MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Glass Cleaner MSDS NO. 4646 Revision Date: 03/27/2007 Date Printed 12/30/2008 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Johnsens Glass Cleaner Synonyms: None Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300 Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Propane 74-98-6 4-7 Not Listed Not Listed Not Listed Butane 106-97-8 4-7 Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 0.5-2 Not Listed Not Listed 50 ppm Ethanol 64-17-5 0.5-2 Not Listed Not Listed Not Listed Methyl Alcohol 67-56-1 3-5 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Propane 74-98-6 4-7 1800 mg/m3 1000 ppm 1800 mg/m3 1000 ppm Not Listed Butane 106-97-8 4-7 Not Listed 1900 mg/m3 800 ppm Not Listed Glycol Ether EB 111-76-2 0.5-2 Not Listed Not Listed 120 mg/m3 25 ppm Ethanol 64-17-5 0.5-2 1900 mg/m3 1000 ppm 1900 mg/m3 1000 ppm Not Listed Methyl Alcohol 67-56-1 3-5 260 mg/m3 200 ppm 260 mg/m3 200 ppm Not Listed Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Propane 74-98-6 1000 ppm Not Listed Not Listed Butane 106-97-8 1000 ppm Not Listed Not Listed Glycol Ether EB 111-76-2 20 ppm Not Listed Not Listed Ethanol 64-17-5 1000 ppm Not Listed Not Listed Methyl Alcohol 67-56-1 200 ppm 250 ppm Not Listed 3. HAZARDS IDENTIFICATION Page 1 of 6 MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Glass Cleaner MSDS NO. 4646 Revision Date: 03/27/2007 Date Printed 12/30/2008 3. HAZARDS IDENTIFICATION Emergency Overview: Content under pressure. Keep away from heat, sparks and flame. Causes respiratory irritation. Possible redness and defatting may result from prolonged skin exposure to this matieral. Ingestion of this product may cause gastrointestinal distress with symptoms of nausea, vomiting, diarrhea and abdominal pain. Gross inhalation overexposure may cause: respiratory track irritation, kidney damage, blood, liver damage, lung damage and central nervous system depression. Causes moderate eye irritation. This material is a skin irritant. HMIS Classification: Health: *2 Flammability: 4 Physical Hazard: 2 NFPA Rating: Health: 3 Flammability: 4 Reactivity: 0 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Ingestion: Get immediate medical attention. Induce vomiting immediately as directed by medical personnel. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. If vomiting occurs, keep head lower than hips to prevent aspiration. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: Wash with soap and water for 15 minutes. If irritation persists or signs of toxicity occur, seek medical attention. Remove contaminated clothing and shoes, and launder before reuse. 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point ?F(?C): -200 F (Propellant) Flash Point Method: TAG Closed Cup Flammable Limits in Air - Lower (%): 1.1% Flammable Limits in Air - Upper (%): Not Determined Autoignition Temperature ?F(?C): 460 F (Lowest Component) Extinguishing Media: Dry chemical. Carbon dioxide. Use water spray to keep containers cool that are exposed to heat or flames. Foam. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Vapor may cause flash fire. Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide. Aerosol Comments: NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Spill Procedures: Contain any liquid from leaking containers. Avoid all sources of ignition; heat, sparks and open flames. Action to be taken if material is released or spilled: Do not puncture or incinerate container. Contents under pressure. Wear proper protective equipment as specified in the protective equipment section. Remove sources of ignition. Leaking containers should be removed to an isolated, well-ventilated area and transferred to other suitable containers. Wipe, scrape, or soak up in an inert material and put in a container intended for flammable materials for disposal. Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Keep out of lakes, ponds or streams. 7. HANDLING AND STORAGE Handling and Storage: Caution: Contents under pressure. Keep away from heat and open flame. Use only in a well ventilated area. