POWERGUARD(TM) 2630 of1 Not available. Industrial applications: Fuel additive. Material Safety Data Sheet Product name Material uses Internal code Product and company identification : : : 1. Supplier : Innospec Fuel Specialties LLC 8310 South Valley Highway Suite 350 Englewood CO, 80112 USA Information contact : 1-800-441-9547 : This email address is being protected from spambots. You need JavaScript enabled to view it. address of person responsible for this SDS POWERGUARD(TM) 2630 of1 Country information : Europe ( all countries, all languages ) : +44 (0) 1235 239 670 Middle East, Africa ( Arabic, French, English ) : +44 (0) 1235 239 671 Middle East, Africa ( French, Portuguese, English ) : +44 (0) 1235 239 670 Asia Pacific ( all countries except China ) : +65 3158 1074 China : +86 10 5100 3039 Emergency telephone number In Europe, Middle East, Africa, Asia Pacific and South America 24 hour / 7 day emergency response for our products is provided by the NCEC CARECHEM 24 global network The main regional centres are listed here in Section 1. Other local contact numbers for specific language support in Asia Pacific are listed in Section 16 Emergency telephone number South America ( all countries ) : +1 215 207 0061 Location London, UK Singapore Beijing China Lebanon London UK Philadelphia USA In USA, Canada and North America, 24 hour / 7 day emergency response for our product is provided by the CHEMTREC (R) Emergency Call Center based in the USA USA : 800 424 9300 Canada, Puerto Rico, Virgin Islands : +1 800 424 9300 In case of difficulties, or for ships at sea : +1 703 527 3887 Emergency telephone number Country information : 1/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Emergency overview Hazards identification Physical state Liquid. See toxicological information (Section 11) WARNING! COMBUSTIBLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. : : Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : Odor : Aromatic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 2. Over-exposure signs/symptoms Ingestion : Adverse symptoms may include the following: nausea or vomiting Skin : Adverse symptoms may include the following: irritation redness Eyes : Adverse symptoms may include the following: pain or irritation watering redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing Target organs : Contains material which causes damage to the following organs: blood, kidneys, liver, gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. Contains material which may cause damage to the following organs: lungs, the nervous system, cardiovascular system. Solvent naphtha (petroleum), heavy arom. 64742-94-5 30 - 60 2-ethylhexyl nitrate 27247-96-7 15 - 30 naphthalene 91-20-3 0.99 - 4.99 1,2,4-trimethylbenzene 95-63-6 0.99 - 4.99 xylene 1330-20-7 0.99 - 4.99 ethylbenzene 100-41-4 0.09 - 0.99 Composition/information on ingredients Name CAS number % 3. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 2/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : 4. Use dry chemical, CO?, water spray (fog) or foam. Fire-fighting measures Extinguishing media Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 5. In case of fire : Do not use water jet. Suitable : Not suitable : Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Flammability of the product : Remarks Decomposes violently when heated above 100?C.: Flash point : Closed cup: >61?C (>141.8?F) [Pensky-Martens.] Lowest known value: 130 to 215?C (266 to 419?F) (2-ethylhexyl nitrate).Auto-ignition temperature : Upper/lower flammability or explosive limits : Greatest known range: Lower: 0.6% Upper: 7% (Solvent naphtha (petroleum), heavy arom.) No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions : 6. Methods for cleaning up 3/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Accidental release measures6. Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. Handling and storage Handling Storage : : 7. Remarks : Consult: Innospec PLMR 2007-05 or RS PB 09-51 Best Practice Manual for blends containing CI-0801. Product trade name CI-0801: 2-ethylhexyl nitrate. Keep away from heat. Storage Temperature: Ambient. 