3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 1 of 18 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 06-8243-5 Version Number: 32.02 Issue Date: 01/14/15 Supercedes Date: 05/15/14 SECTION 1: Identification 1.1. Product identifier 3M? Primer 94 Product Identification Numbers ID Number UPC ID Number UPC 70-0064-1371-3 70-0160-4782-4 00-21200-46201-6 70-0160-5476-2 00-21200-23930-4 70-0160-5477-0 00-21200-23929-8 70-0160-5478-8 00-21200-23926-7 70-0160-5497-8 00-21200-24481-0 70-0160-5499-4 00-21200-24479-7 70-0160-5500-9 00-21200-24478-0 70-0160-5501-7 00-21200-24477-3 70-0160-5506-6 00-21200-26207-4 70-0160-5507-4 00-21200-26206-7 70-0160-5508-2 00-21200-26205-0 70-0705-7964-7 00-21200-23925-0 70-0707-4298-9 00-21200-31530-5 H0-0017-3728-9 HB-0040-4920-9 HB-0042-9605-7 XI-0039-2700-5 XI-0039-2719-5 XI-0039-2857-3 XT-0007-0061-4 XT-0007-0096-0 1.2. Recommended use and restrictions on use Recommended use Surface Primer, Primer 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1. Aspiration Hazard: Category 1. 25645365 - ACDelco Windshield O/S Moisture Cleaning Kit 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 2 of 18 Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes eye irritation. May cause an allergic skin reaction. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs: sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | May cause damage to organs through prolonged or repeated exposure: sensory organs | Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 3 of 18 Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed: Call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Keep cool. Keep container tightly closed. Store locked up in a well-ventilated place. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 2% of the mixture consists of ingredients of unknown acute oral toxicity. 2% of the mixture consists of ingredients of unknown acute dermal toxicity. 4% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Cyclohexane 110-82-7 30 - 60 Trade Secret * Xylene 1330-20-7 20 - 35 Trade Secret * Ethyl Alochol 64-17-5 5 - 10 Trade Secret * Ethylbenzene 100-41-4 1 - 10 Trade Secret * Ethyl Acetate 141-78-6 1 - 5 Trade Secret * Acrylate Polymer (NJTS Reg No 04499600-5984P) Trade Secret* 1 - 5 Trade Secret * Chlorinated Polyolefin 68609-36-9 < 2 Trade Secret * Methyl Alcohol 67-56-1 0.1 - 1.0 Trade Secret * Epoxy Resin 25068-38-6 < 0.5 Trade Secret * Toluene 108-88-3 < 0.5 Trade Secret * Chlorobenzene 108-90-7 < 0.5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 4 of 18 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 5 of 18 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Protect from sunlight. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Chlorobenzene 108-90-7 ACGIH TWA:10 ppm A3: Confirmed animal carcin. Chlorobenzene 108-90-7 OSHA TWA:350 mg/m3(75 ppm) Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 CMRG TWA:50 ppm;STEL:75 ppm Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Ethyl Acetate 141-78-6 ACGIH TWA:400 ppm Ethyl Acetate 141-78-6 OSHA TWA:1400 mg/m3(400 ppm) 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 6 of 18 Ethyl Alochol 64-17-5 ACGIH STEL:1000 ppm A3: Confirmed animal carcin. Ethyl Alochol 64-17-5 OSHA TWA:1900 mg/m3(1000 ppm) Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm Skin Notation Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. Provide appropriate local exhaust ventilation on open containers. Use in a well- ventilated area. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Liquid Odor, Color, Grade: Amber colored, solvent odor Odor threshold No Data Available 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 7 of 18 pH Not Applicable Melting point Not Applicable Boiling Point 170 ?F Flash Point 1 ?F [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1 % Flammable Limits(UEL) 11 % Vapor Pressure 68 mmHg [@ 68 ?F] Vapor Density No Data Available Density 0.82 g/ml Specific Gravity 0.82 [@ 77 ?F] [Ref Std: WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 1 - 35 centipoise [@ 73.4 ?F ] Hazardous Air Pollutants 35.2 - 45.3 % weight [Test Method: Calculated] Hazardous Air Pollutants <=15.11 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 781 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: low solids less exempts] Percent volatile 95.3 - 97 % weight [Test Method: Estimated] VOC Less H2O & Exempt Solvents <=97 % [Test Method: calculated per CARB title 2] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 8 of 18 reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: May be harmful in contact with skin. