg/l/4h Air Acetone (67-64-1) LD50 oral rat 5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rabbit 20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402) LC50 inhalation rat (mg/l) 71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value) LC50 inhalation rat (ppm) 30000 ppm/4h (Rat; Experimental value) Skin corrosion/irritation : Causes skin irritation. pH: 7 Serious eye damage/irritation : Causes serious eye irritation. pH: 7 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Benzene (71-43-2) IARC group 1 Toluene (108-88-3) IARC group 3 Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Causes damage to organs. May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Coughing. Irritation of the respiratory tract. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Itching. Red skin. Causes skin irritation. Skin rash/inflammation. JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 7/13 Symptoms/injuries after eye contact : Redness of the eye tissue. Inflammation/damage of the eye tissue. Irritation of the eye tissue. Causes serious eye irritation. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity Benzene (71-43-2) LC50 fish 1 5.3 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 18 mg/l (24 h; Daphnia magna) EC50 other aquatic organisms 1 29 mg/l (72 h; Selenastrum capricornutum) LC50 fish 2 15.1 mg/l (96 h; Pimephales promelas) EC50 Daphnia 2 10 mg/l (48 h; Daphnia magna) TLM fish 1 22.5 mg/l (96 h; Lepomis macrochirus; Soft water) TLM fish 2 32 mg/l (96 h; Pimephales promelas; Hard water) TLM other aquatic organisms 1 10 - 100,96 h Threshold limit algae 2 50 mg/l (24 h; Phaeodactylum; Photosynthesis) Toluene (108-88-3) LC50 fish 1 24 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 84 mg/l (24 h; Daphnia magna; Locomotor effect) LC50 fish 2 13 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 2 11.5 - 19.6 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 400 mg/l (168 h; Scenedesmus quadricauda; Toxicity test) Threshold limit algae 2 105 mg/l (192 h; Microcystis aeruginosa) Heptane (142-82-5) LC50 fish 1 375 mg/l (96 h; Tilapia mosambica; Nominal concentration) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) EC50 Daphnia 1 1.5 mg/l (48 h; Daphnia magna) LC50 fish 2 > 100 mg/l (96 h; Oncorhynchus kisutch) TLM fish 1 4924 mg/l (48 h; Gambusia affinis) Threshold limit other aquatic organisms 1 > 1000 mg/l (96 h) Threshold limit algae 1 > 200 mg/l (Scenedesmus quadricauda; Toxicity test) Threshold limit algae 2 1.5 mg/l (8 h; Algae; Photosynthesis) Acetone (67-64-1) TLM fish 1 13000 ppm (96 h; Gambusia affinis; Turbulent water) TLM fish 2 > 1000 ppm (96 h; Pisces) Threshold limit other aquatic organisms 1 3000 mg/l (Plankton) Threshold limit other aquatic organisms 2 28 mg/l (Protozoa) Threshold limit algae 1 7500 mg/l (Scenedesmus quadricauda; pH = 7) Threshold limit algae 2 3400 mg/l (48 h; Chlorella sp.) Methanol (67-56-1) LC50 fish 1 15400 mg/l (96 h; Lepomis macrochirus; Lethal) EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna; Lethal) LC50 fish 2 10800 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 2 24500 mg/l (48 h; Daphnia magna) Threshold limit other aquatic organisms 1 6600 mg/l (16 h; Pseudomonas putida) Threshold limit algae 1 530 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 8000 mg/l (168 h; Scenedesmus quadricauda) Acetone (67-64-1) LC50 fish 1 6210 mg/l (96 h; Pimephales promelas; Nominal concentration) EC50 Daphnia 1 8800 mg/l (48 h; Daphnia pulex) LC50 fish 2 5540 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) TLM fish 1 13000 ppm (96 h; Gambusia affinis; Turbulent water) TLM fish 2 > 1000 ppm (96 h; Pisces) Threshold limit other aquatic organisms 1 3000 mg/l (Plankton) Threshold limit other aquatic organisms 2 28 mg/l (Protozoa) Threshold limit algae 1 7500 mg/l (Scenedesmus quadricauda; pH = 7) JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 8/13 Acetone (67-64-1) Threshold limit algae 2 3400 mg/l (48 h; Chlorella sp.) 12.2. Persistence and degradability JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Persistence and degradability Not established. Benzene (71-43-2) Persistence and degradability Biodegradable in water. Ozonation in water. Forming sediments in water. Biodegradable in the soil. Photolysis in the air. Biochemical oxygen demand (BOD) 2.18 g O? /g substance Chemical oxygen demand (COD) 2.15 g O? /g substance ThOD 3.10 g O? /g substance BOD (% of ThOD) 0.70 % ThOD Toluene (108-88-3) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Low potential for adsorption in soil. Biochemical oxygen demand (BOD) 2.15 g O? /g substance Chemical oxygen demand (COD) 2.52 g O? /g substance ThOD 3.13 g O? /g substance BOD (% of ThOD) 0.69 % ThOD Heptane (142-82-5) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Adsorbs into the soil. Biochemical oxygen demand (BOD) 1.92 g O? /g substance Chemical oxygen demand (COD) 0.06 g O? /g substance ThOD 3.52 g O? /g substance BOD (% of ThOD) > % ThOD (5 day(s)) > 0.5 Heptane, Branched Cyclic (426260-76-6) Persistence and degradability May cause long-term adverse effects in the environment. Acetone (67-64-1) Persistence and degradability Not established. Methanol (67-56-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biochemical oxygen demand (BOD) 0.6 - 1.12 g O? /g substance Chemical oxygen demand (COD) 1.42 g O? /g substance ThOD 1.5 g O? /g substance BOD (% of ThOD) 0.8 % ThOD Acetone (67-64-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. No (test)data on mobility of the substance available. Not established. Biochemical oxygen demand (BOD) 1.43 g O? /g substance Chemical oxygen demand (COD) 1.92 g O? /g substance ThOD 2.20 g O? /g substance BOD (% of ThOD) (20 day(s)) 0.872 12.3. Bioaccumulative potential JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Bioaccumulative potential Not established. Benzene (71-43-2) BCF fish 1 19 Salmo gairdneri (Oncorhynchus mykiss) BCF other aquatic organisms 1 30 (24 h; Chlorella sp.; Fresh weight) Log Pow 2.13 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Toluene (108-88-3) BCF fish 1 13.2 (Anguilla japonica) BCF fish 2 90 (72 h; Leuciscus idus) BCF other aquatic organisms 1 380 (24 h; Chlorella sp.; Fresh weight) BCF other aquatic organisms 2 4.2 (Mytilus edulis; Fresh weight) JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 9/13 Toluene (108-88-3) Log Pow 2.73 (Experimental value; Other; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Heptane (142-82-5) BCF other aquatic organisms 1 552 Log Pow 4.66 (Experimental value; 4.5; Literature) Bioaccumulative potential Potential for bioaccumulation (4 ? Log Kow ? 