Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 1 of 9 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT INFORMATION Product Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER External Keys: Brake Parts Cleaner (45% VOC) Primary Tradename - Distributable Material 19287400 Distributable Material (Part #) 10-6013 Distributable Material (Part #) MANUFACTURER INFORMATION Manufacturer: SHERWIN-WILLIAMS COMPANY Address: 101 Prospect Avenue N.W. USA Ohio 44115 Cleveland MAILING Communication Lines: Phone 216-566-2917 Medical emergency Phone 216-566-2902 Regulatory information Phone 800-247-3270 Information - Duplicolor Products Group Phone 800-247-3266 Information - Diversified Brands Phone 800-832-2541 Information - Krylon Products Group Phone 800-251-2486 Information - Consumer Group Industrial Phone 800-424-9300 Transportation emergency (Chemtrec) 2 INGREDIENT INFORMATION Synonyms: PRODUCT NUMBER Z2B100945 FORMULATION Ingredients: Chemical Name CAS Number Prefix Value Unit Exposure Limits HEPTANE 142-82-5 = 21 %Wt Yes Solvent naphtha, petroleum, light aliph. 64742-89-8 = 1 %Wt No TOLUENE 108-88-3 = 22 %Wt Yes CYCLOHEXANE, METHYL- 108-87-2 = 1 %Wt Yes ACETONE 67-64-1 = 47 %Wt Yes CARBON DIOXIDE 124-38-9 = 8 %Wt Yes 3 HAZARDS IDENTIFICATION Specific Hazards: ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Specific Hazards (Routes Of Exposure): Exposure Routes Observation Eye contact Irritation. Skin Contact Prolonged or repeated exposure may cause irritation. Inhalation Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Effects Of Overexposure: Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 2 of 9 3 HAZARDS IDENTIFICATION Effects Of Overexposure: Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: ? the liver ? the urinary system ? the cardiovascular system ? the reproductive system Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. Medical Conditions Aggravated By Exposure: None generally recognized. 4 FIRST AID MEASURES First Aid By:: Inhalation If affected, remove from exposure. Restore breathing. Keep warm and quiet. Skin Contact Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. Eye Contact Flush eyes with large amounts of water for 15 minutes. Get medical attention. Ingestion Do not induce vomiting. Get medical attention immediately. 5 FIRE FIGHTING MEASURES Flash Point: = 13 ?F PMCC Explosive Limits: Upper Explosive Limit (UEL) = 12.8 Lower Explosive Limit (LEL) = 1 Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam. Fire and Explosion Hazards: UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Special Fire Fighting Procedures: Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. 6 ACCIDENTAL RELEASE MEASURES SPILL OR LEAK PROCEDURES Recovery: ? Remove all sources of ignition. Ventilate the area. ? Remove with inert absorbent. 7 HANDLING AND STORAGE HANDLING Safe Handling Procedures: Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 3 of 9 7 HANDLING AND STORAGE HANDLING Safe Handling Procedures: stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. STORAGE Storage Conditions: STORAGE CATEGORY Not Available Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. EXPOSURE LIMITS Limit Values: Chemical Name CAS Number Type Value Specification Source Memo HEPTANE 142-82-5 PEL- TWA 500ppm - OSHA - Permissible Exposure Limits (PELs) HEPTANE 142-82-5 GM OEG -TWA 400ppm - GM Occupational Exposure Guidelines (OEG) HEPTANE 142-82-5 GM OEG -STEL 500ppm - GM Occupational Exposure Guidelines (OEG) HEPTANE 142-82-5 TLV- TWA 400ppm - Threshold Limit Values (TLVs) - ACGIH HEPTANE 142-82-5 TLV- STEL 500ppm - Threshold Limit Values (TLVs) - ACGIH HEPTANE 142-82-5 State- TWA 400ppm - MICHIGAN HEPTANE 142-82-5 State- STEL 500ppm - MICHIGAN HEPTANE 142-82-5 State- TWA 400ppm - NEW YORK HEPTANE 142-82-5 State- STEL 500ppm - NEW YORK HEPTANE 142-82-5 State- Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 4 of 9 8 EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS