PENRAY COOL-TEC? 2 Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 07/10/2014 Revision date: 07/10/2014 Version: 1.0 07/10/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY COOL-TEC? 2 Product code : 1112 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Cooling system treatment. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye irritation 2A 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : Causes serious eye irritation. Precautionary statements (GHS-US) : Wash hands thoroughly after handling. Wear eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Sodium silicate (CAS No) 1344-09-8 0.1 - 1 Acute Tox. 4 (Oral) Skin Irrit. 2 Eye Dam. 1 STOT SE 3 Methanol (CAS No) 67-56-1 < 0.1 Flam. Liq. 2 Acute Tox. 3 (Oral, Dermal, Inhalation) Eye Irrit. 2B STOT SE 1 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. PENRAY COOL-TEC? 2 Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/10/2014 EN (English) 2/6 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : If irritation occurs, flush skin with plenty of water. Get medical attention if irritation persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Treat for surrounding material. Unsuitable extinguishing media : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Do not swallow. Avoid breathing gas/fumes/vapor/spray. Handle and open container with care. When using do not eat, drink or smoke. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in a well-ventilated place. 7.3. Specific end use(s) Not available. PENRAY COOL-TEC? 2 Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/10/2014 EN (English) 3/6 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Sodium silicate (1344-09-8) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Methanol (67-56-1) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 260 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear suitable gloves. Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield). Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Color : Colorless. Odor : Odorless. Odor threshold : No data available. pH : 8.0 - 9.5 Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Not flammable. Vapor pressure : No data available. Relative vapor density at 20 ?C : No data available. Relative density : 1.095 - 1.131 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. PENRAY COOL-TEC? 2 Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/10/2014 EN (English) 4/6 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 1112 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat No data available. Sodium silicate (1344-09-8) LD50 oral rat 1153 mg/kg LD50 dermal rabbit > 4640 mg/kg Methanol (67-56-1) LD50 oral rat 5628 mg/kg LD50 dermal rabbit 15800 mg/kg LC50 inhalation rat 83.2 mg/l/4h Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 1112 Persistence and degradability Not established. PENRAY COOL-TEC? 2 Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/10/2014 EN (English) 5/6 12.3. Bioaccumulative potential 1112 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. SECTION 14: Transport information In accordance with DOT 14.1. UN number Not applicable 14.2. UN proper shipping name Not applicable 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Phosphonic acid, methyl-, monomethyl ester, monosodium salt CAS No 73750-69-3 Phosphonic acid, methyl-, mono[3-(trihydroxysilyl)propyl] ester, monosodium salt CAS No 84962-98-1 Methanol (67-56-1) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % 15.2. US State regulations 1112 State or local regulations This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 07/10/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 0 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product PENRAY COOL-TEC? 2 Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/10/2014 EN (English) 6/6