MATERIAL SAFETY DATA SHEET 3M? Long Strand Fiberglass Reinforced Filler PN 05813, 05814 08/22/12 _________________________________________________________________________________________________________ Page 1 of 2 Material Safety Data Sheet Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. PRODUCT NAME: 3M? Long Strand Fiberglass Reinforced Filler PN 05813, 05814 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 08/22/12 Supercedes Date: 04/23/09 Document Group: 24-8072-1 ID Number(s): 60-9800-4284-4, 60-9800-4285-1 This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for each of these components is included. Please do not separate the component MSDSs from this cover page. The document numbers of the MSDSs for components of this product are: 29-5993-0, 24-6797-5 Revision Changes: Kit: Component document group number(s) was modified. Section 1: Manufacturer name was added. Section 16: Disclaimer (first paragraph) was added. Section 16: Disclaimer (second paragraph) was added. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. MATERIAL SAFETY DATA SHEET 3M? Long Strand Fiberglass Reinforced Filler PN 05813, 05814 08/22/12 _________________________________________________________________________________________________________ Page 2 of 2 Company Logo was deleted. Copyright was deleted. Kit: Manufacturer's name was deleted. Kit: Emergency phone information was deleted. Kit: Disclaimer (first paragraph) was deleted. Kit: Disclaimer (second paragraph) was deleted. Kit: Address line 1 was deleted. Kit: Address line 2 was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 24-6797-5 Version Number: 7.00 Issue Date: 08/14/14 Supercedes Date: 12/27/12 SECTION 1: Identification 1.1. Product identifier 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 Product Identification Numbers LB-K100-0507-4, LB-K100-0567-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Body filler 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 3. Serious Eye Damage/Irritation: Category 2B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Health Hazard | 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 2 of 12 Pictograms Hazard Statements Flammable liquid and vapor. Causes eye irritation. Suspected of causing cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: liver | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Store locked up. 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 3 of 12 Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 7% of the mixture consists of ingredients of unknown acute oral toxicity. 43% of the mixture consists of ingredients of unknown acute dermal toxicity. 39% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 1,3-Isobenzofurandione, Polymer with 2,5-Furandione and 2,2'-Oxybis[ethanol] 26123-45-5 30 - 60 Trade Secret * Styrene Monomer 100-42-5 10 - 30 Trade Secret * Talc 14807-96-6 10 - 30 Trade Secret * Magnesium Carbonate 546-93-0 10 - 30 Trade Secret * Oxide Glass Chemicals 65997-17-3 1 - 5 Trade Secret * Fiberglass Trade Secret* 1 - 5 Trade Secret * Chlorite (Mineral) 1318-59-8 < 2 Trade Secret * Fiber Trade Secret* 0.5 - 1.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 4 of 12 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of dust created by cutting, sanding, grinding or machining. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed to prevent loss of stabilizing materials. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 5 of 12 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Styrene Monomer 100-42-5 ACGIH TWA:20 ppm;STEL:40 ppm A4: Not class. as human carcin Styrene Monomer 100-42-5 OSHA TWA:100 ppm;CEIL:200 ppm Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Magnesium Carbonate 546-93-0 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Oxide Glass Chemicals 65997-17-3 Manufacturer determined TWA(as dust):10 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA) Polymer laminate 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 6 of 12 Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Paste Odor, Color, Grade: Pungent Styrene odor Green paste Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 293 ?F Flash Point 88 ?F [Test Method: Closed Cup] Evaporation rate <=1 Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.1 % [Details: based on styrene] Flammable Limits(UEL) No Data Available Vapor Pressure 4.5 mmHg [Details: CONDITIONS: at 20 C] Vapor Density 3.6 [Ref Std: AIR=1] Density 1.32 g/ml Specific Gravity 1.32 [Ref Std: WATER=1] Solubility in Water Negligible Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 19.8 % weight [Test Method: Calculated] Volatile Organic Compounds 262 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 19.9 % weight [Test Method: calculated per CARB title 2] Percent volatile 19.9 % VOC Less H2O & Exempt Solvents 262 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Light Sparks and/or flames 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 