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3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 1 of 18 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-3353-9 Version Number: 47.00 Issue Date: 01/21/15 Supercedes Date: 05/06/13 SECTION 1: Identification 1.1. Product identifier 3M? Brushable Seam Sealer, P.N. 08656 Product Identification Numbers 41-3701-2171-1, 60-4550-6600-5, 62-5507-6509-3 1.2. Recommended use and restrictions on use Recommended use Automotive, Seal sheetmetal overlap joints 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Solid: Category 1. Acute Toxicity (inhalation): Category 4. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 2 of 18 Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Flammable solid. Causes serious eye irritation. Causes skin irritation. Harmful if inhaled. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: cardiovascular system | nervous system | kidney/urinary tract | respiratory system | Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 3 of 18 Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: This product contains ethylene glycol. Effects of oral ethylene glycol poisoning can be divided into three stages which generally occur over a time-course of hours to days following ingestion: Stage 1 (neurological effects), stage 2 (cardiopulmonary effects) and stage 3 (renal effects). If ethylene glycol poisoning is confirmed, intravenous (IV) administration of ethanol should be considered. Additional pharmacologic and supportive care should be based on the treating physician?s judgement. 2.3. Hazards not otherwise classified None. 3% of the mixture consists of ingredients of unknown acute oral toxicity. 12% of the mixture consists of ingredients of unknown acute dermal toxicity. 41% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Toluene 108-88-3 15 - 40 Trade Secret * Synthetic Rubber Trade Secret* 10 - 30 Trade Secret * Methyl Isobutyl Ketone 108-10-1 10 - 30 Trade Secret * Talc 14807-96-6 7 - 13 Trade Secret * Ammonia, O-Cresol, Formaldehyde, Phenol Polymer 55185-45-0 3 - 7 Trade Secret * Phenolic Polymer - NJTSR No. 04499600-6305 Trade Secret* 3 - 7 Trade Secret * Salicylic Acid 69-72-7 1 - 5 Trade Secret * Ethylene Glycol 107-21-1 1 - 5 Trade Secret * Zinc Oxide 1314-13-2 1 - 5 Trade Secret * 2,2'-Methylenebis(6-Nonyl-P-Cresol) 7786-17-6 0.1 - 1.5 Trade Secret * Proprietary Polymer Trade Secret* 0.1 - 1.5 Trade Secret * Titanium Dioxide 13463-67-7 0.5 - 1.5 Trade Secret * Phenol 108-95-2 < 0.5 Trade Secret * O-Cresol 95-48-7 < 0.5 Trade Secret * Benzene 71-43-2 < 0.05 Trade Secret * Formaldehyde 50-00-0 < 0.05 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 4 of 18 Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required This product contains ethylene glycol. Effects of oral ethylene glycol poisoning can be divided into three stages which generally occur over a time-course of hours to days following ingestion: Stage 1 (neurological effects), stage 2 (cardiopulmonary effects) and stage 3 (renal effects). If ethylene glycol poisoning is confirmed, intravenous (IV) administration of ethanol should be considered. Additional pharmacologic and supportive care should be based on the treating physician?s judgement. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of vapors created during cure cycle. Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 5 of 18 heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylene Glycol 107-21-1 ACGIH CEIL(as aerosol):100 mg/m3 A4: Not class. as human carcin Ethylene Glycol 107-21-1 CMRG CEIL(as vapor and aerosol):100 mg/m3 Methyl Isobutyl Ketone 108-10-1 ACGIH TWA:20 ppm;STEL:75 ppm A3: Confirmed animal carcin. Methyl Isobutyl Ketone 108-10-1 OSHA TWA:410 mg/m3(100 ppm) Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Phenol 108-95-2 ACGIH TWA:5 ppm A4: Not class. as human carcin, Skin Notation Phenol 108-95-2 OSHA TWA:19 mg/m3(5 ppm) Skin Notation Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2 mg/m3;STEL(respirable fraction):10 mg/m3 Zinc Oxide 1314-13-2 OSHA TWA(as fume):5 mg/m3;TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 6 of 18 Formaldehyde 50-00-0 ACGIH CEIL:0.3 ppm A2: Suspected human carcin., Sensitizer Formaldehyde 50-00-0 CMRG TWA:0.5 ppm Formaldehyde 50-00-0 OSHA TWA:0.75 ppm;STEL:2 ppm 29 CFR 1910.1048 Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., Skin Notation Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 CRESOLS (ORTHO-; META-; PARA-) 95-48-7 OSHA TWA:22 mg/m3(5 ppm) Skin Notation O-Cresol 95-48-7 ACGIH TWA(inhalable fraction and vapor):20 mg/m3 A4: Not class. as human carcin, Skin Notation ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Fluoroelastomer Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 7 of 18 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Toluene Odor, Gray Paste Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 232.00 ?F [Details: CONDITIONS: (toluene)] Evaporation rate 5.00 [Ref Std: ETHER=1] Flammability (solid, gas) Flammable Solid: Category 1. Flammable Limits(LEL) 1.27 % volume Flammable Limits(UEL) 7.00 % volume Vapor Pressure 25.0000 mmHg Vapor Density 3.30 [Ref Std: AIR=1] Density 0.99 g/ml Specific Gravity 0.990 [Ref Std: WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Hazardous Air Pollutants 1.706 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 617 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 60.7 % weight [Test Method: calculated per CARB title 2] Percent volatile 62.3 % weight VOC Less H2O & Exempt Solvents 617 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 8 of 18 The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart muscle, heart attack, and may be fatal. