AC Delco Diesel Exhaust Fluid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : AC Delco Diesel Exhaust Fluid Product code : ACF002 (GM # 88865336) 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Solution for NOx reduction in SCR systems 1.3. Details of the supplier of the safety data sheet Old World Industries, LLC 4065 Commercial Ave. Northbrook, IL 60062 - USA T (847) 559-2000 www.oldworldind.com 1.4. Emergency telephone number Emergency number : (800) 424-9300; (703) 527 3887 (International) Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling Signal word (GHS-US) : None Hazard statements (GHS-US) : None Precautionary statements (GHS-US) : None 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % by wt GHS-US classification Water (CAS No) 7732-18-5 67.5 Not classified urea (CAS No) 57-13-6 32.5 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 01/28/2015 EN (English) Page 1 10-4082, 88865336 - ACDelco Diesel Exhaust Fluid AC Delco Diesel Exhaust Fluid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : The EPA has no established reportable quantity for spills for this material, secondary containment is not specified. 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Dilute with plenty of water and mop up. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, Heat sources. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters No additional information available 01/28/2015 EN (English) 2/6 AC Delco Diesel Exhaust Fluid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Gloves. Protective goggles. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless;Clear Odor : ammonia odor Odor threshold : No data available pH : 9 - 10 Relative evaporation rate (butylacetate=1) : < 1 Freezing point : -11 ?C (12 ?F) Boiling point : > 100 ?C (212 ?F) Flash point : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : Not Applicable Relative vapor density at 20 ?C : 0.6 H2O, >1 Specific Gravity : 1.09 Solubility : Soluble in water. Water: 100 % Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid No additional information available 10.5. Incompatible materials Strong acids. Strong bases. oxidizing agents (peroxides, chromates, dichromates). 01/28/2015 EN (English) 3/6 AC Delco Diesel Exhaust Fluid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. Fume. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified urea (57-13-6) LD50 oral rat 8,471 mg/kg (Rat) LD50 dermal rat > 3,200 mg/kg (Rat) LD50 dermal rabbit > 21,000 mg/kg (Rabbit) ATE US (oral) 8,471 mg/kg bodyweight Skin corrosion/irritation : Not classified pH: 9 - 10 Serious eye damage/irritation : Not classified pH: 9 - 10 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity urea (57-13-6) LC50 fish 1 > 6,810 mg/l (96 h; Leuciscus idus) EC50 Daphnia 1 > 10,000 mg/l (48 h; Daphnia magna) LC50 fish 2 17,500 mg/l (96 h; Poecilia reticulata) EC50 Daphnia 2 > 10,000 mg/l (24 h; Daphnia magna) TLM fish 1 17,500 ppm (96 h; Poecilia reticulata) Threshold limit other aquatic organisms 1 120,000 mg/l (16 h; Bacteria; Toxicity test) Threshold limit other aquatic organisms 2 > 10,000 mg/l (Pseudomonas putida) Threshold limit algae 2 > 10,000 mg/l (168 h; Scenedesmus quadricauda) 12.2. Persistence and degradability urea (57-13-6) Persistence and degradability Inherently biodegradable. Hydrolysis in water. ThOD 0.27 g O2/g substance 12.3. Bioaccumulative potential urea (57-13-6) BCF fish 1 1 (72 h; Brachydanio rerio; Fresh water) BCF other aquatic organisms 1 11700 (Chlorella sp.) Log Pow -2.59 - -1.59 Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil No additional information available 01/28/2015 EN (English) 4/6 AC Delco Diesel Exhaust Fluid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12.5. Other adverse effects Effect on ozone layer : No known effect on the ozone layer Effect on global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. As a non-hazardous liquid waste, it should be solidified with stabilizing agents such as sand, fly ash, or clay absorbent, so that no free liquid remains before disposal to an industrial waste landfill. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not a dangerous good in sense of transport regulations Other information : Non Bulk: Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package). ADR No additional information available Transport by sea UN-No. (IMDG) : Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package) Air transport UN-No.(IATA) : Not regulated by IATA (in quantities under 5,000 lbs in any one inner package) SECTION 15: Regulatory information 15.1. US Federal regulations AC Delco Diesel Exhaust Fluid EPA TSCA Regulatory Flag Toxic Substances Control Act (TSCA): The intentional ingredients of this product are listed RQ (Reportable quantity, section 304 of EPA's List of Lists) None. This material is not classified as hazardous under U.S. EPA regulations. SARA Section 302 Threshold Planning Quantity (TPQ) No extremely hazardous substances are in this product. SARA Section 311/312 Hazard Classes Urea. No hazards resulting from the material as supplied. urea (57-13-6) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations CANADA WHMIS Classification Uncontrolled product according to WHMIS classification criteria AC Delco Diesel Exhaust Fluid WHMIS Classification Uncontrolled product according to WHMIS classification criteria EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 01/28/2015 EN (English) 5/6 AC Delco Diesel Exhaust Fluid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15.2.2. National regulations AC Delco Diesel Exhaust Fluid Canadian Enviornmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). DSL (Canada): The intentional ingredients of this product are listed ECL (South Korea): The intentional ingredients of this product are listed. EINECS (Europe): The intentional ingredients of this product are listed ENCS (Japan): The intentional ingredients of this product are listed 15.3. US State regulations AC Delco Diesel Exhaust Fluid U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm Water (7732-18-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No urea (57-13-6) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No No No No SECTION 16: Other information NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 0 Minimal Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS GHS US (GHS HazCom 2012) OWI Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. 01/28/2015 EN (English) 6/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet 1.4. Emergency telephone number 2.1. Classification of the substance or mixture GHS-US classification 2.2. Label elements GHS-US labelling 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) 3.1. Substance 3.2. Mixture SECTION 4: First aid measures 4.1. Description of first aid measures 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials SECTION 11: Toxicological information 11.1. Information on toxicological effects SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil SECTION 13: Disposal considerations 13.1. Waste treatment methods SECTION 14: Transport information ADR SECTION 15: Regulatory information 15.1. US Federal regulations 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.3. US State regulations