JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 09/09/2014 : Version: 19/02/2015 EN (English US) 1/7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S OIL TREATMENT 12 FL.OZ. Product code : 4624 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Oil Treatment 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Inhalation:dust,mist) H332 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H332 - Harmful if inhaled Precautionary statements (GHS-US) : P261 - Avoid breathing dust,fume,gas,mist,vapor spray P271 - Use only outdoors or in a well-ventilated area P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Distillates (Petroleum), Hydrotreated Heavy Naphthenic (CAS No) 64742-52-5 >= 95 Acute Tox. 4 (Inhalation:dust,mist), H332 Ethene/ Hexadiene/ Propene,Terpolymers (CAS No) 25038-37-3 1 - 5 Not classified The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 19/02/2015 EN (English US) 2/7 First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : If you feel unwell, seek medical advice. Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/injuries after skin contact : May cause slight irritation . Red skin. Itching. Skin rash/inflammation. Symptoms/injuries after eye contact : May cause slight eye irritation . Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Use only outdoors or in a well-ventilated area. Avoid breathing dust,fume,gas,mist,vapor spray. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 19/02/2015 EN (English US) 3/7 Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters JOHNSEN'S OIL TREATMENT 12 FL.OZ. USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? Mist 8 Hours USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Mist 8 Hours Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? Inhalable fraction Ethene/ Hexadiene/ Propene,Terpolymers (25038-37-3) USA ACGIH ACGIH TWA (mg/m?) 3 mg/m? 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Colorless to pale yellow liquid. Color : Light amber. Odor : Petroleum-like odour. Mild. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : > 260 ?C Flash point : > 182 ?C Auto-ignition temperature : > 343 K Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.001 mm Hg Relative vapor density at 20 ?C : > 5 Air=1 Relative density : 0.9 Solubility : Poorly soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 19/02/2015 EN (English US) 4/7 Explosive limits : No data available 9.2. Other information VOC content : 0 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if inhaled. Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) LD50 oral rat > 5000 ml/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Ethene/ Hexadiene/ Propene,Terpolymers (25038-37-3) LD50 oral rat > 7500 mg/kg (Rat) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Harmful if inhaled. Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/injuries after skin contact : May cause slight irritation . Red skin. Itching. Skin rash/inflammation. Symptoms/injuries after eye contact : May cause slight eye irritation . Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) EC50 Daphnia 1 > 1000 mg/l 48 HOURS 12.2. Persistence and degradability JOHNSEN'S OIL TREATMENT 12 FL.OZ. Persistence and degradability Not established. JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 19/02/2015 EN (English US) 5/7 Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Persistence and degradability Not established. Ethene/ Hexadiene/ Propene,Terpolymers (25038-37-3) Persistence and degradability Biodegradability in water: no data available. Not established. 12.3. Bioaccumulative potential JOHNSEN'S OIL TREATMENT 12 FL.OZ. Bioaccumulative potential Not established. Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Bioaccumulative potential Not established. Ethene/ Hexadiene/ Propene,Terpolymers (25038-37-3) Bioaccumulative potential No bioaccumulation data available. Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Use appropriate containment to avoid environmental contamination. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. . Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): Not regulated, ICAO/IATA (air): Not regulated, IMO/IMDG (water): Not regulated, Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Not regulated 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S OIL TREATMENT 12 FL.OZ. Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on on the United States EPA list of carcinogens SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 19/02/2015 EN (English US) 6/7 15.2. International regulations CANADA JOHNSEN'S OIL TREATMENT 12 FL.OZ. Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Listed on the Canadian DSL (Domestic Sustances List) EU-Regulations JOHNSEN'S OIL TREATMENT 12 FL.OZ. Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.2; R45 Full text of R-phrases: see section 16 15.2.2. National regulations Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) 15.3. US State regulations No additional information available SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ H332 Harmful if inhaled NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC JOHNSEN'S OIL TREATMENT 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 19/02/2015 EN (English US) 7/7 The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.