ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 1 of 8 Safety Data Sheet Product identifier Product Name ECLEEN Pro Grade FI Cleaner Product Code CSF115 Relevant identified uses of the substance or mixture and uses advised against Recommended use Gasoline fuel stabilizer Restrictions on use Do NOT use in diesel fuel Details of the supplier of the safety data sheet Manufacturer Gold Eagle Co. 4400 S. Kildare Avenue Chicago, IL 60632-4372 United States http://www.goldeagle.com/ Telephone (General) 773-376-4400 Emergency telephone number Manufacturer 1-800-535-5053 - (INFOTRAC #22283) United States (US) According to: OSHA 29 CFR 1910.1200 HCS Classification of the substance or mixture OSHA HCS 2012 Flammable Liquids 4 Aspiration 1 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Carcinogenicity 2 Reproductive Toxicity 2 Label elements OSHA HCS 2012 DANGER Hazard statements Combustible liquid May be fatal if swallowed and enters airways May cause drowsiness or dizziness Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Precautionary statements Section 2: Hazard Identification Section 1: Identification ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 2 of 8 Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. Avoid breathing mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response In case of fire: Use appropriate media for extinction. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF exposed or concerned: Get medical advice/attention. Storage/Disposal Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Other information NFPA Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % LD50/LC50 Classifications According to Regulation/Directive Distillates (petroleum), hydrotreated light CAS:64742-47- 8 > 90% NDA OSHA HCS 2012: Flam. Liq. 4; Asp. Tox. 1; STOT SE 3: Narc. Confidential ingredient NDA < 10% NDA OSHA HCS 2012: Not Classified Description of first aid measures Inhalation Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical Section 4: First-Aid Measures Section 3 - Composition/Information on Ingredients ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 3 of 8 attention. Skin Remove and isolate contaminated clothing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Eye Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Get medical attention immediately. Ingestion Do NOT induce vomiting. Get medical attention immediately. Most important symptoms and effects, both acute and delayed Refer to Section 11 - Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Extinguishing media Suitable Extinguishing Media Use carbon dioxide, dry chemical, foam and/or water fog. Unsuitable Extinguishing Media No data available Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Containers may explode when heated. Vapor explosion hazard indoors, outdoors or in sewers. Combustible material: may burn but does not ignite readily. Many liquids are lighter than water. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to sewer may create fire or explosion hazard. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Water may cause frothing. No data available Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). Move containers from fire area if you can do it without risk. LARGE FIRES: Cool containers with flooding quantities of water until well after fire is out. Personal precautions, protective equipment and emergency procedures Personal Precautions Do not walk through spilled material. Use appropriate Personal Protective Equipment (PPE) Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Emergency Procedures As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. Section 6 - Accidental Release Measures Section 5: Fire-Fighting Measures ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 4 of 8 Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Methods and material for containment and cleaning up Containment/Clean-up Measures Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material. A vapor suppressing foam may be used to reduce vapors. All equipment used when handling the product must be grounded. LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition in closed spaces. Precautions for safe handling Handling Use only in well ventilated areas. Avoid contact with heat and ignition sources. Take precautionary measures against static charges. Do not use sparking tools. All equipment used when handling the product must be grounded. Wear appropriate personal protective equipment, avoid direct contact. Avoid breathing . Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Conditions for safe storage, including any incompatibilities Storage Store in a tightly closed container. Keep away from incompatible materials. Store in a well-ventilated place. Store in an area equipped with automatic sprinklers or fire extinguishing system. Store below 150? F. Empty containers contain product residues, assume emptied containers to have same hazards as full containers. Control parameters Exposure controls Engineering Measures/Controls Personal Protective Equipment Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Use only appropriately classified electrical equipment. Respiratory In case of insufficient ventilation, wear suitable respiratory equipment. Follow the OSHA respirator regulations found in 29 CFR 1910.134. Use a NIOSH/MSHA approved respirator if exposure limits are exceeded or symptoms are experienced. Eye/Face Wear chemical splash safety goggles. Skin/Body Wear appropriate gloves. Environmental Exposure Controls Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Follow best practice for site management and disposal of waste. Key to abbreviations ACGIH = American Conference of Governmental Industrial Hygiene STEL = Short Term Exposure Limits are based on 15-minute exposures NIOSH = National Institute of Occupational Safety and Health TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures OSHA = Occupational Safety and Health Administration Section 9 - Physical and Chemical Properties Section 8 - Exposure Controls/Personal Protection Section 7 - Handling and Storage ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 5 of 8 