SAFETY DATA SHEET Prepared according to USA OSHA Hazcom 2012 / Canada WHMIS 2015 Date Prepared : 06/03/2015 MSDS No : GM12378500_ENG 12378500 Medium Body Seam Sealing Compound - White 1. PRODUCT AND COMPANY IDENTIFICATION Product Name : 12378500 Medium Body Seam Sealing Compound - White Product Description: White adhesive / sealant, 300 ml / 10.1 fl oz US General Use : Adhesive / sealant, designed exclusively for automotive uses Product Stock/Code : 10-2013 / 12378500 Chemical Family : Solvent-based / ? base de solvant Molecular Formula : Mixture / M?lange Manufacturer / Supplier Distributor Dominion Sure Seal Ltd. 6175 Danville Road, Mississauga Ontario, Canada L5T 2H7 Customer Service: 905-670-5411 ACDelco 6200 Grand Pointe Drive Grand Blanc, Michigan 48439 Customer Service: 1-800-223-3526 E-Mail: www.acdelco.com Emergency Telephone Numbers (24 hour) CANUTEC : (613) 996-6666 CHEMTREC : (800) 424-9300 2. HAZARDS IDENTIFICATION GHS CLASSIFICATIONS Health: Skin Irritation, Category 2 Target Organ Toxicity (Single exposure), Category 3 Target Organ Toxicity (Repeated exposure), Category 2 Reproductive Toxicity, Category 2 Carcinogenicity, Category 2 Physical: Flammable Liquids, Category 2 GHS LABEL Hazardous components for labelling: Toluene Flame Exclamation mark Health hazard SIGNAL WORD: DANGER HAZARD STATEMENTS Page 1 of 11 10-2013, 12378500 - ACDelco Medium Body Seam Sealing Compound H225: Highly flammable liquid and vapour. H315: Causes skin irritation. H336: May cause drowsiness or dizziness. H373: May cause damage to organs through prolonged or repeated exposure. H361: Suspected of damaging fertility or the unborn child. PRECAUTIONARY STATEMENT(S) Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof electrical / ventilating / lighting equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P264: Wash hands thoroughly after handling. P260: Do not breathe mist, vapours or spray. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves and eye protection. Response: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P332+P313: If skin irritation occurs: Get medical advice/attention. P362+P364: Take off contaminated clothing and wash it before reuse. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P370+P378: In case of fire: Use dry chemical or foam to extinguish. Storage: P403+P235: Store in a well-ventilated place. Keep cool. P233: Keep container tightly closed. Disposal: P501: Dispose of contents/container in accordance with applicable local, regional and/or national regulations. Emergency Overview Immediate Concerns: Flammable liquid and vapor. Harmful if inhaled. Possible risk of harm to the unborn child. Moderately irritating to the skin. Vapours may cause drowsiness and dizziness. Hazards Not Otherwise Classified: No data available. Comments: This product is a consumer product and is labeled in accordance with the Canadian Consumer Chemicals and Containers Regulations and US Consumer Product Safety Commission regulations which take precedence over Canadian WHMIS 2015 and OSHA Hazcom 2012 Hazard Communication labeling. The actual container label will not include the above label elements. The labeling above applies to products used solely for industrial / professional use. 3. COMPOSITION / INFORMATION ON INGREDIENTS 12378500 Medium Body Seam Sealing Compound - White Page 2 of 11 Chemical Name Wt.% CAS No. Toluene 30 - 35 108-88-3 Titanium dioxide 1 - 2 13463-67-7 Comments: There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the product and hence require reporting in this section. 4. FIRST AID MEASURES Eye Contact: In case of contact, immediately flush eyes, keeping eyelids open, with plenty of water for at least 15 minutes. Get medical attention, if irritation persists. Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists. Remove contaminated clothing and wash before reuse. Ingestion: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Signs and Symptoms of Overexposure Eye Contact: Mildly irritating to the eyes. Symptoms may include tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Skin Contact: Contact causes skin irritation. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Ingestion: Substance may be harmful if swallowed. May cause irritation. Symptoms of ingestion may include abdominal pain, nausea, vomiting and diarrhea. Inhalation: High vapor or spray mist concentrations may be harmful if inhaled. May cause headaches and dizziness. High vapor concentrations may cause drowsiness. Notes to Physician: Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. Additional Information: No data available. 5. FIRE FIGHTING MEASURES Flammable Properties: Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at or above the flash point. Product can be ignited by static discharge. Extinguishing Media: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Hazardous Combustion Products: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. 