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 9 of 18 Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Formaldehyde 50-00-0 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Formaldehyde 50-00-0 Known human carcinogen National Toxicology Program Carcinogens Formaldehyde 50-00-0 Cancer hazard OSHA Carcinogens Methyl Isobutyl Ketone 108-10-1 Grp. 2B: Possible human carc. International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 10 - 20 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Methyl Isobutyl Ketone Dermal Rabbit LD50 > 16,000 mg/kg Methyl Isobutyl Ketone Inhalation- Vapor (4 hours) Rat LC50 >8.2,<16.4 mg/l Methyl Isobutyl Ketone Ingestion Rat LD50 3,038 mg/kg Synthetic Rubber Dermal Rabbit LD50 > 15,000 mg/kg Synthetic Rubber Ingestion Rat LD50 > 30,000 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available Ammonia, O-Cresol, Formaldehyde, Phenol Polymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Phenolic Polymer - NJTSR No. 04499600-6305 Ingestion Rat LD50 5,660 mg/kg Salicylic Acid Dermal Rat LD50 > 2,000 mg/kg Salicylic Acid Ingestion Rat LD50 891 mg/kg Ethylene Glycol Ingestion Human LD50 1,600 mg/kg Ethylene Glycol Inhalation- Dust/Mist (4 hours) Other LC50 estimated to be 5 - 12.5 mg/l Ethylene Glycol Dermal Rabbit 9,530 mg/kg Zinc Oxide Dermal LD50 estimated to be > 5,000 mg/kg Zinc Oxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.7 mg/l Zinc Oxide Ingestion Rat LD50 > 5,000 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist Rat LC50 > 6.82 mg/l 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 10 of 18 (4 hours) Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Phenol Inhalation- Vapor LC50 estimated to be 2 - 10 mg/l Phenol Dermal Rat LD50 670 mg/kg Phenol Ingestion Rat LD50 340 mg/kg O-Cresol Dermal Rabbit LD50 890 mg/kg O-Cresol Inhalation- Vapor (4 hours) Rat LC50 > 24.5 mg/l O-Cresol Ingestion Rat LD50 121 mg/kg Formaldehyde Dermal Rabbit LD50 270 mg/kg Formaldehyde Inhalation- Gas (4 hours) Rat LC50 470 ppm Formaldehyde Ingestion Rat LD50 800 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Toluene Rabbit Irritant Methyl Isobutyl Ketone Rabbit Mild irritant Synthetic Rubber Professio nal judgeme nt No significant irritation Talc Rabbit No significant irritation Salicylic Acid Rabbit No significant irritation Ethylene Glycol Rabbit Minimal irritation Zinc Oxide Human and animal No significant irritation Titanium Dioxide Rabbit No significant irritation Phenol Rat Corrosive Formaldehyde official classifica tion Corrosive Serious Eye Damage/Irritation Name Species Value Toluene Rabbit Moderate irritant Methyl Isobutyl Ketone Rabbit Mild irritant Synthetic Rubber Professio nal judgeme nt No significant irritation Talc Rabbit No significant irritation Salicylic Acid Rabbit Corrosive Ethylene Glycol Rabbit Mild irritant Zinc Oxide Rabbit Mild irritant Titanium Dioxide Rabbit No significant irritation Phenol Rabbit Corrosive Formaldehyde official classifica tion Corrosive Skin Sensitization Name Species Value Toluene Guinea pig Not sensitizing Methyl Isobutyl Ketone Guinea pig Not sensitizing Phenolic Polymer - NJTSR No. 04499600-6305 Human Some positive data exist, but the data are not sufficient for classification 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 11 of 18 Salicylic Acid Mouse Not sensitizing Ethylene Glycol Human Some positive data exist, but the data are not sufficient for classification Zinc Oxide Guinea pig Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Human and animal Not sensitizing Phenol Guinea pig Not sensitizing Formaldehyde Guinea pig Sensitizing Photosensitization Name Species Value Salicylic Acid Mouse Not sensitizing Respiratory Sensitization Name Species Value Talc Human Not sensitizing Formaldehyde Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Methyl Isobutyl Ketone In Vitro Not mutagenic Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Salicylic Acid In Vitro Not mutagenic Salicylic Acid In vivo Not mutagenic Ethylene Glycol In Vitro Not mutagenic Ethylene Glycol In vivo Not mutagenic Zinc Oxide In Vitro Some positive data exist, but the data are not sufficient for classification Zinc Oxide In vivo Some positive data exist, but the data are not sufficient for classification Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Phenol In Vitro Some positive data exist, but the data are not sufficient for classification Phenol In vivo Some positive data exist, but the data are not sufficient for classification Formaldehyde In Vitro Some positive data exist, but the data are not sufficient for classification Formaldehyde In vivo Mutagenic Carcinogenicity Name Route Species Value Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Methyl Isobutyl Ketone Inhalation Multiple animal species Carcinogenic Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Ethylene Glycol Ingestion