1. IDENTIFICATION Product identifier Product Name SUPER GLUE 1 OZ Other means of identification Product Code 49450 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use This product is a cyanoacrylate-based adhesive Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 8 Warning Flammable liquids Revision Date 05-Jun-2015 Causes skin irritation Causes serious eye irritation May cause respiratory irritation Category 4 Combustible liquid SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep cool Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable. Unknown acute toxicity 15 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret ETHYL-2-CYANOACRYLATE 7085-85-0 60 - 100 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. _____________________________________________________________________________________________ Page 2 / 8 Revision Date 05-Jun-201549450 - SUPER GLUE 1 OZ Odor IrritatingAppearance Clear Physical state Liquid _____________________________________________________________________________________________ Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. Allow warm water to penetrate the bond and gently attempt to move bonded areas without pulling the skin away from bonded area. If symptoms persist, call a physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Keep product and empty container away from heat and sources of ignition. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. _____________________________________________________________________________________________ Page 3 / 8 49450 - SUPER GLUE 1 OZ Revision Date 05-Jun-2015 _____________________________________________________________________________________________ Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents, Water, Alcohols, Alkalis, Amines 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ETHYL-2-CYANOACRYLATE 7085-85-0 TWA: 0.2 ppm - - Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear Odor Irritating Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 8 Boiling point / boiling range 185 ?C / 365 ?F Remarks ? Method Flash point 86 ?C / 187 ?F pH No information available Evaporation rate No information available 49450 - SUPER GLUE 1 OZ Flammability (solid, gas) No information available Property Melting point / freezing point No information available Values Revision Date 05-Jun-2015 _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <20 g/l ( <2%) Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Water, Alcohols, Alkalis, Amines Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Will bond to skin. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ETHYL-2-CYANOACRYLATE 7085-85-0 > 5 mL/kg ( Rat ) - - Information on toxicological effects _____________________________________________________________________________________________ Page 5 / 8 Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Vapor pressure 1 mmHg @ 20?C Dynamic viscosity No information available Revision Date 05-Jun-2015 Vapor density No information available Relative density 1.06 Upper flammability limit: No information available Water solubility Insoluble in water 49450 - SUPER GLUE 1 OZ Solidifies Solubility in other solvents No information available Flammability Limit in Air No data available Partition coefficient No information available Lower flammability limit: No information available _____________________________________________________________________________________________ Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 4990 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 100 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA UN/ID no 3334 Proper shipping name: Aviation regulated liquid, n.o.s, (ethyl cyanoacrylate), Limited Quantity (LQ) Hazard Class 9 Packing Group III ERG Code 9A IMDG Proper shipping name: Not regulated _____________________________________________________________________________________________ Page 6 / 8 49450 - SUPER GLUE 1 OZ Revision Date 05-Jun-2015 _____________________________________________________________________________________________ 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ETHYL-2-CYANOACRYLATE 7085-85-0 X - - U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) _____________________________________________________________________________________________ Page 7 / 8 Health hazards 2 Flammability 2 Physical hazards 0 Personal protection B Health hazards 2 49450 - SUPER GLUE 1 OZ Flammability 2 Instability 0 Revision Date 05-Jun-2015 - HMIS NFPA _____________________________________________________________________________________________ HMIS (Hazardous Material Information System) Revision Date 05-Jun-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 8 / 8 Revision Date 05-Jun-201549450 - SUPER GLUE 1 OZ