Page 1 of 8 Safety Data Sheet Section 1: Identification Product Identifier Ice removal Product Name Trade Name: SPLASH Pet Safe Ice Melt 8# Jug PN (Part number): 135004 Relevant identified uses of the substance or mixture and uses advised against -Material for industrial applications -Industrial and professional use -Consumer end use Details of the supplier of the safety data sheet Manufacturer SPLASH Products 51 E. Maryland Ave. St. Paul, MN 55117 Phone: (651) 489-8211 Emergency telephone number 1-800-535-5053 Section 2: Hazard(s) Identification OSHA/HCS status This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Not a hazardous substance or mixture. GHS label elements Hazard pictograms-No Pictograms Signal word-No Signal Words Hazard statements-No Hazard Statements Precautionary statements Prevention Not a hazardous substance or mixture. Response IF SWALLOWED: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. IF ON SKIN (or hair): Wash with soap and water. Get medical attention if irritation develops. Cold water may be used. Page 2 of 8 IF IN EYES: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. IF EXPOSED or CONCERNED: Immediately call a POISON CENTER or a doctor/physician. Storage Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified Product is stable. Section 3: Composition/Information on Ingredients Substance/mixture: Mixture Chemical name: N/A Other means of identification: No CAS number/other identifiers Ingredient name % CAS number Magnesium Chloride <100 7786-30-3 Section 4: First Aid Measurements Description of necessary first aid measures Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention if irritation persists. Inhalation: Bring accident victims out into the fresh air. Call a physician immediately in severe cases or if recovery is not rapid. Skin contact: After contact with skin, wash immediately with plenty of water. Remove contaminated clothing and wash before reuse. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Not an eye irritant. Inhalation Not an inhalation hazard. Skin contact Does not irritate the skin. Ingestion Not dangerous if swallowed. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Exposure may aggravate acute or chronic asthma, emphysema and bronchitis. Specific treatments N/A Page 3 of 8 Protection of first-aiders N/A See toxicological information (Section 11) Section 5: Fire Fighting Measures Extinguishing media Suitable extinguishing media SMALL FIRE: Use DRY chemical powder, CO2 or appropriate foam. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Unsuitable extinguishing media None known Specific hazards arising from the chemical None. Hazardous thermal decomposition products/Products of combustion None known. Special protective actions for fire fighters Do not release runoff from fire control methods to sewers or waterways. Special protective equipment for fire-fighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Environmental precautions Methods and materials for containment and cleaning up: Exposure to the spilled material may be irritating. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including: the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Gather and store in a sealed container pending a waste disposal evaluation.. Section 7: Handling and Storage Precautions for safe handling Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities: Provide local or general ventilation to keep below nuisance dust limit of 15mg/m3 Avoid contact with the eyes. Avoid repeated or prolonged contact with the skin or clothing. Avoid dust inhalation. Contact lenses should not be worn. Store in closed containers in cool, dry, isolated, well ventilated area away from heat, sources of ignition, and incompatibles. Store in a well-ventilated area. Keep cool. Section 8: Exposure Controls/Personal Protection Control parameters Page 4 of 8 Occupational exposure limits Ingredient name Exposure limits Magnesium Chloride ACGIH OSHA (TWA) (STEL) (TWA) (STEL) N/A N/A N/A N/A Appropriate engineering controls and Environmental exposure controls A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Individual protection measures Hygiene measures None Eye/face protection: Use chemical safety goggles. Skin protection Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Other skin protection Wash hands and other exposed areas with mild soap and water before eating or drinking. Respiratory protection: No respiratory protection required under normal circumstances. Respirator Type(s) (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen- deficient atmospheres. Section 9: Physical and Chemical Properties Appearance Physical state: White granules Odor: Odorless Odor threshold: Not available pH: No Data Available Specific Gravity: No Data Available Melting point: 118 o C Boiling point: No Data Available Flash point: Not applicable Evaporation rate (BuAc=1): Not applicable Flammability (solid, gas): No Lower and upper explosive (flammable) limits: Not applicable Vapor pressure: No Data Available Vapor density (Air=1): No Data Available Solubility: 468.7 g/L at 20 o C in water Partition coefficient: n-octanol/water: Not Established Page 5 of 8 Auto-ignition temperature: Not Applicable Decomposition temperature: Not Established Viscosity: Not determined VOC%: 0 Section 10: Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Will