Information on Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Amber to brown liquid with a distillate odor. Color Amber to brown. Odor Distillate odor. Odor Threshold No data available General Properties Boiling Point 180 F(82.2222 C) Melting Point No data available Decomposition Temperature No data available pH No data available Specific Gravity/Relative Density = 0.83 Water=1 Water Solubility Negligible < 0.1 % Viscosity 3 Centistoke (cSt, cS) or mm2/sec @ 40 C(104 F) Volatility Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available VOC (Vol.) 100 % Volatiles (Vol.) 100 % Flammability Flash Point > 141.5 F(> 60.8333 C) UEL 7 % LEL 0.8 % Autoignition No data available Flammability (solid, gas) No data available Reactivity Chemical stability No dangerous reaction known under conditions of normal use. Stable under normal temperatures and pressures. Possibility of hazardous reactions Hazardous polymerization will not occur. Conditions to avoid Incompatible materials Excess heat. Incompatible materials. Strong oxidants. Hazardous decomposition products Excessive heating and/or incomplete combustion will produce carbon monoxide. Information on toxicological effects CAS ECLEEN Pro Grade FI Cleaner NDA Acute Toxicity: Ingestion/Oral-Rat LD50 ? >2 g/kg; Skin-Rabbit ? >2 g/kg ? Comments: No deaths; Irritation: Skin-Rabbit ? Essentially non-irritating; Unreported Route-Rabbit ? Essentially non-irritating GHS Properties Classification Section 11 - Toxicological Information Section 10: Stability and Reactivity ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 6 of 8 Acute toxicity OSHA HCS 2012 ? Data lacking Aspiration Hazard OSHA HCS 2012 ? Aspiration 1 Carcinogenicity OSHA HCS 2012 ? Carcinogenicity 2 Germ Cell Mutagenicity OSHA HCS 2012 ? Non-mutagenic Skin corrosion/Irritation OSHA HCS 2012 ? Data lacking Skin sensitization OSHA HCS 2012 ? Data lacking STOT-RE OSHA HCS 2012 ? Data lacking STOT-SE OSHA HCS 2012 ? Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Toxicity for Reproduction OSHA HCS 2012 ? Toxic to Reproduction 2 Respiratory sensitization OSHA HCS 2012 ? Data lacking Serious eye damage/Irritation OSHA HCS 2012 ? Data lacking Potential Health Effects Inhalation Acute (Immediate) May affect the central nervous system. Symptoms may include dizziness, drowsiness, lethargy, coma and death. Chronic (Delayed) No data available. Skin Acute (Immediate) Causes mild skin irritation. Chronic (Delayed) No data available. Eye Acute (Immediate) Causes eye irritation. Chronic (Delayed) No data available. Ingestion Acute (Immediate) Material may be aspirated into lungs during ingestion and/or subsequent vomiting. Aspiration of this material will cause severe lung injury, chemical pneumonitis, pulmonary edema or death. Chronic (Delayed) No data available. Carcinogenic Effects Suspected of causing cancer. This product contains components that are considered carcinogenic by OSHA, IARC, NTP. Reproductive Effects Animal tests for components have shown adverse reproductive effects. Key to abbreviations LD = Lethal Dose TC = Toxic Concentration TD = Toxic Dose Toxicity Non-mandatory section - information about this substance not complied for this reason. Persistence and degradability Non-mandatory section - information about this substance not complied for this reason. Bioaccumulative potential Section 12 - Ecological Information ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 7 of 8 Mobility in Soil Other adverse effects Non-mandatory section - information about this substance not complied for this reason. Non-mandatory section - information about this substance not complied for this reason. Non-mandatory section - information about this substance not complied for this reason. Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards DOT NDA Not Regulated NDA NDA NDA Special precautions for user None specified. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No data available Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute, Chronic, Fire Other Information WARNING: This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. Last Revision Date 09/June/2015 Preparation Date 09/June/2015 Other Information Schedule B Number: 3811.90.0000. Disclaimer/Statement of Information presented herein is believed to be factual, as it has been derived from the Section 16 - Other Information Component CAS Inventory TSCA Distillates (petroleum), hydrotreated light 64742-47-8 Yes Section 15 - Regulatory Information Section 14 - Transport Information Section 13 - Disposal Considerations ECLEEN Pro Grade FI Cleaner Preparation Date: 09/June/2015 Format: GHS Language: English (US) Revision Date: 09/June/2015 OSHA HCS 2012 Page 8 of 8 Liability works and opinions of persons believed to be qualified experts. However, nothing contained in this information is to be taken as warranty or representation for which the Gold Eagle Co. bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Key to abbreviations NDA = No Data Available Safety Data Sheet Relevant identified uses of the substance or mixture and uses advised against Details of the supplier of the safety data sheet Emergency telephone number United States (US) According to: OSHA 29 CFR 1910.1200 HCS Label elements OSHA HCS 2012 Other hazards Other information NFPA Description of first aid measures Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed Extinguishing media Unsuitable Extinguishing Media Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up Containment/Clean-up Measures Precautions for safe handling Conditions for safe storage, including any incompatibilities Control parameters Exposure controls Engineering Measures/Controls Environmental Exposure Controls Information on Physical and Chemical Properties Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Information on toxicological effects Potential Health Effects Inhalation Skin Eye Ingestion Toxicity Persistence and degradability Bioaccumulative potential Waste treatment methods Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Safety, health and environmental regulations/legislation specific for the substance or mixture Other Information