Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: 97BR HIGH TACK SUPER ADHESIVE SEALANT 1.75 FL.OZ Item No: 80060 Product Type: Sealant 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight% ACGIH; TLV-TWA OSHA PEL ACETONE 67-64-1 >40 500 ppm 1000 ppm; 2400 mg/m3 ACRYLONITRILE-BUTADIENE POLYMER 9003-18-3 <20 Not listed Not listed PHENOLIC RESIN 25085-75-0 <10 Not listed Not listed METHYL ETHYL KETONE (BUTANONE) 78-93-3 <10 200 ppm 200 ppm; 590 mg/m3 N-HEXANE 110-54-3 <7 50 ppm 500 ppm; 1800 mg/m3 TALC 14807-96-6 <5 2 mg/m3 20 mppcf ETHYL ACETATE 141-78-6 <5 400 ppm 400 ppm; 1400 mg/m3 4,4 -ISOPROPYLIDENEDIPHENOL 80-05-7 <2 Not listed Not listed 3. HAZARDS IDENTIFICATION Toxicity: Moderately toxic by ingestion. Ethyl acetate may cause anemia. Prolonged and repeated exposure to methyl ethyl ketone and/or n-hexane may cause peripheral neuropathy by damaging peripheral nerve tissue (that of arms and legs) and result in muscular weakness and loss of sensation. Excessive inhalation causes headache, dizziness, nausea, and incoordination. Long term exposure to high concentrations of vapor may cause lung, liver or kidney damage. May cause eye, skin and respiratory irritation. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage (sometimes referred to as "solvent" or "painter's syndrome"). Symptoms include fatigue, concentration difficulties, anxiety, depression, rapid mood swings, and short-term memory loss. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation Signs and Symptoms of Exposure: Excessive overexposure may cause giddiness, dizziness, headache, nausea and in extreme cases, unconsciousness and respiratory depression. May cause pain, redness or swelling of the eyes and excessive blinking and tear production. Component Weight% NTP ACGIH Carcinogens IARC Carcinogen ACETONE 67-64-1 >40 Not known A4 - Not Classifiable as a Human Carcinogen TALC 14807-96-6 <5 male rat-some evidence, female rat- clear evidence, male mice-no evidence, female mice-no evidence A4- Not classifiable as a human carcinogen Group 3 Supplement 7, 1987 Monograph 42, 1987 4,4 -ISOPROPYLIDENEDIPHENOL 80-05-7 <2 male rat-equivocal; female rat-negative; male mice-negative; female mice-negative Aggravated Medical Condition: Persons with preexisting respiratory, liver, kidney, eye or skin diseases may be adversely affected. 1 of 3 ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: 800-255-3924 (ChemTel) International Emergency: +01-813-248-0585 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move to fresh air in case of accidental inhalation of vapours. If not breathing, give artificial respiration. Obtain medical attention. Skin Contact: Remove contaminated clothing. Wash area with soap and water. If irritation persists, seek medical attention Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. 5. FIRE FIGHTING MEASURES Flash Point ?F(C?): <0?F Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam. Special Fire-Fighting Procedures: Firefighters should wear self-contained breathing apparatus. Water spray may be ineffective on flames but should be used to keep fire-exposed containers cool. Hazardous Products of Combustion: Oxides of carbon Unusual Fire/Explosion Hazards: Closed containers may rupture or explode when exposed to extreme heat. Keep containers cool. Vapors may travel from container toward sources of ignition and flashback. Lower Explosive Limit: 1.0% Upper Explosive Limit: 13.0% 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Eliminate all sources of ignition. Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. 7. HANDLING AND STORAGE Storage: Store away from heat, sparks or open flame. Do not store at temperatures above 100?F (38?C). Handling: Do not use near heat, sparks or open flame. Vapors may accumulate readily and may ignite explosively. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Wash hands before eating and smoking. Keep container closed when not in use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses with side shields or chemical goggles. Skin: Neoprene or nitrile gloves recommended. Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: An approved organic vapor respirator should be worn when exposures are expected to exceed the applicable limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Yellow liquid Odor: Ketone odor Boiling Point: Not determined. pH: Does not apply Solubility in Water: Partial Specific Gravity: 0.91 VOC(Wt.