7 of 12 Heat 10.5. Incompatible materials Strong acids Strong bases Strong oxidizing agents Water Alkali and alkaline earth metals 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 8 of 12 Target Organ Effects: Single exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Styrene Monomer 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens Styrene Monomer 100-42-5 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value 1,3-Isobenzofurandione, Polymer with 2,5-Furandione and 2,2'- Oxybis[ethanol] Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available Styrene Monomer Dermal Rat LD50 > 2,000 mg/kg Styrene Monomer Inhalation- Vapor (4 hours) Rat LC50 8.3 mg/l Styrene Monomer Ingestion Rat LD50 5,000 mg/kg Magnesium Carbonate Ingestion Mouse LD50 > 5,000 mg/kg Oxide Glass Chemicals Dermal LD50 estimated to be > 5,000 mg/kg Oxide Glass Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Talc Rabbit No significant irritation Styrene Monomer official classifica tion Mild irritant Magnesium Carbonate In vitro data Minimal irritation Oxide Glass Chemicals No significant irritation Serious Eye Damage/Irritation Name Species Value Talc Rabbit No significant irritation Styrene Monomer official Moderate irritant 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 9 of 12 classifica tion Magnesium Carbonate Rabbit Mild irritant Oxide Glass Chemicals No significant irritation Skin Sensitization Name Species Value Styrene Monomer Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Talc Human Not sensitizing Germ Cell Mutagenicity Name Route Value Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Styrene Monomer In Vitro Some positive data exist, but the data are not sufficient for classification Styrene Monomer In vivo Some positive data exist, but the data are not sufficient for classification Oxide Glass Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Styrene Monomer Ingestion Mouse Carcinogenic Styrene Monomer Inhalation Human and animal Carcinogenic Oxide Glass Chemicals Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Styrene Monomer Ingestion Not toxic to female reproduction Rat NOAEL 21 mg/kg/day 3 generation Styrene Monomer Inhalation Not toxic to female reproduction Rat NOAEL 2.1 mg/l 2 generation Styrene Monomer Inhalation Not toxic to male reproduction Rat NOAEL 2.1 mg/l 2 generation Styrene Monomer Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 60 days Styrene Monomer Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during gestation Styrene Monomer Inhalation Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2.1 mg/l during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 10 of 12 Name Route Target Organ(s) Value Species Test Result Exposure Duration Styrene Monomer Inhalation auditory system Causes damage to organs Multiple animal species LOAEL 4.3 mg/l not available Styrene Monomer Inhalation liver Causes damage to organs Mouse LOAEL 2.1 mg/l not available Styrene Monomer Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available occupational exposure Styrene Monomer Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Styrene Monomer Inhalation endocrine system All data are negative Rat NOAEL Not available not available Styrene Monomer Inhalation kidney and/or bladder All data are negative Multiple animal species NOAEL 2.1 mg/l not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Styrene Monomer Inhalation eyes Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Styrene Monomer Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Multiple animal species NOAEL 1.3 mg/l not available Styrene Monomer Inhalation liver May cause damage to organs though prolonged or repeated exposure Mouse LOAEL 0.85 mg/l 13 weeks Styrene Monomer Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Multiple animal species LOAEL 1.1 mg/l not available Styrene Monomer Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.85 mg/l 7 days Styrene Monomer Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.6 mg/l 10 days Styrene Monomer Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species LOAEL 0.09 mg/l not available Styrene Monomer Inhalation heart | bone, teeth, nails, and/or hair | muscles | kidney and/or bladder All data are negative Multiple animal species NOAEL 4.3 mg/l 2 years Styrene Monomer Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 500 mg/kg/day 8 weeks Styrene Monomer Ingestion immune system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available not available Styrene Monomer Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 677 mg/kg/day 6 months Styrene Monomer Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 600 mg/kg/day 470 days Styrene Monomer Ingestion heart | respiratory system All data are negative Rat NOAEL 35 mg/kg/day 105 weeks Oxide Glass Chemicals Inhalation respiratory system Some positive data exist, but the Human NOAEL not occupational 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 11 of 12 data are not sufficient for classification available exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. As a disposal alternative, Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Styrene Monomer 100-42-5 10 - 30 15.2. State Regulations Contact 3M for more information. 