2-ethylhexyl nitrate Innospec (United States, 1/2010). Absorbed through skin. TWA: 1 ppm 8 hours. Innospec (United States, 6/2010). Absorbed through skin. STEL: 1 ppm 15 minutes. naphthalene ACGIH TLV (United States, 6/2013). Absorbed through skin. TWA: 10 ppm, 0 times per shift, 8 hours. TWA: 52 mg/m?, 0 times per shift, 8 hours. STEL: 15 ppm, 0 times per shift, 15 minutes. STEL: 79 mg/m?, 0 times per shift, 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 10 ppm, 0 times per shift, 8 hours. Exposure controls/personal protection8. Ingredient Exposure limits 4/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Exposure controls/personal protection8. TWA: 50 mg/m?, 0 times per shift, 8 hours. STEL: 15 ppm, 0 times per shift, 15 minutes. STEL: 75 mg/m?, 0 times per shift, 15 minutes. NIOSH REL (United States, 10/2013). TWA: 10 ppm, 0 times per shift, 10 hours. TWA: 50 mg/m?, 0 times per shift, 10 hours. STEL: 15 ppm, 0 times per shift, 15 minutes. STEL: 75 mg/m?, 0 times per shift, 15 minutes. OSHA PEL (United States, 2/2013). TWA: 10 ppm, 0 times per shift, 8 hours. TWA: 50 mg/m?, 0 times per shift, 8 hours. 1,2,4-trimethylbenzene ACGIH TLV (United States, 6/2013). TWA: 25 ppm, 0 times per shift, 8 hours. TWA: 123 mg/m?, 0 times per shift, 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 25 ppm, 0 times per shift, 8 hours. TWA: 125 mg/m?, 0 times per shift, 8 hours. NIOSH REL (United States, 10/2013). TWA: 25 ppm, 0 times per shift, 10 hours. TWA: 125 mg/m?, 0 times per shift, 10 hours. xylene ACGIH TLV (United States, 6/2013). TWA: 100 ppm, 0 times per shift, 8 hours. TWA: 434 mg/m?, 0 times per shift, 8 hours. STEL: 150 ppm, 0 times per shift, 15 minutes. STEL: 651 mg/m?, 0 times per shift, 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm, 0 times per shift, 8 hours. TWA: 435 mg/m?, 0 times per shift, 8 hours. STEL: 150 ppm, 0 times per shift, 15 minutes. STEL: 655 mg/m?, 0 times per shift, 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm, 0 times per shift, 8 hours. TWA: 435 mg/m?, 0 times per shift, 8 hours. ethylbenzene ACGIH TLV (United States, 6/2013). TWA: 20 ppm, 0 times per shift, 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm, 0 times per shift, 8 hours. TWA: 435 mg/m?, 0 times per shift, 8 hours. STEL: 125 ppm, 0 times per shift, 15 minutes. STEL: 545 mg/m?, 0 times per shift, 15 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm, 0 times per shift, 10 hours. TWA: 435 mg/m?, 0 times per shift, 10 hours. STEL: 125 ppm, 0 times per shift, 15 minutes. STEL: 545 mg/m?, 0 times per shift, 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm, 0 times per shift, 8 hours. TWA: 435 mg/m?, 0 times per shift, 8 hours. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. 5/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Exposure controls/personal protection8. Use a properly fitted, air-purifying or supplied-air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Personal protection Eyes Skin Respiratory : : : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Lowest known value: 138.85?C (281.9?F) (xylene). Weighted average: 194.25?C (381. 6?F) Liquid. 0.9328 [ASTM D 4052] Highest known value: 4.6 to 5.5 (Air = 1) (Solvent naphtha (petroleum), heavy arom.). Weighted average: 3.77 (Air = 1) Highest known value: 0.7 to 0.9 kPa (5 to 6.6 mm Hg) (at 20?C) (xylene). Weighted average: 0.09 kPa (0.68 mm Hg) (at 20?C) Lowest known value: 0.001 to 0.03 ppm (2-ethylhexyl nitrate) Aromatic. Clear. Amber. [Light] Boiling/condensation point Physical and chemical properties Physical state Specific gravity Vapor pressure Vapor density Odor threshold Odor Color : : : : : : : : Flash point : Closed cup: >61?C (>141.8?F) [Pensky-Martens.] Lowest known value: 130 to 215?C (266 to 419?F) (2-ethylhexyl nitrate).:Auto-ignition temperature Flammable limits : Greatest known range: Lower: 0.6% Upper: 7% (Solvent naphtha (petroleum), heavy arom.) 9. Density : 0.93205 g/cm? [15?C (59?F)] Density : 7.78 lbs/gal 6/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Physical and chemical properties9. Not dispersible in the following materials: cold water. Highest known value: <1 (2-ethylhexyl nitrate) Weighted average: 0.33compared with butyl acetate Evaporation rate Dispersibility properties : : Solubility(ies) : Insoluble in the following materials: cold water, hot water. The product is stable. Reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Stability and reactivity Chemical stability Conditions to avoid Materials to avoid Hazardous decomposition products : : : : 10. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Decomposes violently when heated above 100?C. Incompatible with fluorine. Conditions of reactivity : Flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. Toxicological information11. Acute toxicity naphthalene - Rat LC50 Inhalation Vapor >340 mg/m? - Rabbit LD50 Dermal >2000 mg/kg - Rat LD50 Dermal >2500 mg/kg - Rat LD50 Oral 490 mg/kg Solvent naphtha (petroleum), heavy arom. - Rat LC50 Inhalation Vapor >590 mg/m? - Rabbit LD50 Dermal >2 mL/kg - Rat LDLo Oral 5 mL/kg 2-ethylhexyl nitrate - Rat LCLo Inhalation Vapor >4.6 mg/l - Rabbit LD50 Dermal >4820 mg/kg - Rat LD50 Oral >9640 mg/kg xylene - Rabbit LD50 Dermal 4320 mg/kg - Rat LD50 Oral 4300 mg/kg ethylbenzene - Mouse LC50 Inhalation Vapor 35500 mg/m? - Rabbit LC50 Inhalation Vapor 4000 ppm - Rabbit LD50 Dermal >5000 mg/kg Product/ingredient name Test Species Result Dose Irritation/Corrosion 7/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Toxicological information11. Carcinogenicity Mutagenicity 2-ethylhexyl nitrate OECD 473 Experiment: In vitro Subject: Mammalian-Human Negative Product/ingredient name Test Experiment Result Reproductive toxicity Product/ingredient name Test Species Result Dose 2-ethylhexyl nitrate OECD 421 Rat No effect level. Oral: 100 mg/kg OECD 421 Rat No effect level. Oral: 20 mg/kg Classification naphthalene A4 2B - - Reasonably anticipated to be a human carcinogen. - xylene A4 3 - - - - ethylbenzene A3 2B - - - - Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA Product/ingredient name Test Result Sensitizer Product/ingredient name Test Species Result 2-ethylhexyl nitrate OECD 406 Skin Sensitization Guinea pig Not sensitizing - Species Solvent naphtha (petroleum), heavy arom. - Rabbit Skin - Mild irritant - - Mammal - species unspecified Eyes - Mild irritant - 2-ethylhexyl nitrate OECD 437 Mammal - species unspecified Eyes - Mild irritant - OECD 405 Acute Eye Irritation/ Corrosion Rabbit Eyes - Mild irritant - xylene - Rabbit Eyes - Severe irritant - - Rat Skin - Mild irritant - - Rabbit Skin - Moderate irritant - ethylbenzene - Rabbit Eyes - Severe irritant - - Rabbit Skin - Mild irritant - Ecological information12. Aquatic ecotoxicity naphthalene Acute EC50 1.96 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2350 ?g/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 1.6 mg/l Fish 96 hours Solvent naphtha (petroleum), heavy arom. Acute EC50 1 to 3 mg/l Algae 72 hours Acute EC50 3 to 10 mg/l Daphnia 48 hours Acute LC50 2 to 5 mg/l Fish 96 hours Product/ingredient name SpeciesResult Exposure 8/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Ecological information12. 2-ethylhexyl nitrate Acute EC50 1 to 10 mg/l Estimated. Nominal Concentration Algae 72 hours Acute EC50 >10 mg/l Estimated. Daphnia 48 hours Acute LC50 2 mg/l Fish - Danio rerio 96 hours 1,2,4-trimethylbenzene Acute LC50 7.72 mg/l Fish 96 hours xylene Acute LC50 3.3 mg/l Fish 96 hours ethylbenzene Acute EC50 4600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 7.2 mg/l Algae 48 hours Acute EC50 2.93 mg/l Daphnia 48 hours Acute LC50 4.2 mg/l Fish 96 hours Chronic NOEC <1000 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Chronic NOEC 6800 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Disposal considerations13. Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Transport information Regulatory information UN number Proper shipping name Classes PG* Label Additional information 14. 9/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Transport information14. Combustible liquid. Reportable quantity 2121.6 lbs / 963.19 kg [273 gal / 1033.4 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 60 L Cargo aircraft Quantity limitation: 220 L Special provisions IB3, T4, TP1 DOT Classification Combustible liquid, n. o.s. (Solvent naphtha (petroleum), heavy arom., 2-ethylhexyl nitrate). Marine pollutant (Solvent naphtha (petroleum), heavy arom., 2-ethylhexyl nitrate) RQ (naphthalene, xylene) III IMDG Class ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Solvent naphtha (petroleum), heavy arom., 2-ethylhexyl nitrate). Marine pollutant (Solvent naphtha (petroleum), heavy arom., 2-ethylhexyl nitrate) 9 III Environmentally hazardous substance, liquid, n.o.s. (Solvent naphtha (petroleum), heavy arom., 2-ethylhexyl nitrate) UN3082IATA-DGR Class 9 III UN3082 The marine pollutant mark is not required when transported in sizes of ?5 L or ?5 kg. Emergency schedules (EmS) F-A, S-F Special provisions 274, 335 NA1993 PG* : Packing group Flash point : Closed cup: >61?C (>141.8?F) [Pensky-Martens.] Remarks re DOT: This material is not regulated under 49CFR 173.150(f) in a container of 119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance. The requirements of this subchapter, 49CFR 171.4(c), specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle, rail car or aircraft. 