not occur. Conditions to avoid When mixed with limited amount of water enough heat may be generated to cause frothing. Exposure to moisture. Incompatible materials Strong oxidizing agents. Hazardous decomposition products No data available Section 11: Toxicological Information Information on toxicological effects Acute toxicity Product/ingredient name Test Results Magnesium Chloride Acute toxicity, oral (female rat) LD50 = > 5000 mg/kg Acute toxicity, dermal (rat) LD50 > 2000 mg/kg Acute toxicity, inhalation (rat) LC50 Rat: No data available Summary Comments: Sensitization Product/ingredient name Test Results Basis Magnesium Chloride No evidence of sensitization effect Summary Comments: Carcinogenicity Product/ingredient name Test Results Basis Magnesium Chloride No known carcinogenic effects Summary Comments: Specific target organ toxicity (single exposure) Product/ingredient name Test Results Basis Magnesium Chloride No Data Available Summary Comments: Specific target organ toxicity (repeated exposure) Product/ingredient name Test Results Basis Magnesium Chloride No Data Available Summary Comments: Aspiration hazard Page 6 of 8 Product/ingredient name Test Results Basis Magnesium Chloride No Data Available Summary Comments: Information on the likely routes of exposure Potential acute health effects Eye contact: May be irritating to the eyes. Inhalation: Not found to be toxic by oral exposure as defined by OSHA. Based on toxicity data for another compound (i.e., ammonium nitrate), not expected to be toxic by dermal and inhalation exposure as defined by OSHA. Skin contact: Mildly irritating to the skin. Ingestion: Not found to be toxic by oral exposure as defined by OSHA. Based on toxicity data for another compound (i.e., ammonium nitrate), not expected to be toxic by dermal and inhalation exposure as defined by OSHA. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Eye redness. Inhalation: May cause irritation of the mucous membranes and upper respiratory tract. Skin contact: Skin redness. Ingestion: May irritate the gastrointestinal tract. Potential chronic health effects (Magnesium Chloride) Carcinogenicity: No known carcinogens. Mutagenicity: Not mutagenic. Teratogenicity: Not teratogenic. Developmental effects: No data available. Fertility effects: No data available. Numerical measures of toxicity Acute toxicity estimates None. Section 12: Ecological Information Toxicity Acute Fish toxicity: (Magnesium Chloride) LC50 - Pimephales promelas (fathead minnow) - 2,119.3 mg/l - 96 h Acute toxicity for daphnia: (Magnesium Chloride) EC50 - Daphnia magna (Water flea) ? 548.4 mg/l -48 h Acute toxicity for algae: (Magnesium Chloride) Growth inhibition EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) - > 100 mg/l - 72 h Acute bacterial toxicity: (Magnesium Chloride) Respiration inhibition EC50 - Sludge Treatment - > 900 mg/l - 3 h. Ecotoxicology Assessment: (Magnesium Chloride) Non-toxic to aquatic organisms as defined by USEPA. No known toxicity. Persistence and degradability Biodegradability: (Magnesium Chloride) No data available Stability in water: (Magnesium Chloride) No data available Photodegradation: (Magnesium Chloride) Page 7 of 8 No data available Volatility (Henry's Law constant): (Magnesium Chloride) Partition coefficient n-octanol/water (log Pow) = No data available Bioaccumulative potential Bioaccumulation: (Magnesium Chloride) No data available on bioaccumulation Bioconcentration factor (BCF): No data available. Mobility in soil: (Magnesium Chloride) Distribution among environmental compartments: The product is water soluble and may spread in water systems Other adverse effects: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Section 13: Disposal Considerations Disposal methods Dispose in accordance with applicable international, national and local laws, ordinances and statutes. Section 14: Transport Information UN Number: N/A DOT Proper Shipping Name: Not Regulated Exemptions: N/A Transport hazard Class(es): N/A Packing Group: N/A Land Transport ADR/RID and GGVS/GGVE (Cross Border / Domestic) Transport Hazard Class(es): N/A Maritime Transport IMDG/GGVSea Transport Hazard Class(es): N/A Marine Pollutant: No Air Transport ICAO-TI and IATA-DGR Transport Hazard Class(es): N/A Section 15: Regulatory Information Chemical Inventory Status-Part 1 Ingredient (CAS#) TSCA EC Japan Australia Magnesium Chloride (7786-30-3) Yes Yes Yes Yes Chemical Inventory Status-Part 2 Ingredient (CAS#) Korea Canada Canada Philippines DSL NDSL Magnesium Chloride (7786-30-3) Yes Yes No Yes Page 8 of 8 Federal, State & International Regulations-Part 1 SARA 302 SARA 313 Ingredient (CAS#) RQ TPQ List Chemical Category Magnesium Chloride (7786-30-3) No No No No Federal, State & International Regulations-Part 2 RCRA TSCA Ingredient (CAS#) CERCLA 261.33 8(d) Magnesium Chloride (7786-30-3) No No No Chemical Weapons Convention: No TSCA 12b: No CDTA: No SARA 311/312: Acute: Yes, Chronic: No, Fire: No, Pressure: No, Reactivity: No Mixture/solid Australian Hazchem Code: No information found Poison Schedule: No information found Section 16: Other Information History Date of issue: 06/08/15 Version: 2a Revised Sections(s): Revised formula to remove urea Prepared by: Andrew Gioino, SPLASH PRODUCTS Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.