ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 1 of 8 Safety Data Sheet Section 1: Identification Product identifier Product Name ECLEEN Pro-Grade Fuel Tank Flush Product Code CSF105 Relevant identified uses of the substance or mixture and uses advised against Recommended use Gasoline fuel additive Restrictions on use Use per the label directions Details of the supplier of the safety data sheet Manufacturer Gold Eagle Co. 4400 S. Kildare Avenue Chicago, IL 60632-4372 United States http://www.goldeagle.com/ Telephone (General) 773-376-4400 Emergency telephone number Manufacturer 1-800-535-5053 - (INFOTRAC #22283) Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR 1910.1200 HCS Classification of the substance or mixture OSHA HCS 2012 Flammable Liquids 4 Aspiration 1 Eye Irritation 2A Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Carcinogenicity 1B Reproductive Toxicity 2 Label elements OSHA HCS 2012 DANGER Hazard statements Combustible liquid May be fatal if swallowed and enters airways Causes serious eye irritation May cause drowsiness or dizziness May cause cancer. Suspected of damaging fertility or the unborn child. ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 2 of 8 Precautionary statements Causes skin irritation Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. Avoid breathing mist/vapours/spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response In case of fire: Use appropriate media for extinction. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF exposed or concerned: Get medical advice/attention. Storage/Disposal Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Other information NFPA Section 3 - Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % LD50/LC50 Classifications According to Regulation/Directive Distillates (petroleum), hydrotreated light CAS:64742- 47-8 0% TO 55% NDA OSHA HCS 2012: Flam. Liq. 4? Asp. Tox. 1? STOT SE 3: Narc. Ingestion/Oral-Rabbit LD50 ? 300 mg/kg ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 3 of 8 Ethylene glycol monobutyl ether CAS:111-76- 2 <= 15% Skin-Rabbit LD50 ? 220 mg/kg Ingestion/Oral-Rat LD50 ? 250 mg/kg OSHA HCS 2012: Petroleum Lube Oil CAS:64742- 65-0 <= 10% NDA OSHA HCS 2012: Mineral oil, petroleum distillates, hydrotreated (severe) heavy paraffinic CAS:64742- 54-7 <= 10% NDA OSHA HCS 2012: Proprietary additive Proprietary 0% TO 10% NDA OSHA HCS 2012: Not Classified Section 4: First-Aid Measures Description of first aid measures Inhalation Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical attention. Skin Remove and isolate contaminated clothing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Eye Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Get medical attention immediately. Ingestion Do NOT induce vomiting. Get medical attention immediately. Most important symptoms and effects, both acute and delayed Refer to Section 11 - Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5: Fire-Fighting Measures Extinguishing media Suitable Extinguishing Media Use halon replacement or carbon dioxide extinguishers or alcohol foam for small fires. Large fires should be extinguished with alcohol foam. Unsuitable Extinguishing Media Water spray or fog can cool fire but may not be effective in extinguishing fire. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Containers may explode when heated. Vapor explosion hazard indoors, outdoors or in sewers. Combustible material: may burn but does not ignite readily. Many liquids are lighter than water. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to sewer may create fire or explosion hazard. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. No data available Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 4 of 8 Move containers from fire area if you can do it without risk. LARGE FIRES: Cool containers with flooding quantities of water until well after fire is out. Section 6 - Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Ventilate enclosed areas. Do not walk through spilled material. Use appropriate Personal Protective Equipment (PPE) Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Emergency Procedures As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions? also, consider initial evacuation for 800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Methods and material for containment and cleaning up Containment/Clean-up Measures Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material. A vapor suppressing foam may be used to reduce vapors. All equipment used when handling the product must be grounded. LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Water spray may reduce vapor? but may not prevent ignition in closed spaces. Section 7 - Handling and Storage Precautions for safe handling Handling Use only in well ventilated areas. Avoid contact with heat and ignition sources. Take precautionary measures against static charges. Do not use sparking tools. All equipment used when handling the product must be grounded. Wear appropriate personal protective equipment, avoid direct contact. Avoid breathing mist, vapours, spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Conditions for safe storage, including any incompatibilities Storage Store in a tightly closed container. Keep away from sources of ignition, flammable, oxidizing materials, and acids. Store in a well-ventilated place. Store in an area equipped with automatic sprinklers or fire extinguishing system. Empty containers contain product residues, assume emptied containers to have same hazards as full containers. Section 8 - Exposure Controls/Personal Protection Control parameters Exposure controls Engineering Measures/Controls Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Use only appropriately classified electrical equipment. ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 5 of 8 Personal Protective Equipment Pictograms Respiratory In case of insufficient ventilation, wear suitable respiratory equipment. Follow the OSHA respirator regulations found in 29 CFR 1910.134. Use a NIOSH/MSHA approved respirator if exposure limits are exceeded or symptoms are experienced. Eye/Face Wear chemical splash safety goggles. Skin/Body Wear appropriate gloves. Environmental Exposure Controls Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Follow best practice for site management and disposal of waste. Key to abbreviations ACGIH = American Conference of Governmental Industrial Hygiene STEL = Short Term Exposure Limits are based on 15-minute exposures NIOSH = National Institute of Occupational Safety and Health TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures OSHA = Occupational Safety and Health Administration Section 9 - Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Amber to brown liquid with a solvent odor. Color Amber to brown. Odor Solvent Odor Threshold No data available General Properties Boiling Point > 180 F(> 82.2222 C) Melting Point No data available Decomposition Temperature No data available pH Not relevant Specific Gravity/Relative Density = 0.862 Water=1 Water Solubility Negligible < 0.1 % Viscosity 3.5 Centistoke (cSt, cS) or mm2/sec @ 40 C(104 F) Volatility Vapor Pressure < 1 mmHg (torr) Vapor Density No data available Evaporation Rate No data available VOC (Vol.) 100 % Volatiles (Vol.) 100 % Flammability Flash Point > 141.5 F(> 60.8333 C) UEL 6 % LEL 1 % Autoignition No data available Flammability (solid, gas) Not relevant. Section 10: Stability and Reactivity Reactivity Chemical stability No dangerous reaction known under conditions of normal use. Stable under normal temperatures and pressures. Possibility of hazardous reactions ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 6 of 8 Conditions to avoid Incompatible materials Hazardous polymerization will not occur. Excess heat. Incompatible materials. Strong oxidizing agents, aluminum, zinc, or metals that displace hydrogen, rubber and rubber based coatings, acid, and perchlorates. Hazardous decomposition products None known. Section 11 - Toxicological Information Information on toxicological effects GHS Properties Classification Acute toxicity OSHA HCS 2012 ? No data available Aspiration Hazard OSHA HCS 2012 ? Aspiration 1 Carcinogenicity OSHA HCS 2012 ? Carcinogenicity 1B Germ Cell Mutagenicity OSHA HCS 2012 ? No data available Skin corrosion/Irritation OSHA HCS 2012 ? No data available Skin sensitization OSHA HCS 2012 ? No data available STOT-RE OSHA HCS 2012 ? No data available STOT-SE OSHA HCS 2012 ? Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Toxicity for Reproduction OSHA HCS 2012 ? Toxic to Reproduction 2 Respiratory sensitization OSHA HCS 2012 ? No data available Serious eye damage/Irritation OSHA HCS 2012 ? Eye Irritation 2A Potential Health Effects Inhalation Acute (Immediate) May affect the central nervous system. Symptoms may include dizziness, drowsiness, lethargy, coma and death. Chronic (Delayed) No data available. Skin Acute (Immediate) Causes mild skin irritation. Chronic (Delayed) No data available. Eye Acute (Immediate) Causes serious eye irritation. Chronic (Delayed) No data available. Ingestion Acute (Immediate) Material may be aspirated into lungs during ingestion and/or subsequent vomiting. Aspiration of this material will cause severe lung injury, chemical pneumonitis, pulmonary edema or death. Chronic (Delayed) No data available. Carcinogenic Effects Suspected of causing cancer. This product contains components that are considered carcinogenic by OSHA, IARC, NTP. ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 7 of 8 Reproductive Effects Animal tests for components have shown adverse reproductive effects. Key to abbreviations LD = Lethal Dose TC = Toxic Concentration TD = Toxic Dose Section 12 - Ecological Information Toxicity Non-mandatory section - information about this substance not complied for this reason. Persistence and degradability Non-mandatory section - information about this substance not complied for this reason. Bioaccumulative potential Mobility in Soil Other adverse effects Non-mandatory section - information about this substance not complied for this reason. Non-mandatory section - information about this substance not complied for this reason. Non-mandatory section - information about this substance not complied for this reason. Section 13 - Disposal Considerations Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 - Transport Information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards DOT NDA Not Regulated NDA NDA NDA Special precautions for user None specified. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No data available Section 15 - Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute, Chronic, Fire ECLEEN Pro-Grade Fuel Tank Flush Preparation Date: 09/June/2015 Revision Date: 09/June/2015 Format: GHS Language: English (US) OSHA HCS 2012 Page 8 of 8 Other Information WARNING: This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. Section 16 - Other Information Last Revision Date 09/June/2015 Preparation Date 09/June/2015 Other Information Schedule B Number: 3811.19.0000. Disclaimer/Statement of Liability Key to abbreviations NDA = No Data Available Information presented herein is believed to be factual, as it has been derived from the works and opinions of persons believed to be qualified experts. However, nothing contained in this information is to be taken as warranty or representation for which the Gold Eagle Co. bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate.