3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 11-4207-4 Version Number: 19.00 Issue Date: 03/06/15 Supercedes Date: 10/26/12 SECTION 1: Identification 1.1. Product identifier 3M? Trim and Emblem Adhesive, PN 08063 Product Identification Numbers 60-9800-1663-2 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Acute Toxicity (inhalation): Category 4. Serious Eye Damage/Irritation: Category 2B. Skin Corrosion/Irritation: Category 2. Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 2 of 15 Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes eye irritation. Causes skin irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause drowsiness or dizziness. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 3 of 15 extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 28% of the mixture consists of ingredients of unknown acute dermal toxicity. 44% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Solvent Naphtha (Petroleum), Light Aliphatic 64742-89-8 < 40 Trade Secret * Heptane 142-82-5 < 40 Trade Secret * Methylcyclohexane 108-87-2 < 40 Trade Secret * Cyclohexane 110-82-7 10 - 30 Trade Secret * Hydrocarbon Resin 68132-00-3 10 - 30 Trade Secret * Styrene-Butadiene Polymer 9003-55-8 7 - 13 Trade Secret * Styrene-Isoprene Copolymer 25038-32-8 1 - 5 Trade Secret * Toluene 108-88-3 1 - 5 Trade Secret * Styrene/Alpha-Methylstyrene Copolymer 9011-11-4 1 - 5 Trade Secret * Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 1 - 5 Trade Secret * 2-Benzotriazolyl-4-Methylphenol 2440-22-4 < 0.15 Trade Secret * Talc 14807-96-6 < 0.15 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 4 of 15 See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Methane During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Ketones During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 5 of 15 precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Methylcyclohexane 108-87-2 ACGIH TWA:400 ppm Methylcyclohexane 108-87-2 OSHA TWA:2000 mg/m3(500 ppm) Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Heptane 142-82-5 OSHA TWA:2000 mg/m3(500 ppm) Heptane 142-82-5 ACGIH TWA:400 ppm;STEL:500 ppm Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 Solvent Naphtha (Petroleum), Light Aliphatic 64742-89-8 CMRG TWA:300 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 6 of 15 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Gel Odor, Color, Grade: clear, characteristic cyclohexane odor. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 140 ?F Flash Point -7 ?F [Test Method: Closed Cup] Evaporation rate 2.50 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 120 mmHg [Details: CONDITIONS: @ 68F] Vapor Density 3.00 [Ref Std: AIR=1] Density 0.860 g/ml Specific Gravity 0.860 [Ref Std: WATER=1] 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 7 of 15 Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Approximately 60,000 centipoise Hazardous Air Pollutants 4.49 % weight [Test Method: Calculated] Volatile Organic Compounds 479 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 54.9 % weight [Test Method: calculated per CARB title 2] Percent volatile 55.7 % weight VOC Less H2O & Exempt Solvents 479 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 8 of 15 and throat pain. May cause additional health effects (see below). Skin Contact: May be harmful in contact with skin. Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Prolonged or repeated exposure by ingestion may cause: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 2,000 - 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 10 - 20 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Heptane Dermal Rabbit LD50 3,000 mg/kg Heptane Inhalation- Vapor (4 hours) Rat LC50 103 mg/l Heptane Ingestion Rat LD50 > 15,000 mg/kg Methylcyclohexane Inhalation- Vapor (4 hours) Mouse LC50 26 mg/l Methylcyclohexane Dermal Rabbit LD50 > 86,700 mg/kg Methylcyclohexane Ingestion Rat LD50 > 3,200 mg/kg 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 9 of 15 Solvent Naphtha (Petroleum), Light Aliphatic Dermal Rabbit LD50 3,000 mg/kg Solvent Naphtha (Petroleum), Light Aliphatic Inhalation- Vapor (4 hours) Rat LC50 > 5.2 mg/l Solvent Naphtha (Petroleum), Light Aliphatic Ingestion Rat LD50 > 5,000 mg/kg Hydrocarbon Resin Ingestion LD50 estimated to be > 5,000 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Styrene-Butadiene Polymer Dermal Rabbit LD50 > 2,000 mg/kg Styrene-Butadiene Polymer Ingestion