10/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Toxic material Irritating material Carcinogen Target organ effects HCS Classification Regulatory information U.S. Federal regulations The following components are listed: NAPHTHALENE; PSEUDOCUMENE; XYLENE Clean Water Act (CWA) 307: naphthalene; ethylbenzene; toluene Clean Water Act (CWA) 311: naphthalene; xylene; toluene Massachusetts SARA 302/304: No products were found. SARA 311/312 Hazards identification: Immediate (acute) health hazard, Delayed (chronic) health hazard : : SARA 313 : Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. 15. naphthalene 91-20-3 0.99 - 4.99 1,2,4-trimethylbenzene 95-63-6 0.99 - 4.99 xylene 1330-20-7 0.99 - 4.99 ethylbenzene 100-41-4 0.09 - 0.99 naphthalene 91-20-3 0.99 - 4.99 1,2,4-trimethylbenzene 95-63-6 0.99 - 4.99 xylene 1330-20-7 0.99 - 4.99 ethylbenzene 100-41-4 0.09 - 0.99 Form R - Reporting requirements Supplier notification Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed New York : The following components are listed: Naphthalene; Xylene (mixed) New Jersey : The following components are listed: NAPHTHALENE; MOTH FLAKES; PSEUDOCUMENE; 1,2,4-TRIMETHYL BENZENE; XYLENES; BENZENE, DIMETHYL- Pennsylvania : The following components are listed: NAPHTHALENE; PSEUDOCUMENE; BENZENE, DIMETHYL- State regulations TSCA 4(a) final test rules: naphthalene TSCA 8(a) PAIR: naphthalene TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. TSCA 12(b) one-time export: naphthalene California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. 11/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Regulatory information15. International lists : At least one component is not listed. All components are listed or exempted. At least one component is not listed. At least one component is not listed in EINECS but all such components are listed in ELINCS. Please contact your supplier for information on the inventory status of this material. At least one component is not listed. At least one component is not listed. Not determined. At least one component is not listed. All components are listed or exempted. Australia inventory (AICS) :Canada inventory :China inventory (IECSC) :EU Inventory :Japan inventory (ENCS) :Korea inventory (KECI) :New Zealand Inventory of Chemicals (NZIoC) :Philippines inventory (PICCS) :United States inventory (TSCA 8b) naphthalene Yes. No. Yes. No. 0.99 - 4.99 ethylbenzene Yes. No. 41 ?g/day (ingestion) 54 ?g/day (inhalation) No. 0.09 - 0.99 cumene Yes. No. No. No. <100ppm toluene No. Yes. No. 7000 ?g/day (ingestion) 13000 ?g/day (inhalation) <1ppm Ingredient name Cancer Reproductive No significant risk level Contains : % or ppm Maximum acceptable dosage level Other information Hazardous Material Information System (U.S.A.) 2 2 1 1 2 2 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards : : 16. Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. 12/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner POWERGUARD(TM) 2630 of1 Other information16. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of printing Date of issue Date of previous issue Version 26-06-2014.: : : : Indicates information that has changed from previously issued version. 26-06-2014. No previous validation. 1 Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Emergency contact numbers for local language support in Asia Pacific region Country information Telephone no.: LocationLanguages supported Australia English +61 2 8014 4558 Australia Bangladesh Bengali, English +65 3158 1200 Singapore China Mandarin, English +86 10 5100 3039 Beijing China India Hindi, English +65 3158 1198 Singapore Indonesia (local toll free number) Bahasa Indonesian, English 00780 3011 0293 Indonesia Japan Japanese, English +81 3 4578 9341 Japan Korea Korean, English +65 3158 1285 Singapore Malaysia Bahasa Malaysian, English +60 3 6207 4347 Malaysia Pakistan Urdu, English +65 3158 1329 Singapore Sri Lanka Sinhalese, English +65 3158 1195 Singapore Thailand (local toll free number) Thai, English 001800 1 2066 6751 Thailand Vietnam Vietnamese, English +65 3158 1255 Singapore New Zealand English +61 9929 1483 Australia Philippines Tagalog, English +65 3158 1203 Singapore 13/13 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. Date of issue : June 26, 2014 HMCS ID: 30109020 SUC: 03-Solvents - Flashpoint >100 F External Key: 10-3011, 88861698 MATERIAL SAFETY DATA SHEET Print Date: 07.Oct.2014 Corporate Synonyms: ACDelco Diesel Fuel Conditioner