Multiple Not carcinogenic 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 12 of 18 animal species Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Phenol Dermal Mouse Some positive data exist, but the data are not sufficient for classification Phenol Ingestion Rat Some positive data exist, but the data are not sufficient for classification Formaldehyde Not Specified Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Methyl Isobutyl Ketone Inhalation Not toxic to female reproduction Multiple animal species NOAEL 8.2 mg/l 2 generation Methyl Isobutyl Ketone Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 13 weeks Methyl Isobutyl Ketone Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 8.2 mg/l 2 generation Methyl Isobutyl Ketone Inhalation Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 12.3 mg/l during organogenesi s Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Salicylic Acid Ingestion Toxic to development Rat NOAEL 75 mg/kg/day during organogenesi s Ethylene Glycol Ingestion Not toxic to female reproduction Multiple animal species NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Ingestion Not toxic to male reproduction Multiple animal species NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Dermal Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 3,549 mg/kg/day during organogenesi s Ethylene Glycol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse LOAEL 750 mg/kg/day during organogenesi s Ethylene Glycol Inhalation Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 1,000 mg/kg/day during organogenesi s Zinc Oxide Ingestion Some positive reproductive/developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 125 mg/kg/day premating & during gestation Phenol Ingestion Some positive female reproductive data Rat NOAEL 321 2 generation 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 13 of 18 exist, but the data are not sufficient for classification mg/kg/day Phenol Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 321 mg/kg/day 2 generation Phenol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 120 mg/kg/day during organogenesi s Formaldehyde Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 100 mg/kg not applicable Formaldehyde Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 10 ppm during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Methyl Isobutyl Ketone Inhalation central nervous system depression May cause drowsiness or dizziness Human LOAEL 0.10 mg/l 2 hours Methyl Isobutyl Ketone Inhalation respiratory irritation May cause respiratory irritation Human NOAEL 0.9 mg/l 7 minutes Methyl Isobutyl Ketone Inhalation vascular system Some positive data exist, but the data are not sufficient for classification Dog NOAEL Not available not available Methyl Isobutyl Ketone Ingestion central nervous system depression May cause drowsiness or dizziness Rat LOAEL 900 mg/kg not applicable Ethylene Glycol Ingestion heart | nervous system | kidney and/or bladder | respiratory system Causes damage to organs Human NOAEL Not available poisoning and/or abuse Ethylene Glycol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Ethylene Glycol Ingestion liver Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available poisoning and/or abuse Phenol Dermal hematoppoitic system Causes damage to organs Rat LOAEL 108 mg/kg not available Phenol Dermal heart | nervous system | kidney and/or bladder Causes damage to organs Rat LOAEL 107 mg/kg 24 hours Phenol Dermal liver Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available not available Phenol Inhalation respiratory irritation May cause respiratory irritation Multiple animal species NOAEL Not available not available Phenol Ingestion kidney and/or bladder Causes damage to organs Rat NOAEL 120 mg/kg/day not applicable Phenol Ingestion respiratory system Causes damage to organs Human NOAEL not available poisoning and/or abuse Phenol Ingestion endocrine system | liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 224 mg/kg not applicable Phenol Ingestion heart Some positive data exist, but the Human NOAEL Not poisoning 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 14 of 18 data are not sufficient for classification available and/or abuse Formaldehyde Inhalation respiratory system Causes damage to organs Rat LOAEL 128 ppm 6 hours Formaldehyde Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks Methyl Isobutyl Ketone Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.41 mg/l 13 weeks Methyl Isobutyl Ketone Inhalation heart Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.8 mg/l 2 weeks Methyl Isobutyl Ketone Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.4 mg/l 90 days Methyl Isobutyl Ketone Inhalation respiratory system All data are negative Multiple animal species NOAEL 4.1 mg/l 14 weeks Methyl Isobutyl Ketone Inhalation endocrine system | hematopoietic system All data are negative Multiple animal species NOAEL 0.41 mg/l 90 days Methyl Isobutyl Ketone Inhalation nervous system All data are negative Multiple animal NOAEL 0.41 mg/l 13 weeks 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 15 of 18 species Methyl Isobutyl Ketone Ingestion endocrine system | hematopoietic system | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 13 weeks Methyl Isobutyl Ketone Ingestion heart | immune system | muscles | nervous system | respiratory system All data are negative Rat NOAEL 1,040 mg/kg/day 120 days Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Salicylic Acid Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 500 mg/kg/day 3 days Ethylene Glycol Ingestion kidney and/or bladder | vascular system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 200 mg/kg/day 2 years Ethylene Glycol Ingestion heart | hematopoietic system | liver | immune system | muscles Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Ingestion respiratory system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 12,000 mg/kg/day 2 years Ethylene Glycol Ingestion skin | endocrine system | bone, teeth, nails, and/or hair | nervous system | eyes All data are negative Multiple animal species NOAEL 1,000 mg/kg/day 2 years Zinc Oxide Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 600 mg/kg/day 10 days Zinc Oxide Ingestion endocrine system | hematopoietic system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Other NOAEL 500 mg/kg/day 6 months Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.010 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available occupational exposure Phenol Dermal nervous system May cause damage to organs though prolonged or repeated exposure Rabbit LOAEL 260 mg/kg/day 18 days Phenol Inhalation heart | liver | kidney and/or bladder | respiratory system Causes damage to organs through prolonged or repeated exposure Guinea pig LOAEL 0.1 mg/l 41 days Phenol Inhalation nervous system May cause damage to organs though prolonged or repeated exposure Multiple animal species LOAEL 0.1 mg/l 14 days Phenol Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Phenol Inhalation immune system All data are negative Rat NOAEL 0.1 mg/l 2 weeks Phenol Ingestion kidney and/or bladder Causes damage to organs through prolonged or repeated exposure Rat NOAEL 12 mg/kg/day 14 days Phenol Ingestion hematopoietic system Causes damage to organs through prolonged or repeated exposure Mouse LOAEL 1.8 mg/kg/day 28 days Phenol Ingestion nervous system May cause damage to organs Rat LOAEL 308 13 weeks 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 16 of 18 though prolonged or repeated exposure mg/kg/day Phenol Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 40 mg/kg/day 14 days Phenol Ingestion respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 40 mg/kg/day 14 days Phenol Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.8 mg/kg/day 28 days Phenol Ingestion endocrine system All data are negative Rat NOAEL 120 mg/kg/day 14 days Phenol Ingestion skin | bone, teeth, nails, and/or hair All data are negative Multiple animal species NOAEL 1,204 mg/kg/day 103 weeks Formaldehyde Dermal respiratory system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 80 mg/kg/day 60 weeks Formaldehyde Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.3 ppm 28 months Formaldehyde Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20 ppm 13 weeks Formaldehyde Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 15 ppm 3 weeks Formaldehyde Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 10 ppm 13 weeks Formaldehyde Inhalation endocrine system | immune system | muscles | kidney and/or bladder All data are negative Rat NOAEL 15 ppm 28 months Formaldehyde Inhalation eyes | vascular system All data are negative Rat NOAEL 14.3 ppm 2 years Formaldehyde Inhalation heart All data are negative Mouse NOAEL 14.3 ppm 2 years Formaldehyde Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20 mg/kg/day 4 weeks Formaldehyde Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 15 mg/kg/day 24 months Formaldehyde Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 109 mg/kg/day 2 years Formaldehyde Ingestion heart | endocrine system | hematopoietic system | respiratory system | vascular system All data are negative Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion skin | muscles | eyes All data are negative Rat NOAEL 109 mg/kg/day 2 years Aspiration Hazard Name Value Toluene Aspiration hazard Methyl Isobutyl Ketone Some positive data exist, but the data are not sufficient for classification Please contact the address or phone number listed on the first page of the SDS for additional toxicological information 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 17 of 18 on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene), D023 (o-Cresol) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 15 - 40 Methyl Isobutyl Ketone 108-10-1 10 - 30 Ethylene Glycol 107-21-1 1 - 5 Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 1 - 5 15.2. State Regulations Contact 3M for more information. California Proposition 65 3M? Brushable Seam Sealer, P.N. 08656 01/21/15 __________________________________________________________________________________________ Page 18 of 18 Ingredient C.A.S. No. Classification Methyl Isobutyl Ketone 108-10-1 Carcinogen Methyl Isobutyl Ketone 108-10-1 Developmental Toxin Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin Titanium Dioxide 13463-67-7 Carcinogen Formaldehyde 50-00-0 Carcinogen Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-3353-9 Version Number: 47.00 Issue Date: 01/21/15 Supercedes Date: 05/06/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com