MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Penetrating Oil MSDS NO. 4602 Revision Date: 03/11/2009 Date Printed 03/11/2009 Page 1 of 4 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Johnsens Penetrating Oil Chemical Family: Petroleum Oil Blend Synonyms: None Emergency Telephone (24 hr.): 24-Hour Emergency Information: CHEMTREC (800) 424-9300 Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Hydrotreated light distillates 64742-47-8 85-100 Not Listed Not Listed Not Listed Oleic Acid 11-28-01 0-5 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 0-5 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Hydrotreated light distillates 64742-47-8 85-100 Not Listed Not Listed Not Listed Oleic Acid 11-28-01 0-5 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 0-5 9000 mg/m3 5000 ppm 18000 mg/m3 10000 ppm Not Listed Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Hydrotreated light distillates 64742-47-8 Not Listed Not Listed Not Listed Oleic Acid 11-28-01 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 5000 ppm 30000 ppm Not Listed 3. HAZARDS IDENTIFICATION Emergency Overview: Content under pressure. Keep away from heat, sparks and flame. This material is a skin irritant. HMIS Classification: Health: 1 Flammability: 2 Physical Hazard: 2 NFPA Rating: Health: 1 Flammability: 2 Reactivity: 0 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Ingestion: If swallowed, do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: Wash with soap and water for 15 minutes. If irritation persists or signs of toxicity occur, seek medical attention. Remove contaminated clothing and shoes, and launder before reuse. 5. FIRE FIGHTING MEASURES MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Penetrating Oil MSDS NO. 4602 Revision Date: 03/11/2009 Date Printed 03/11/2009 Page 2 of 4 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point ?F(?C): >100F Flash Point Method: TAG Closed Cup Flammable Limits in Air - Lower (%): .9% Flammable Limits in Air - Upper (%): Not Determined Autoignition Temperature ?F(?C): Not Determined Extinguishing Media: Carbon dioxide. Foam. Use water spray to keep containers cool that are exposed to heat or flames. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide. Aerosol Comments: NFPA Level 3 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Spill Procedures: Contain any liquid from leaking containers. Avoid all sources of ignition; heat, sparks and open flames. Action to be taken if material is released or spilled: Do not puncture or incinerate container. Contents under pressure. Wear proper protective equipment as specified in the protective equipment section. Remove sources of ignition. Leaking containers should be removed to an isolated, well-ventilated area and transferred to other suitable containers. Wipe, scrape, or soak up in an inert material and put in a container intended for flammable materials for disposal. Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Keep out of lakes, ponds or streams. 7. HANDLING AND STORAGE Handling and Storage: Caution: Contents under pressure. Keep away from heat and open flame. Use only in a well ventilated area. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with sk and eyes. Do not puncture, incinerate or store above 120 F. Exposure to high temperatures may cuase bursting. DO NOT store in the passenger compartment of an automobile. in 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Use in a well ventilated area. Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Eyes: Chemical goggles; also wear a face shield if splashing hazard exists. Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Respiratory Protection: Do not breath mist or vapor. Use in a well ventilated area. Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colorless to pale yellow liquid Odor: HYDROCARBON ODOR pH Value: Not Determined Vapor Pressure: Not Determined Vapor Density (Air=1): Not Determined Boiling Point (?F): >300F (liquid) Melting/Freezing Point: Not determined. Solubility in Water: MODERATE Bulk Density at 20?C: Not Determined Molecular Weight: Mixture Specific Gravity (H20=1): .76 @ 60 F (liquid) Viscosity: Not Determined. Evaporation Rate: Not Determined VOC Content(%): 49.2% Decomposition Temperature: Not Determined 10. STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions of handling, use and transportation. MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Penetrating Oil MSDS NO. 4602 Revision Date: 03/11/2009 Date Printed 03/11/2009 Page 3 of 4 10. STABILITY AND REACTIVITY Conditions to Avoid: Keep away from heat,sparks and flame. Avoid any source of ignition. Do not expose to heat or store at temperatures above 120 F. Materials to Avoid: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Oxides of carbon and nitrogen, AVOID extreme heat Hazardous Polymerization: WILL NOT OCCUR 11. TOXICOLOGICAL INFORMATION Toxicological Data: Component Route Species Dose Hydrotreated light distillates 64742-47-8 Inhalation Rats Not known. Oleic Acid 11-28-01 Inhalation Rats Not known. Carbon Dioxide 124-38-9 NA NA Not known. Carcinogenicity: Component IARC NTP OSHA Hydrotreated light distillates 64742-47-8 Not Listed Not Listed Not Listed Oleic Acid 11-28-01 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Remarks: Ecological testing has not been conducted on this product. 13. DISPOSAL CONSIDERATION Waste Classification: Residues and spilled material are hazardous waste due to ignitability. Waste Management: Not determined. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: CONSUMER COMMODITY Hazard Class: ORM-D UN/NA Number: Not Applicable DOT Packing Group: Not Applicable IMDG: Proper Shipping Name: Aerosols Hazard Class: 2 Hazard Subclass: Not Applicable UN No.: UN 1950 Packing Group: Not Applicable Marine Pollutant: No 15. REGULATORY INFORMATION US Federal Regulations: MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Penetrating Oil MSDS NO. 4602 Revision Date: 03/11/2009 Date Printed 03/11/2009 Page 4 of 4 Component SARA 313 SARA 302 TPQ RQ Hydrotreated light distillates 64742-47-8 Not Listed Not Listed Not Listed Not Listed Oleic Acid 11-28-01 Not Listed Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Not Listed US OSHA HEALTH CLASSIFICATION: Hazardous per OSHA 29 CFR 1910.1200 SARA 311/312 Hazard Catagories: Not Determined. State Regulations: Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Hydrotreated light distillates 64742-47-8 Not Listed Not Listed Not Listed Not Listed Oleic Acid 11-28-01 Not Listed Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Not Listed Component New Jersey Right-to-Know List: Carbon Dioxide 124-38-9 Substance no. 0343 U.S. TSCA: One or more components of this product is not listed on the TSCA Inventory. Canadian Inventory: One or more components of this product is not listed on the Canadian DSL or NDSL Inventory. Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and e by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures a packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product contain nforced re er. 16. OTHER INFORMATION General Notes: not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. Do Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.