12378500 Medium Body Seam Sealing Compound - White Page 3 of 11 Fire Fighting Procedures: Containers can build up pressure if exposed to heat (fire). Fire Fighting Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. Sensitivity to Static Discharge: Product is sensitive to static discharge. Sensitivity to Mechanical Impact: Product is not sensitive to mechanical impact. 6. ACCIDENTAL RELEASE MEASURES Small Spill: Eliminate all ignition sources. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Sweep up material being careful not to raise dust. Place in an appropriate disposal container and seal tightly. Environmental Precautions Water Spill: Do not flush to sewer. Land Spill: Avoid runoff into storm sewers and ditches which lead to waterways. Special Protective Equipment: Clean up spills immediately, observing precautions in Protective Equipment section 8. 7. HANDLING AND STORAGE General Procedures: Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of flammable liquids. Ensure thorough ventilation of stores and work areas. Handling: Do not use in the presence of open flame or spark. Use only in a well ventilated area. Wear recommended personal protective equipment. Keep container closed when not in use. Avoid breathing vapours or mist. Avoid contact with eyes, skin, and clothing. After handling, always wash hands thoroughly with soap and water. Storage: Store away from heat, sparks, open flames, strong oxidizing agents and direct sunlight. Protect from physical damage. Keep container tightly closed and in a well-ventilated place. Store in a cool place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) Occupational Exposure Limits OSHA PEL ACGIH TLV NIOSH REL Chemical Name ppm mg/m3 ppm mg/m3 ppm mg/m3 Toluene TWA 200 50 188 100 375 STEL 300 150 560 Titanium dioxide TWA 15 T 10 NL NL STEL NL NL 12378500 Medium Body Seam Sealing Compound - White Page 4 of 11 Engineering Controls: Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits. Personal Protective Equipment Eyes and Face: Wear safety glasses with side shields (or goggles). Contact lenses should not be worn when working with this product. Eye wash fountains should be readily available to areas of use and handling. Skin Contact: Wear chemical resistant gloves. Respiratory: If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved respirator must be worn. Respirator type: NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Protective Clothing: Wear protective clothing as necessary to prevent contact. Work Hygienic Practices: Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing/wash thoroughly before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State : Liquid Odor : Aromatic Odor Threshold : 1.7 to 40 ppm Appearance : Viscous thixotropic paste Color : White pH : Not Applicable % Volatiles : 30 to 35 % w/w Flash Point and Method : 4 ?C Setaflash Closed Cup (Toluene) Flammable Limits : 1.1 to 7.1 Notes: Based on data for toluene. Autoignition Temperature : 480?C Notes: Based on data for toluene. Vapor Pressure : 3.8 kPa (21 mm Hg) [Toluene] at 20?C Vapor Density : 3.1 (air = 1) Boiling Point : 110 ?C (Toluene) Freezing Point : No data available. Melting Point : No data available. Solubility in Water : Practically insoluble Evaporation Rate 12378500 Medium Body Seam Sealing Compound - White Page 5 of 11 (n-butyl acetate = 1) : 2.24 Density : 1.17?0.03g/ml at 20?C Viscosity : > 200000 cps VOC Content : 400 g/l (3.34 lb/gal), less exempt solvents Partition Coefficient (n-octanol/water) : No data available. Oxidizing Properties : None Comments: VOC Compliance Statement VOC Content: Less Exempts: 400 g/l (3.34 lb/gal) Total Material: 400 g/l (3.34 lb/gal) Density: 1.15 to 1.20 g/ml Total Volatiles: 30 to 35 % w/w Exempt Content: 0 % w/w; 0 % v/v VOC Regulation: SCAQMD Rule 1168 -Adhesives & Sealants - California Coating Category: Sealants and Caulks, All Other Sealants The product VOC content meets the 420 g/l limit for Underbody Coatings. The product also meets the small container exemption in the various Adhesives and Sealants district rules - packaged in ? 475 ml (16 fl oz) cartridges. California compliant. VOC Regulation: CARB, OTC ? Consumer Product Regulations Coating Category: Sealant & Caulking Compounds This product is formulated for automotive use only and is not regulated under the CARB Consumer Products Regulations. It does not meet the CARB definition of Sealant & Caulking compounds which excludes "exclusive automotive use" sealants from the scope of the definition. 10. STABILITY AND REACTIVITY Reactive Hazard : No Hazardous Polymerization: Not expected to occur. Stability: Stable. Conditions to Avoid: Keep away from flames and any object that sparks. Possibility of Hazardous Reactions: Not Available Hazardous Decomposition Products: Carbon Monoxide and other toxic vapors. Incompatible Materials: Oxidizing materials. 