Limit Values: Chemical Name CAS Number Type Value Specification Source Memo TWA 400ppm - TENNESSEE HEPTANE 142-82-5 State- STEL 500ppm - TENNESSEE TOLUENE 108-88-3 PEL- TWA 200ppm - OSHA - Permissible Exposure Limits (PELs) TOLUENE 108-88-3 PEL- Ceiling 300ppm - OSHA - Permissible Exposure Limits (PELs) TOLUENE 108-88-3 GM OEG -TWA 50ppm - GM Occupational Exposure Guidelines (OEG) Skin TOLUENE 108-88-3 TLV- TWA 20ppm - Threshold Limit Values (TLVs) - ACGIH Skin TOLUENE 108-88-3 State- TWA 100ppm - MICHIGAN TOLUENE 108-88-3 State- STEL 150ppm - MICHIGAN TOLUENE 108-88-3 State- TWA 100ppm - NEW YORK TOLUENE 108-88-3 State- STEL 150ppm - NEW YORK TOLUENE 108-88-3 State- TWA 100ppm - TENNESSEE TOLUENE 108-88-3 State- STEL 150ppm - TENNESSEE CYCLOHEXANE, METHYL- 108-87-2 PEL- TWA 500ppm - OSHA - Permissible Exposure Limits (PELs) CYCLOHEXANE, METHYL- 108-87-2 GM OEG -TWA 400ppm - GM Occupational Exposure Guidelines (OEG) CYCLOHEXANE, METHYL- 108-87-2 TLV- TWA 400ppm - Threshold Limit Values (TLVs) - ACGIH CYCLOHEXANE, METHYL- 108-87-2 State- TWA 400ppm - MICHIGAN CYCLOHEXANE, METHYL- 108-87-2 State- TWA 400ppm - NEW YORK CYCLOHEXANE, METHYL- 108-87-2 State- TWA 400ppm - TENNESSEE ACETONE 67-64-1 GM OEG GM Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 5 of 9 8 EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS Limit Values: Chemical Name CAS Number Type Value Specification Source Memo -STEL 750ppm - Occupational Exposure Guidelines (OEG) ACETONE 67-64-1 TLV- TWA 500ppm - Threshold Limit Values (TLVs) - ACGIH ACETONE 67-64-1 TLV- STEL 750ppm - Threshold Limit Values (TLVs) - ACGIH ACETONE 67-64-1 State- TWA 750ppm - MICHIGAN ACETONE 67-64-1 State- STEL 1000ppm - MICHIGAN ACETONE 67-64-1 State- TWA 750ppm - NEW YORK ACETONE 67-64-1 State- STEL 1000ppm - NEW YORK ACETONE 67-64-1 State- TWA 750ppm - TENNESSEE ACETONE 67-64-1 State- STEL 1000ppm - TENNESSEE ACETONE 67-64-1 PEL- TWA 1000ppm - OSHA - Permissible Exposure Limits (PELs) ACETONE 67-64-1 GM OEG -TWA 500ppm - GM Occupational Exposure Guidelines (OEG) CARBON DIOXIDE 124-38-9 PEL- TWA 5000ppm - OSHA - Permissible Exposure Limits (PELs) CARBON DIOXIDE 124-38-9 GM OEG -TWA 5000ppm - GM Occupational Exposure Guidelines (OEG) CARBON DIOXIDE 124-38-9 GM OEG -STEL 30000ppm - GM Occupational Exposure Guidelines (OEG) CARBON DIOXIDE 124-38-9 TLV- TWA 5000ppm - Threshold Limit Values (TLVs) - ACGIH CARBON DIOXIDE 124-38-9 TLV- STEL 30000ppm - Threshold Limit Values (TLVs) - Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 6 of 9 8 EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS Limit Values: Chemical Name CAS Number Type Value Specification Source Memo ACGIH CARBON DIOXIDE 124-38-9 State- TWA 10000ppm - MICHIGAN CARBON DIOXIDE 124-38-9 State- STEL 30000ppm - MICHIGAN CARBON DIOXIDE 124-38-9 State- TWA 10000ppm - NEW YORK CARBON DIOXIDE 124-38-9 State- STEL 30000ppm - NEW YORK CARBON DIOXIDE 124-38-9 State- TWA 10000ppm - TENNESSEE CARBON DIOXIDE 124-38-9 State- STEL 30000ppm - TENNESSEE PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment (PPE): Respiratory Protection If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/ particulate respirator approved by NIOSH/MSHA for protection against the ingredients. Eye Protection Wear safety spectacles with unperforated sideshields. Hand Protection None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. Special Precautions: Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Comment: Physical state: Aerosol. PHYSICAL PROPERTIES pH Value: = 7 Changes of State: Boiling Point Range <0 - 238 ?F <-18 - 114 ?C Melting/Freezing Point Not Available Vapor Density: Heavier than air. Evaporation Rate: Faster than ether. Specific Gravity: = 0.80 Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 7 of 9 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL PROPERTIES Solubility: Water Not Available VOC: Analytical VOC (by. wt.) = 45 '%' Less water and federally exempt solvents. VOC = 2.99 lb/gal 358 