%): 18.8% Vapor Pressure: 400 mm Hg Vapor Density (Air=1): 2.5 Evaporation Rate: >1 (air = 1) 10. STABILITY AND REACTIVITY Chemical Stability: Stable at normal conditions Hazardous Polymerization: Will not occur Incompatabilities: Strong oxidizers Conditions to Avoid: Keep away from heat, sparks and open flame. Hazardous Products of Combustion: Oxides of carbon 11. TOXICOLOGICAL INFORMATION See Section 3 97BR HIGH TACK SUPER ADHESIVE SEALANT 1.75 FL.OZ Product Name: Item No. 80060 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: D001/D035 as per 40CFR 261.21 and a TCLP waste per 261.24 (methyl ethyl ketone and benzene) 14. TRANSPORTATION INFORMATION DOT (49CFR 172) U.S. Department of Transportation - DOT - 49 CFR (Ground) DOT Shipping Name: Adhesives, Limited Quantity Hazard Class: Class 3, PG II UN/ID Number: UN 1133 IATA (Air) Proper Shipping Name: Consumer Commodity (Not more than 500 ml) Class or Division: Class 9 UN/ID Number: ID 8000 IMDG (Vessel) Proper Shipping Name: Adhesives, Limited Quantity Hazard Class: Class 3, PG II UN Number: UN 1133 Marine Pollutant: None 15. REGULATORY INFORMATION SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. N-HEXANE, 4,4-ISOPROPYLIDENEDIPHENOL California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 3 , REACTIVITY 0. Estimated HMIS Classification: HEALTH 2, FLAMMABILITY 3, PHYSICAL HAZARD 0 (NFPA is a registered trademark of the National Fire Protection Association) HMIS is a registered trademark of the National Paint and Coatings Association Product Name: Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106 Item No. 80060 Revision Number: 4 97BR HIGH TACK SUPER ADHESIVE SEALANT 1.75 FL.OZ Telephone No.: 1-87-Permatex (877) 376-2839 Prepared By: Denise Boyd, Manager-Environmental, Health & Safety Revision Date: May 14, 2012 << /ASCII85EncodePages false /AllowTransparency false /AutoPositionEPSFiles true /AutoRotatePages /All /Binding /Left /CalGrayProfile (Dot Gain 20%) /CalRGBProfile (sRGB IEC61966-2.1) /CalCMYKProfile (U.S. Web Coated \050SWOP\051 v2) /sRGBProfile (sRGB IEC61966-2.1) /CannotEmbedFontPolicy /Warning /CompatibilityLevel 1.6 /CompressObjects /Tags /CompressPages true /ConvertImagesToIndexed true /PassThroughJPEGImages true /CreateJDFFile false /CreateJobTicket false /DefaultRenderingIntent /Default /DetectBlends true /DetectCurves 0.0000 /ColorConversionStrategy /LeaveColorUnchanged /DoThumbnails false /EmbedAllFonts true /EmbedOpenType false /ParseICCProfilesInComments true /EmbedJobOptions true /DSCReportingLevel 0 /EmitDSCWarnings false /EndPage -1 /ImageMemory 1048576 /LockDistillerParams false /MaxSubsetPct 100 /Optimize true /OPM 1 /ParseDSCComments true /ParseDSCCommentsForDocInfo true /PreserveCopyPage true /PreserveDICMYKValues true /PreserveEPSInfo true /PreserveFlatness true /PreserveHalftoneInfo false /PreserveOPIComments false /PreserveOverprintSettings true /StartPage 1 /SubsetFonts true /TransferFunctionInfo /Apply /UCRandBGInfo /Preserve /UsePrologue false /ColorSettingsFile () /AlwaysEmbed [ true ] /NeverEmbed [ true ] /AntiAliasColorImages false /CropColorImages true /ColorImageMinResolution 300 /ColorImageMinResolutionPolicy /OK /DownsampleColorImages true /ColorImageDownsampleType /Bicubic /ColorImageResolution 300 /ColorImageDepth -1 /ColorImageMinDownsampleDepth 1 /ColorImageDownsampleThreshold 1.50000 /EncodeColorImages true /ColorImageFilter /DCTEncode /AutoFilterColorImages true /ColorImageAutoFilterStrategy /JPEG /ColorACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /ColorImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000ColorACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000ColorImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasGrayImages false /CropGrayImages true /GrayImageMinResolution 300 /GrayImageMinResolutionPolicy /OK /DownsampleGrayImages true /GrayImageDownsampleType /Bicubic /GrayImageResolution 300 /GrayImageDepth -1 /GrayImageMinDownsampleDepth 2 /GrayImageDownsampleThreshold 1.50000 /EncodeGrayImages true /GrayImageFilter /DCTEncode /AutoFilterGrayImages true /GrayImageAutoFilterStrategy /JPEG /GrayACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /GrayImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000GrayACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000GrayImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasMonoImages false /CropMonoImages true /MonoImageMinResolution 1200 /MonoImageMinResolutionPolicy /OK /DownsampleMonoImages true /MonoImageDownsampleType /Bicubic /MonoImageResolution 1200 /MonoImageDepth -1 /MonoImageDownsampleThreshold 1.50000 /EncodeMonoImages true /MonoImageFilter /CCITTFaxEncode /MonoImageDict << /K -1 >> /AllowPSXObjects false /CheckCompliance [ /None ] /PDFX1aCheck false /PDFX3Check false /PDFXCompliantPDFOnly false /PDFXNoTrimBoxError true /PDFXTrimBoxToMediaBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXSetBleedBoxToMediaBox true /PDFXBleedBoxToTrimBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXOutputIntentProfile () /PDFXOutputConditionIdentifier () /PDFXOutputCondition () /PDFXRegistryName () /PDFXTrapped /False /Description << /CHS /CHT /DAN /DEU /ESP /FRA /ITA /JPN /KOR /NLD (Gebruik deze instellingen om Adobe PDF-documenten te maken voor kwaliteitsafdrukken op desktopprinters en proofers. 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