Rat LD50 > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Styrene-Isoprene Copolymer Dermal Not available LD50 > 2,000 mg/kg Styrene-Isoprene Copolymer Ingestion Not available LD50 > 2,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Rat LD50 > 5,110 mg/kg Styrene/Alpha-Methylstyrene Copolymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Heptane Human Mild irritant Methylcyclohexane Rabbit Minimal irritation Solvent Naphtha (Petroleum), Light Aliphatic Rabbit Irritant Hydrocarbon Resin Professio nal judgeme nt No significant irritation Cyclohexane Rabbit Mild irritant Styrene-Butadiene Polymer Professio nal judgeme nt No significant irritation Toluene Rabbit Irritant Styrene-Isoprene Copolymer Professio nal judgeme nt No significant irritation Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Talc Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Heptane Professio nal judgeme nt Moderate irritant Methylcyclohexane Rabbit Mild irritant Solvent Naphtha (Petroleum), Light Aliphatic Rabbit No significant irritation Hydrocarbon Resin Professio nal No significant irritation 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 10 of 15 judgeme nt Cyclohexane Rabbit Mild irritant Toluene Rabbit Moderate irritant Styrene-Isoprene Copolymer Professio nal judgeme nt No significant irritation Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Talc Rabbit No significant irritation Skin Sensitization Name Species Value Toluene Guinea pig Not sensitizing Styrene-Isoprene Copolymer Not sensitizing Synthetic Amorphous Silica, Fumed, Crystalline Free Human and animal Not sensitizing Respiratory Sensitization Name Species Value Talc Human Not sensitizing Germ Cell Mutagenicity Name Route Value Heptane In Vitro Not mutagenic Solvent Naphtha (Petroleum), Light Aliphatic In Vitro Not mutagenic Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Synthetic Amorphous Silica, Fumed, Crystalline Free In Vitro Not mutagenic Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Carcinogenicity Name Route Species Value Methylcyclohexane Inhalation Multiple animal species Not carcinogenic Solvent Naphtha (Petroleum), Light Aliphatic Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Cyclohexane Inhalation Not toxic to female reproduction Rat NOAEL 24 mg/l 2 generation 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 11 of 15 Cyclohexane Inhalation Not toxic to male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 6.9 mg/l 2 generation Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Heptane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Heptane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Heptane Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Methylcyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Methylcyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Solvent Naphtha (Petroleum), Light Aliphatic Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Solvent Naphtha (Petroleum), Light Aliphatic Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 12 of 15 Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Heptane Inhalation liver | nervous system | kidney and/or bladder All data are negative Rat NOAEL 12 mg/l 26 weeks Methylcyclohexane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.6 mg/l 12 months Methylcyclohexane Inhalation liver Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL 12 mg/l 10 weeks Cyclohexane Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system All data are negative Rat NOAEL 8.6 mg/l 30 weeks Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks Synthetic Amorphous Silica, Fumed, Crystalline Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 13 of 15 Free Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Aspiration Hazard Name Value Heptane Aspiration hazard Methylcyclohexane Aspiration hazard Solvent Naphtha (Petroleum), Light Aliphatic Aspiration hazard Cyclohexane Aspiration hazard Toluene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 14 of 15 Ingredient C.A.S. No % by Wt Toluene 108-88-3 1 - 5 Cyclohexane 110-82-7 10 - 30 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 11-4207-4 Version Number: 19.00 Issue Date: 03/06/15 Supercedes Date: 10/26/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M? Trim and Emblem Adhesive, PN 08063 03/06/15 __________________________________________________________________________________________ Page 15 of 15 3M USA SDSs are available at www.3M.com