g/l Total VOC = 5.69 lb/gal 682 g/l Less exempt solvents VOC = 0.00 lb/gal of solids VOC = 0.00 lb/lb (0.00 kg/kg) of solids VOC = 6.65 lb/gal Coating density VOC = 100.0 %Wt Total volatiles VOC = 8.0 %Wt Non Organic volatiles: Carbon Dioxide. VOC Federally exempt solvents: Water: 0.0 % by wt, 0.0 % by vol Acetone: 47.0 % by wt, 47.4 % by vol VOC = 45 %Wt Organic volatiles 46.3 % by vol VOC = 0.0 %Wt Percent Non-Volatile Total Amount Of:: Percent Volatile by Volume = 100 '%' 10 STABILITY AND REACTIVITY STABILITY INFORMATION Stability Under Normal Conditions: Stable Conditions to Avoid: None known. Incompatible Materials: None known. Hazardous Polymerization: Will not occur. HAZARDOUS DECOMPOSITION Reactions: Type of Reaction Reaction Products Decomposition HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide 11 TOXICOLOGICAL INFORMATION OCCUPATIONAL EXPERIENCES Health Effects: Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. SCIENTIFIC OBSERVATIONS LETHAL LIMIT VALUES Additional Information: Heptane (142-82-5) LC50 RAT 4H: Not available LD50 RAT: Not available Lt. Aliphatic Hydrocarbon Solvent (64742-89-8) Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 8 of 9 11 TOXICOLOGICAL INFORMATION SCIENTIFIC OBSERVATIONS LETHAL LIMIT VALUES Additional Information: LC50 RAT 4H: Not available LD50 RAT: Not available Toluene (108-88-3) LC50 RAT 4HR: 4000 ppm LD50 RAT: 5000 mg/kg Methyl Cyclohexane (108-87-2) LC50 RAT 4H: Not available LD50 RAT: Not available Acetone (67-64-1) LC50 RAT 4H: Not available LD50 RAT: 5800 mg/kg Carbon Dioxide (124-38-9) LC50 RAT 4H: Not available LD50 RAT: Not available CLASSIFICATION OF INGREDIENTS Carcingenicity: No ingredient in this product is an lARC, NTP or OSHA listed carcinogen. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer. Reproductive Effects: CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause birth defects or other reproductive harm. 12 ECOLOGICAL INFORMATION ENVIRONMENTAL IMPACT Comment: No data available. ECOTOXICITY Comment: No data available. 13 DISPOSAL CONSIDERATIONS Waste Disposal Information: WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. 14 TRANSPORT INFORMATION DOT Information: May be classed as Consumer Commodity, ORM-D LIMITED QUANTITY, (ERG#126) DOT Shipping Name: AEROSOLS DOT Hazard Class: 2.1 Prod.Name: Z2B100945 VOC COMPLIANT CONTACT CLEANER Manufacturer: SHERWIN-WILLIAMS COMPANY HMCS ID: 30052284 SUC: 02 - Solvents - Flashpoint < 100 F MATERIAL SAFETY DATA SHEET Revision: 08.Nov.2010 Effective: 08.Nov.2010 Print Date: 01.Feb.2011 Page: 9 of 9 14 TRANSPORT INFORMATION DOT UN Code: UN1950 Comment: IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D) 15 REGULATORY INFORMATION LABELLING Hazard Codes: NFPA Health 2 NFPA Flammability 3 NFPA Reactivity 0 HMIS Health 2 HMIS Flammability 3 HMIS Reactivity 0 Comment: NFPA assigned by General Motors Technica Review. NATIONAL REGULATIONS SARA 311/312: Yes SARA 313: Yes Immediate Health: Yes Delayed Health: No Fire: Yes Sudden Pressure Release: No Reactive: No Other Regulation: SARA 313 Toluene (108-88-3): 22 % by WT TSCA All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Air Quality Data Density of Organic Solvent Blend 6.53 lb/gal Photochemically Reactive Yes Maximum Incremental Reactivity (MIR) (California Air Resources Board Aerosol Products Regulation, MIR Value July 18, 2001) 1.55 Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule) 1.55 STATE/LOCAL REGULATIONS Comment: CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. 16 OTHER INFORMATION 1 PRODUCT AND COMPANY IDENTIFICATION 2 INGREDIENT INFORMATION 3 HAZARDS IDENTIFICATION 4 FIRST AID MEASURES 5 FIRE FIGHTING MEASURES 6 ACCIDENTAL RELEASE MEASURES 7 HANDLING AND STORAGE 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 10 STABILITY AND REACTIVITY 11 TOXICOLOGICAL INFORMATION 12 ECOLOGICAL INFORMATION 13 DISPOSAL CONSIDERATIONS 14 TRANSPORT INFORMATION 15 REGULATORY INFORMATION 16 OTHER INFORMATION