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 9 of 18 Additional Information: This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 2,000 - 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l Xylene Ingestion Rat LD50 3,523 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Ethyl Alochol Dermal Rabbit LD50 > 15,800 mg/kg Ethyl Alochol Inhalation- Vapor (4 hours) Rat LC50 124.7 mg/l Ethyl Alochol Ingestion Rat LD50 17,800 mg/kg Ethyl Acetate Dermal Rabbit LD50 > 18,000 mg/kg Ethyl Acetate Inhalation- Vapor (4 hours) Rat LC50 70.5 mg/l Ethyl Acetate Ingestion Rat LD50 5,620 mg/kg Chlorinated Polyolefin Dermal Guinea pig LD50 > 1,000 mg/kg Chlorinated Polyolefin Ingestion Rat LD50 > 3,200 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg Epoxy Resin Dermal Rat LD50 > 1,600 mg/kg Epoxy Resin Ingestion Rat LD50 > 1,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Chlorobenzene Dermal Rabbit LD50 2,212 mg/kg Chlorobenzene Inhalation- Vapor (4 hours) Rat LC50 16.7 mg/l Chlorobenzene Ingestion Rat LD50 1,419 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 10 of 18 Name Species Value Cyclohexane Rabbit Mild irritant Xylene Rabbit Mild irritant Ethylbenzene Rabbit Mild irritant Ethyl Alochol Rabbit No significant irritation Ethyl Acetate Rabbit Minimal irritation Chlorinated Polyolefin Guinea pig No significant irritation Methyl Alcohol Rabbit Mild irritant Epoxy Resin Rabbit Mild irritant Toluene Rabbit Irritant Chlorobenzene Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Cyclohexane Rabbit Mild irritant Xylene Rabbit Mild irritant Ethylbenzene Rabbit Moderate irritant Ethyl Alochol Rabbit Moderate irritant Ethyl Acetate Rabbit Mild irritant Chlorinated Polyolefin Mild irritant Methyl Alcohol Rabbit Moderate irritant Epoxy Resin Rabbit Moderate irritant Toluene Rabbit Moderate irritant Chlorobenzene Rabbit Mild irritant Skin Sensitization Name Species Value Ethylbenzene Human Not sensitizing Ethyl Alochol Human Some positive data exist, but the data are not sufficient for classification Ethyl Acetate Guinea pig Not sensitizing Methyl Alcohol Guinea pig Not sensitizing Epoxy Resin Human and animal Sensitizing Toluene Guinea pig Not sensitizing Chlorobenzene Multiple animal species Not sensitizing Respiratory Sensitization Name Species Value Epoxy Resin Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Ethyl Alochol In Vitro Some positive data exist, but the data are not sufficient for classification 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 11 of 18 Ethyl Alochol In vivo Some positive data exist, but the data are not sufficient for classification Ethyl Acetate In Vitro Not mutagenic Ethyl Acetate In vivo Not mutagenic Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Epoxy Resin In vivo Not mutagenic Epoxy Resin In Vitro Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Chlorobenzene In Vitro Not mutagenic Carcinogenicity Name Route Species Value Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Ethylbenzene Inhalation Multiple animal species Carcinogenic Ethyl Alochol Ingestion Multiple animal species Some positive data exist, but the data are not sufficient for classification Methyl Alcohol Inhalation Multiple animal species Not carcinogenic Epoxy Resin Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Chlorobenzene Ingestion Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Cyclohexane Inhalation Not toxic to female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not toxic to male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 6.9 mg/l 2 generation Xylene Ingestion Not toxic to female reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Ingestion Not toxic to male reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Xylene Ingestion Some positive developmental data exist, Mouse NOAEL Not during 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 12 of 18 but the data are not sufficient for classification available organogenesi s Xylene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available during gestation Ethylbenzene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 4.3 mg/l premating & during gestation Ethyl Alochol Inhalation Not toxic to development Rat NOAEL 38 mg/l during gestation Ethyl Alochol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 5,200 mg/kg/day premating & during gestation Methyl Alcohol Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 1,600 mg/kg/day 21 days Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 mg/kg/day during organogenesi s Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s Epoxy Resin Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation Epoxy Resin Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation Epoxy Resin Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s Epoxy Resin Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Chlorobenzene Inhalation Not toxic to female reproduction Rat NOAEL 2.07 mg/l 2 generation Chlorobenzene Ingestion Not toxic to development Rat NOAEL 300 mg/kg/day during organogenesi s Chlorobenzene Inhalation Not toxic to development Rat NOAEL 2.07 mg/l 2 generation Chlorobenzene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.07 mg/l 2 generation Lactation Name Route Species Value Xylene Ingestion Mouse Does not cause effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 