3M? Long Strand Fiberglass Reinforced Filler PN 5813, 5814 08/14/14 __________________________________________________________________________________________ Page 12 of 12 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 3 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? III ratings are to be used with a fully implemented HMIS? III program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 24-6797-5 Version Number: 7.00 Issue Date: 08/14/14 Supercedes Date: 12/27/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-5993-0 Version Number: 3.02 Issue Date: 02/21/14 Supercedes Date: 10/02/12 SECTION 1: Identification 1.1. Product identifier Cream Hardener (Red, White & Blue) Product Identification Numbers LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100- 0966-3, LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-7987-9, 60-4550-6614-6, 60-4550-6617-9, 60-4550- 6830-8, 60-4550-6981-9, 60-4550-6982-7, 60-4550-8123-6 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Organic Peroxide: Type E. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. 2.2. Label elements Signal word Warning Symbols Flame | Exclamation mark | Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 2 of 11 Pictograms Hazard Statements Heating may cause a fire. Causes serious eye irritation. May cause an allergic skin reaction. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from clothing and other combustible materials. Keep only in original container. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Storage: Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Store away from other materials. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Not applicable 2.3. Hazards not otherwise classified None. 6% of the mixture consists of ingredients of unknown acute dermal toxicity. 14% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 3 of 11 Benzoyl Peroxide 94-36-0 30 - 60 Trade Secret * Water 7732-18-5 10 - 30 Trade Secret * Benzoic Acid, C9-11-Branched Alkyl Esters 131298-44-7 10 - 30 Trade Secret * Zinc Stearate 557-05-1 3 - 7 Trade Secret * Oxirane, Polymer with Methyloxirane, Monobutyl Ether 9038-95-3 1 - 5 Trade Secret * Calcium Sulfate 7778-18-9 1 - 5 Trade Secret * Iron Oxide (FE2O3) 1309-37-1 1 - 5 Trade Secret * Ferric Ferrocyanide 14038-43-8 0 - 1 Trade Secret * Ferric Ammonium Ferrocyanide 25869-00-5 0 - 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied by the peroxide itself. 5.3. Special protective actions for fire-fighters No unusual fire or explosion hazards are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 4 of 11 provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed. Protect from sunlight. Store away from heat. Store at temperatures not exceeding 32C/90F. Keep cool. Keep only in original container. Store away from other materials. Keep/store away from clothing and other combustible materials. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Iron Oxide (FE2O3) 1309-37-1 Amer Conf of Gov. Indust. Hyg. TWA(respirable fraction):5 mg/m3 Iron Oxide (FE2O3) 1309-37-1 US Dept of Labor - OSHA TWA(as fume):10 mg/m3 CYANIDES 14038-43-8 US Dept of Labor - OSHA TWA(as CN):5 mg/m3 Skin Notation Zinc Stearate 557-05-1 US Dept of Labor - OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Calcium Sulfate 7778-18-9 Amer Conf of Gov. Indust. Hyg. TWA(inhalable fraction):10 mg/m3 Calcium Sulfate 7778-18-9 US Dept of Labor - OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 5 of 11 Benzoyl Peroxide 94-36-0 Amer Conf of Gov. Indust. Hyg. TWA:5 mg/m3 Benzoyl Peroxide 94-36-0 US Dept of Labor - OSHA TWA:5 mg/m3 Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists American Indust. Hygiene Assoc : American Industrial Hygiene Association Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Viscous Odor, Color, Grade: Red paste with slight ester odor Odor threshold No Data Available Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 6 of 11 pH No Data Available Melting point No Data Available Boiling Point No Data Available Flash Point 111 ?C [Test Method: Estimated] Evaporation rate No Data Available Flammability (solid, gas) Organic Peroxide: Type E. Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 1.2 g/cm3 Specific Gravity 1.2 [@ 25 ?C] [Ref Std: WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds 0 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2] Percent volatile 20 % [Details: Water is the volatile component] VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. Stable unless exposed to heat, flames and drying conditions. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Accelerators 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 7 of 11 present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: May be harmful in contact with skin. Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 4,339.3 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE 10.7 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Benzoyl Peroxide Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Benzoyl Peroxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 24.3 mg/l Benzoyl Peroxide Ingestion Rat LD50 > 5,000 mg/kg Benzoic Acid, C9-11-Branched Alkyl Esters Dermal Rabbit LD50 > 2,000 mg/kg Benzoic Acid, C9-11-Branched Alkyl Esters Inhalation- Dust/Mist (4 hours) Rat LC50 2 mg/l Benzoic Acid, C9-11-Branched Alkyl Esters Ingestion Rat LD50 > 5,000 mg/kg Zinc Stearate Dermal Rabbit LD50 > 2,000 mg/kg Zinc Stearate Ingestion Rat LD50 > 5,000 mg/kg Oxirane, Polymer with Methyloxirane, Monobutyl Ether Dermal Rabbit LD50 > 16,960 mg/kg Calcium Sulfate Ingestion Rat LD50 > 5,000 mg/kg Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation- Dust/Mist (4 hours) Rat LC50 > 5 mg/l Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Rat LD50 4,240 mg/kg Iron Oxide (FE2O3) Dermal Not available LD50 3,100 mg/kg Iron Oxide (FE2O3) Ingestion Not available LD50 3,700 mg/kg Ferric Ammonium Ferrocyanide Ingestion Rat LD50 > 5,110 mg/kg Ferric Ferrocyanide Ingestion Rat LD50 > 8,000 mg/kg Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 8 of 11 ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Benzoyl Peroxide Rabbit Minimal irritation Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit Minimal irritation Iron Oxide (FE2O3) Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Benzoyl Peroxide Rabbit Severe irritant Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit No significant irritation Iron Oxide (FE2O3) Rabbit No significant irritation Skin Sensitization Name Species Value Benzoyl Peroxide Human and animal Sensitizing Iron Oxide (FE2O3) Human Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Benzoyl Peroxide In Vitro Not mutagenic Benzoyl Peroxide In vivo Not mutagenic Iron Oxide (FE2O3) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Benzoyl Peroxide Ingestion Multiple animal species Not carcinogenic Benzoyl Peroxide Dermal Mouse Some positive data exist, but the data are not sufficient for classification Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Rat Not carcinogenic Iron Oxide (FE2O3) Inhalation Human Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Benzoyl Peroxide Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day premating & during gestation Benzoyl Peroxide Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 500 mg/kg/day premating & during gestation Benzoyl Peroxide Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 500 mg/kg/day premating & during gestation Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Not toxic to female reproduction Rat NOAEL 3,770 mg/kg/day 90 days Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Not toxic to male reproduction Rat NOAEL 3,770 mg/kg/day 90 days Oxirane, Polymer with Methyloxirane, Inhalation Some positive male reproductive data Rat NOAEL 1 2 weeks Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 9 of 11 Monobutyl Ether exist, but the data are not sufficient for classification mg/l Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation endocrine system | hematopoietic system | liver | nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL .005 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL .001 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation heart All data are negative Rat NOAEL .5 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 145 mg/kg/day 90 days Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion hematopoietic system All data are negative Rat NOAEL 500 mg/kg/day 2 years Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion heart | endocrine system | respiratory system All data are negative Rat NOAEL 3,770 mg/kg/day 90 days Iron Oxide (FE2O3) Inhalation pulmonary fibrosis | pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 10 of 11 Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Zinc Stearate (ZINC COMPOUNDS) 557-05-1 3 - 7 Benzoyl Peroxide 94-36-0 30 - 60 Ferric Ferrocyanide (CYANIDES) 14038-43-8 0 - 1 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 1 Special Hazards: Oxidizer National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Cream Hardener (Red, White & Blue) 02/21/14 __________________________________________________________________________________________ Page 11 of 11 HMIS Hazard Classification Health: 2 Flammability: 1 Physical Hazard: 1 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? III ratings are to be used with a fully implemented HMIS? III program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 29-5993-0 Version Number: 3.02 Issue Date: 02/21/14 Supercedes Date: 10/02/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com