11. TOXICOLOGICAL INFORMATION 12378500 Medium Body Seam Sealing Compound - White Page 6 of 11 Product Acute Toxicity Chemical Name ORAL LD50 mg/kg(rat) DERMAL LD50 mg/kg(rabbit) INHALATION LC50 mg/l Toluene 7000, 6400, 5500 12,270 49.0(rat;4h) 30.0(mouse;2h) 19.9(mouse;7h) Acute Toxicity - Dermal LD50: The calculated ATE is >2000 mg/kg. Notes: Based on available data, the classification criteria for Acute Dermal Toxicity are not met for this mixture. Acute Toxicity - Oral LD50: The calculated ATE is >2000 mg/kg. Notes: Based on available data, the classification criteria for Acute Oral Toxicity are not met for this mixture. Acute Toxicity - Inhalation LC50: The calculated ATE is >20 mg/l/4h (vapours) and >5 mg/l/4h (mists). Notes: Based on available data, the classification criteria for Acute Toxicity - inhalation are not met for this mixture. Toxicological Data: < 5% of the mixture consists of an ingredient or ingredients of unknown acute toxicity. No additional toxicology information is available for this product itself. (See Component Toxicity Information). Eye Irritation / Serious Eye Damage: Based on available data, the classification criteria for eye irritation are not met for this mixture. Slightly irritating but does not injure eye tissue. Skin Irritation / Corrosion: Contains: Toluene. Causes skin irritation. The mixture is classified as: Skin Irritant, category 2, based on summation of ingredient data (>10% ingredients classified as skin irritant, category 2). Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Carcinogenicity Chemical Name NTP Status IARC Status OSHA Status Other Toluene None 3 None -- Titanium dioxide None 2B None -- Notes: Based on available data, the classification criteria for Carcinogenicity are not met for this mixture. Titanium dioxide is listed as Group 2B (possibly carcinogenic to humans) Titanium dioxide: applies only to respirable dust. The product is unlikely to form a respirable dust. Specific Target Organ Toxicity - Repeated Exposure: The mixture is classified as: Specific Target Organ Toxicity - Repeated Exposure, category 2, based on ingredient data using the applicable cut-off/concentration limits (? 1.0% ingredients classified as Specific Target Organ Toxicity - Repeated Exposure, category 2). Prolonged inhalation may be harmful. Chronic exposure to organic solvents such as Toluene have been associated with various neurotoxic effects including permanent brain and nervous system damage. Symptoms include: loss of memory, loss of intellectual ability, and loss of coordination. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Respiratory / Skin Sensitizer: Based on available data, the classification criteria for skin/respiratory sensitization are not met for this mixture (< 0.1% ingredients classified as a skin sensitizer, category 1 or sub-category 1A and < 1.0% ingredients classified as a skin/respiratory sensitizer, sub-category 1B). 12378500 Medium Body Seam Sealing Compound - White Page 7 of 11 Reproductive Toxicity: The mixture is classified as: Reproductive Toxicity, category 2 based on ingredient data using the applicable cut- off/concentration limits (? 0.1% ingredients classified as Reproductive Toxicity, category 2). May cause adverse reproductive effects. Possible risk of harm to the unborn child (Toluene). Specific Target Organ Toxicity - Single Exposure: Contains: Acetone and Toluene. The mixture is classified as: Specific Target Organ Toxicity - Single Exposure, category 3, based on summation of ingredient data using the applicable cut-off/concentration limits (? 20% summation of all ingredients classified as Specific Target Organ Toxicity - Single Exposure, category 3). Can cause central nervous system depression (including unconsciousness). High vapor concentrations may cause drowsiness. May cause headaches and dizziness. Germ Cell Mutagenicity: Based on available data, the classification criteria for Germ Cell Mutagenicity are not met for this mixture (< 0.1% ingredients classified as Germ Cell Mutagen, category 1A or 1B and < 1.0% ingredients classified as Germ Cell Mutagen, category 2). Aspiration Hazard: Based on available data, the classification criteria for Aspiration Hazard are not met for this mixture (< 10% ingredients classified as an Aspiration Hazard, category 1 and/or mixture viscosity > 20.5 mm2/s at 40 ?C). 12. ECOLOGICAL INFORMATION Environmental Data: No data available. Ecotoxicological Information: No data available. Bioaccumulation/Accumulation: No data available. Distribution: No data available. Aquatic Toxicity (Acute): No data available. Chemical Fate Information: No data available. 13. DISPOSAL CONSIDERATIONS Disposal Method: Comply with applicable local, state or international regulations concerning solid or hazardous waste disposal and/or container disposal. Do not discharge substance/product into sewer system. Product Disposal: Empty containers retain product residue; observe all precautions for product. Decontaminate containers prior to disposal. 