SAFETY DATA SHEET 1. Identification Product identifier Plastic Bonding Adhesive Other means of identification FIR No. 159252 Recommended use Structural Urethane Adhesive Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Not classified.Physical hazards Category 2Acute toxicity, inhalationHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 1Sensitization, respiratory Category 1Sensitization, skin Category 2Carcinogenicity Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 2Specific target organ toxicity, repeated exposure Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Fatal if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 1 / 7 Response If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Immediately call a poison center/doctor. Take off contaminated clothing and wash before reuse. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May be harmful if swallowed. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 101-68-84,4'-Methylenediphenyl diisocyanate 10 - < 20 Trade SecretAromatic polyisocyanate 10 - 20 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician or poison control center immediately. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Call a physician or poison control center immediately. Do not induce vomiting. Most important symptoms/effects, acute and delayed Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Coughing. Difficulty in breathing. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Powder. Alcohol foam. Carbon dioxide (CO2). Unsuitable extinguishing media Water. Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Container may explode in heat of fire. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 2 / 7 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Do not breathe vapors or spray mist. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up The product is immiscible with water and will sediment in water systems. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe vapors or spray mist. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type Ceiling 0.2 mg/m34,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) 0.02 ppm Ceiling 0.2 mg/m3Aromatic polyisocyanate 0.02 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 0.005 ppm4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) TWA 0.005 ppmAromatic polyisocyanate US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type Ceiling 0.2 mg/m34,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) 0.02 ppm TWA 0.05 mg/m3 0.005 ppm Ceiling 0.2 mg/m3Aromatic polyisocyanate 0.02 ppm TWA 0.05 mg/m3 0.005 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls General ventilation normally adequate. Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 3 / 7 Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Use protective gloves made of: Nitrile. Neoprene. Rubber gloves. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Tan. Odor Odorless. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point > 199.4 ?F (> 93.0 ?C) SETAFLASH Evaporation rate < 1 (BuAc=1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density > 1 (AIR=1) Relative density 1.41 Relative density temperature 39.2 ?F (4 ?C) Solubility(ies) Solubility (water) INSOLUBLE IN WATER Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information VOC (Weight %) 0 g/l FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 4 / 7 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Water. Acids. Strong oxidizing agents. Amines. Alcohols. Hazardous decomposition products Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May be harmful if inhaled. Skin contact Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion May be harmful if swallowed. However, ingestion is not likely to be a primary route of occupational exposure. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Coughing. Difficulty in breathing. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity Fatal if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. Species Calculated/Test ResultsComponents 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) LC50 Rat Inhalation Acute 0.369 mg/l, 4 Hours Aromatic polyisocyanate (CAS Trade Secret) LC50 Rat Inhalation Acute 0.369 mg/l, 4 Hours Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) 3 Not classifiable as to carcinogenicity to humans. Aromatic polyisocyanate (CAS Trade Secret) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Skin. May cause respiratory irritation. Specific target organ toxicity - repeated exposure Skin. Lungs. Respiratory tract. May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Not an aspiration hazard. FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 5 / 7 Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) Listed. Aromatic polyisocyanate (CAS Trade Secret) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 6 / 7 SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. 4,4'-Methylenediphenyl diisocyanate 101-68-8 10 - < 20 Aromatic polyisocyanate Trade Secret 10 - 20 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) Aromatic polyisocyanate (CAS Trade Secret) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) Aromatic polyisocyanate (CAS Trade Secret) US. New Jersey Worker and Community Right-to-Know Act 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) Aromatic polyisocyanate (CAS Trade Secret) US. Pennsylvania Worker and Community Right-to-Know Law 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) Aromatic polyisocyanate (CAS Trade Secret) US. Rhode Island RTK 4,4'-Methylenediphenyl diisocyanate (CAS 101-68-8) Aromatic polyisocyanate (CAS Trade Secret) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-20-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 1 Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) TA-9 FIR No.: 159252 SDS US Issue Date: 05-20-2015 Version: 01 7 / 7