5). Heptane, Branched Cyclic (426260-76-6) Bioaccumulative potential Not established. Acetone (67-64-1) Bioaccumulative potential Not established. Methanol (67-56-1) BCF fish 1 < 10 (Leuciscus idus) Log Pow -0.77 (Experimental value; Other) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Acetone (67-64-1) BCF fish 1 0.69 (Pisces) BCF other aquatic organisms 1 3 Log Pow -0.24 (Test data) Bioaccumulative potential Not bioaccumulative. Not established. 12.4. Mobility in soil Benzene (71-43-2) Surface tension 0.029 N/m (20 ?C) Toluene (108-88-3) Surface tension 0.03 N/m (20 ?C) Heptane (142-82-5) Surface tension 0.020 N/m (20 ?C) Methanol (67-56-1) Surface tension 0.023 N/m (20 ?C) Acetone (67-64-1) Surface tension 0.0237 N/m (20 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 10/13 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1993, Flammable liquids, n.o.s. (Acetone, Heptane, Methanol), 3, II ICAO/IATA (air): UN1993, Flammable liquids, n.o.s. (Acetone, Heptane, Methanol), 3 , II IMO/IMDG (water): UN1993, Flammable liquids, n.o.s. (Acetone, Heptane, Methanol), 3 , II Special Provisions: IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Flammable liquids, n.o.s. (Acetone, Heptane, Methanol) Department of Transportation (DOT) Hazard Classes : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid DOT Symbols : G - Identifies PSN requiring a technical name Packing group (DOT) : II - Medium Danger DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : B - (i) The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ??On deck only?? on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 5 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 11/13 SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Toluene (108-88-3) Listed on United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Heptane, Branched Cyclic (426260-76-6) Not listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard Methanol (67-56-1) Listed on United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard Delayed (chronic) health hazard 15.2. International regulations CANADA JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON WHMIS Classification Class B Division 2 - Flammable Liquid Toluene (108-88-3) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Heptane, Branched Cyclic (426260-76-6) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Methanol (67-56-1) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Acetone (67-64-1) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations Toluene (108-88-3) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Acetone (67-64-1) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)- Directive 79/831/EEC, sixth Amendment of Directive 67/548/EEC (dangerous substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 12/13 Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 Xn; R20/21/22 Xn; R68/20/21/22 Xi; R36 N; R51/53 R66 Full text of R-phrases: see section 16 15.2.2. National regulations Acetone (67-64-1) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on KECI (Korean Existing Chemicals Inventory) Listed on AICS (Australian Inventory of Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) 15.3. US State regulations JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Acetone (67-64-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes Toluene (108-88-3) U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Acetone (67-64-1) U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Benzene 71-43-2 U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 ------ Acute Tox. 3 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 3 ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1 ------ Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3 ------ Asp. Tox. 1 Aspiration hazard Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 1 Flammable liquids Category 1 ------ Flam. Liq. 2 Flammable liquids Category 2 ------ Repr. 2 Reproductive toxicity Category 2 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 ------ STOT SE 1 Specific target organ toxicity (single exposure) Category 1 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H224 Extremely flammable liquid and vapor JOHNSEN'S NON-CHLORINATATED BRAKE PARTS CLEANER CALIFORNIA 5 GALLON Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 13/13 ------ H225 Highly flammable liquid and vapor ------ H301 Toxic if swallowed ------ H304 May be fatal if swallowed and enters airways ------ H311 Toxic in contact with skin ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H331 Toxic if inhaled ------ H336 May cause drowsiness or dizziness ------ H361 Suspected of damaging fertility or the unborn child ------ H370 Causes damage to organs ------ H373 May cause damage to organs through prolonged or repeated exposure ------ H400 Very toxic to aquatic life ------ H410 Very toxic to aquatic life with long lasting effects ------ H412 Harmful to aquatic life with long lasting effects NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.