14. TRANSPORT INFORMATION DOT (Department of Transportation) Proper Shipping Name : ADHESIVES Primary Hazard Class/Division: 3 UN/NA Number : 1133 Packing Group : II Label : Flammable Liquid 12378500 Medium Body Seam Sealing Compound - White Page 8 of 11 Note: With an inner packaging < 1.0 L, this product may be shipped as a Limited Quantity. Vessel (IMO/IMDG) Shipping Name : ADHESIVES UN/NA Number : 1133 Primary Hazard Class/Division: 3 Packing Group : II Marine Pollutant : None Label : Flammable Liquid Note: With an inner packaging < 1.0 L, this product may be shipped as a Limited Quantity. Canadian Transportation of Dangerous Goods Regulations Shipping Name : ADHESIVES UN/NA Number : 1133 Primary Hazard Class/Division: 3 Packing Group : II Label : Flammable Liquid TDG Note: With an inner packaging < 1.0 L, this component may be shipped as a Limited Quantity as per TDG Section 1.17. 15. REGULATORY INFORMATION UNITED STATES SARA Section 311/312 Hazard Categories Fire Hazard : Yes Sudden Release of Pressure : No Reactive Hazard : No Product Acute Toxicity : Yes Product Chronic Toxicity : Yes EPCRA Section 313 Toxic Chemicals Chemical Name Wt.% CAS No. Toluene 30 - 35 108-88-3 EPCRA Section 302 Extremely Hazardous Substances EPCRA Status: This product contains no listed extremely hazardous substances that are subject to the reporting requirements of SARA Title III, Section 302. CERCLA Hazardous Substances and Reportable Quantities (RQ) Chemical Name Wt.% RQ Toluene 30 - 35 1,000 TSCA (The Toxic Substances Control Act) TSCA Status: 12378500 Medium Body Seam Sealing Compound - White Page 9 of 11 All components are included or are otherwise exempt from inclusion on this inventory. CAA 112(b) - Hazardous Air Pollutants Chemical Name Wt.% CAS No. Toluene 30 - 35 108-88-3 CAA 112(r) - List of Substances for Accidental Release Prevention: This product contains no chemicals subject to CAA 112(r). California Proposition 65 Chemical Name Wt.% Listed Toluene 30 - 35 Developmental Toxicity Female Reproductive OSHA Hazard Communication Standard (29 CFR 1910.1200): OSHA Status: Hazardous Product (See Section 2 for details). This product has been classified in accordance with the hazard criteria of the USA OSHA Hazard Communication Standard (29CFR 1910.1200) and the Safety Data Sheet contains all the information required by the OSHA Hazard Communication Standard (HazCom 2012). CANADA WHMIS Hazard Symbol and Classification See Section 2 for details. WHMIS Regulatory Status: This product has been classified in accordance with the hazard criteria of the Canadian Hazardous Products Regulations and the Safety Data Sheet contains all the information required by the Hazardous Products Regulations (WHMIS 2015). WHMIS Classification: WHMIS 2015 (Canada) Status: Hazardous Product (See Section 2 for details). CEPA - National Pollutant Release Inventory (NPRI): Name CAS No. NPRI Part No. Toluene 108-88-3 1A, 5 (VOC) Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components are included or are otherwise exempt from inclusion on this inventory. Comments VOC Content -- See section 9. 16. OTHER INFORMATION Reason for Issue: NEW Prepared By : Product Regulatory Department Date Prepared: 06/03/2015 Information Contact: 1-800-223-3526 12378500 Medium Body Seam Sealing Compound - White Page 10 of 11 HMIS RATING HEALTH * 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 PERSONAL PROTECTION G NFPA CODES 3 2 0 NFPA 30 / 30B Storage Classification: Flammable Liquid IB Manufacturer Supplemental Notes: None Data Sources: Not Available Additional MSDS Information: N/AV Not Available N/AP Not Applicable ND Not yet determined CAA The Clean Air Act CCCR The Consumer Chemicals and Containers Regulations CEPA The Canadian Environmental Protection Act CERCLA Comprehensive Environmental Response, Compensation, and Liability Act EPCRA The Emergency Planning and Community Right-To-Know Act IARC International Agency for Research on Cancer MSHA Mine Safety and Health Administration NIOSH National Institute for Occupational Safety and Health NTP National Toxicology Program OSHA The Occupational Safety and Health Act SARA The Superfund Amendments and Reauthorization Act WHMIS Workplace Hazardous Materials Information System General Statements: None Comments: None Manufacturer Disclaimer: The information contained herein is based on data considered accurate. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. No responsibility is assumed for personal injury or property damage to vendees or users or third parties, caused by the material. Such vendees or users assume all risks with the use of this material. 12378500 Medium Body Seam Sealing Compound - White Page 11 of 11