3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-4794-3 Version Number: 47.00 Issue Date: 03/03/15 Supercedes Date: 09/21/12 SECTION 1: Identification 1.1. Product identifier 3M? Plastic and Emblem Adhesive - Clear, PN 08061 Product Identification Numbers 41-0003-7952-3, 41-3701-2181-0, 60-4550-3003-5, 60-4550-5499-3 1.2. Recommended use and restrictions on use Recommended use Adhesive, Clear Adhesive for Plastic Repair and Emblem Application 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 2 of 11 Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 41% of the mixture consists of ingredients of unknown acute oral toxicity. 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 3 of 11 41% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methyl Ethyl Ketone 78-93-3 30 - 60 Trade Secret * Vinyl Chloride, Vinyl Acetate, Maleic Acid Polymer 32650-26-3 15 - 40 Trade Secret * Thermoplastic Polyester Trade Secret* 15 - 40 Trade Secret * 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer 25068-38-6 < 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 4 of 11 prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Methyl Ethyl Ketone 78-93-3 ACGIH TWA:200 ppm;STEL:300 ppm Methyl Ethyl Ketone 78-93-3 OSHA TWA:590 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 5 of 11 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Butyl Rubber Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: clear, ketone odor Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 176 ?F [Details: CONDITIONS: (MEK)] Flash Point 20 ?F [Test Method: Tagliabue Closed Cup] [Details: CONDITIONS: (methyl ethyl ketone)] Evaporation rate 2.70 [Ref Std: WATER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.80 % volume Flammable Limits(UEL) 10 % volume Vapor Pressure 91 mmHg [Details: CONDITIONS: @ 68F] Vapor Density 2.41 [Ref Std: AIR=1] Density 0.950 g/ml Specific Gravity 0.95 [Ref Std: WATER=1] 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 6 of 11 Solubility in Water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 404 ?C [Details: MEK] Decomposition temperature No Data Available Viscosity Approximately 8,500 centipoise Hazardous Air Pollutants < 0.0001 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 552 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 58.1 % weight [Test Method: calculated per CARB title 2] Percent volatile 58.1 % weight VOC Less H2O & Exempt Solvents 552 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 7 of 11 and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Methyl Ethyl Ketone Dermal Rabbit LD50 > 8,050 mg/kg Methyl Ethyl Ketone Inhalation- Vapor (4 hours) Rat LC50 34.5 mg/l Methyl Ethyl Ketone Ingestion Rat LD50 2,737 mg/kg 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Rat LD50 > 1,600 mg/kg 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Ingestion Rat LD50 > 1,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Minimal irritation 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Severe irritant 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Moderate irritant Skin Sensitization Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Human and animal Sensitizing 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 8 of 11 Respiratory Sensitization Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Methyl Ethyl Ketone In Vitro Not mutagenic 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer In vivo Not mutagenic 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Methyl Ethyl Ketone Inhalation Human Not carcinogenic 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation Not toxic to female reproduction Rat NOAEL 14.7 mg/l 90 days Methyl Ethyl Ketone Inhalation Not toxic to male reproduction Rat NOAEL 14.7 mg/l 90 days Methyl Ethyl Ketone Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 8.8 mg/l during gestation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation central nervous system depression May cause drowsiness or dizziness official classifica tion NOAEL Not available Methyl Ethyl Ketone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Methyl Ethyl Ketone Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available not applicable Methyl Ethyl Ketone Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1,080 mg/kg not applicable Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 9 of 11 Methyl Ethyl Ketone Dermal nervous system All data are negative Guinea pig NOAEL Not available 31 weeks Methyl Ethyl Ketone Inhalation liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 14.7 mg/l 90 days Methyl Ethyl Ketone Inhalation heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | muscles All data are negative Rat NOAEL 14.7 mg/l 90 days Methyl Ethyl Ketone Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 7 days Methyl Ethyl Ketone Ingestion nervous system All data are negative Rat NOAEL 173 mg/kg/day 90 days 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 10 of 11 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-4794-3 Version Number: 47.00 Issue Date: 03/03/15 Supercedes Date: 09/21/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M? Plastic and Emblem Adhesive - Clear, PN 08061 03/03/15 __________________________________________________________________________________________ Page 11 of 11 3M USA SDSs are available at www.3M.com