13 of 18 data are not sufficient for classification and animal available Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.5 mg/l not available Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg not applicable Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethyl Alochol Inhalation central nervous system depression May cause drowsiness or dizziness Human LOAEL 2.6 mg/l 30 minutes Ethyl Alochol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human LOAEL 9.4 mg/l not available Ethyl Alochol Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL not available Ethyl Alochol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Dog NOAEL 3,000 mg/kg Ethyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethyl Acetate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Ethyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure Methyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 hours Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse Methyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Chlorobenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Chlorobenzene Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not occupational 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 14 of 18 data are not sufficient for classification available exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Cyclohexane Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system All data are negative Rat NOAEL 8.6 mg/l 30 weeks Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | hematopoietic system | muscles | kidney and/or bladder | respiratory system All data are negative Multiple animal species NOAEL 3.5 mg/l 13 weeks Xylene Ingestion auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system All data are negative Mouse NOAEL 1,000 mg/kg/day 103 weeks Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Some positive data exist, but the data are not sufficient for Mouse NOAEL 3.3 mg/l 103 weeks 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 15 of 18 classification Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles All data are negative Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system All data are negative Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 680 mg/kg/day 6 months Ethyl Alochol Inhalation liver Some positive data exist, but the data are not sufficient for classification Rabbit LOAEL 124 mg/l 365 days Ethyl Alochol Inhalation hematopoietic system | immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25 mg/l 14 days Ethyl Alochol Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat LOAEL 8,000 mg/kg/day 4 months Ethyl Alochol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Dog NOAEL 3,000 mg/kg/day 7 days Ethyl Acetate Inhalation endocrine system | liver | nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.043 mg/l 90 days Ethyl Acetate Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rabbit LOAEL 16 mg/l 40 days Ethyl Acetate Ingestion hematopoietic system | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3,600 mg/kg/day 90 days Methyl Alcohol Inhalation liver All data are negative Rat NOAEL 6.55 mg/l 4 weeks Methyl Alcohol Inhalation respiratory system All data are negative Rat NOAEL 13.1 mg/l 6 weeks Methyl Alcohol Ingestion liver | nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 90 days Epoxy Resin Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years Epoxy Resin Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks Epoxy Resin Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 16 of 18 Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks Chlorobenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.69 mg/l 2 generation Chlorobenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.1 mg/l 2 generation Chlorobenzene Inhalation blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.35 mg/l 24 weeks Chlorobenzene Ingestion bone marrow Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg/day 13 weeks Chlorobenzene Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 188 mg/kg/day 192 days Chlorobenzene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 125 mg/kg/day 13 weeks Chlorobenzene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 750 mg/kg/day 13 weeks Aspiration Hazard Name Value Cyclohexane Aspiration hazard Xylene Aspiration hazard Ethylbenzene Aspiration hazard Toluene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 17 of 18 and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D021 (Chlorobenzene) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 30 - 60 Xylene 1330-20-7 20 - 35 Ethylbenzene 100-41-4 1 - 10 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Primer 94 01/14/15 __________________________________________________________________________________________ Page 18 of 18 SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 06-8243-5 Version Number: 32.02 Issue Date: 01/14/15 Supercedes Date: 05/15/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com