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Do not puncture, incinerate or store above 120 F. Exposure to high temperatures may cuase bursting. DO NOT store in the passenger compartment of an automobile. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Page 2 of 6 MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Glass Cleaner MSDS NO. 4646 Revision Date: 03/27/2007 Date Printed 12/30/2008 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Use in a well ventilated area. Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Eyes: Chemical goggles; also wear a face shield if splashing hazard exists. Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Respiratory Protection: Do not breath mist or vapor. Use in a well ventilated area. Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colorless to light yellow liquid Odor: SLIGHT ALCOHOL pH Value: 9.0 Vapor Pressure: Not Determined Vapor Density (Air=1): Not Determined Boiling Point (?F): Not Determined Melting/Freezing Point: Not Determined. Solubility in Water: Solubility in Water: Bulk Density at 20?C: Not Determined Molecular Weight: Mixture Specific Gravity (H20=1): .98 @ 60 F (liquid) Viscosity: Not Determined. Evaporation Rate: Not Determined VOC Content(%): Not determined. Decomposition Temperature: Not Determined 10. STABILITY AND REACTIVITY Chemical Stability: STABLE. Conditions to Avoid: Keep away from heat,sparks and flame. Avoid any source of ignition. Do not expose to heat or store at temperatures above 120 F. Materials to Avoid: Contact with oxidizing agents. Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Oxides of nitrogen. Hazardous Polymerization: WILL NOT OCCUR 11. TOXICOLOGICAL INFORMATION Toxicological Data: Component Route Species Dose Propane 74-98-6 NA NA Not known. Butane 106-97-8 NA NA LC50 658 gm/m3/4H Glycol Ether EB 111-76-2 Inhalation Rats LC50 450 ppm/4H Ethanol 64-17-5 Inhalation Rats Not known. Methyl Alcohol 67-56-1 Inhalation Rats LC50 64,000 ppm Carcinogenicity: Page 3 of 6 MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Glass Cleaner MSDS NO. 4646 Revision Date: 03/27/2007 Date Printed 12/30/2008 Component IARC NTP OSHA Propane 74-98-6 Not Listed Not Listed Not Listed Butane 106-97-8 Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 Not Listed Not Listed Not Listed Ethanol 64-17-5 Not Listed Not Listed Not Listed Methyl Alcohol 67-56-1 Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Remarks: Ecological testing has not been conducted on this product. 13. DISPOSAL CONSIDERATION Waste Classification: Not determined. Waste Management: Not determined. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: ORM-D CONSUMER COMMODITY Hazard Class: ORM-D UN/NA Number: Not Applicable DOT Packing Group: Not Applicable IMDG: Proper Shipping Name: Aeroslols (Limited Quantity) Hazard Class: 2.1 Hazard Subclass: Not determined. UN No.: UN1950 Packing Group: PG II Marine Pollutant: No 15. REGULATORY INFORMATION US Federal Regulations: Component SARA 313 SARA 302 TPQ RQ Propane 74-98-6 Not Listed Not Listed Not Listed Not Listed Butane 106-97-8 Not Listed Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 Not Listed Not Listed Not Listed Not Listed Ethanol 64-17-5 Not Listed Not Listed Not Listed Not Listed Methyl Alcohol 67-56-1 Listed. Not Listed Not Listed Not Listed US OSHA HEALTH CLASSIFICATION: Hazardous per OSHA 29 CFR 1910.1200 SARA 311/312 Hazard Catagories: Not Determined. Page 4 of 6 MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Glass Cleaner MSDS NO. 4646 Revision Date: 03/27/2007 Date Printed 12/30/2008 State Regulations: Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Propane 74-98-6 Not Listed Not Listed Not Listed Not Listed Butane 106-97-8 Not Listed Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 Not Listed Not Listed Not Listed Not Listed Ethanol 64-17-5 Not Listed Not Listed Not Listed Not Listed Methyl Alcohol 67-56-1 Not Listed Not Listed Not Listed Not Listed Component New Jersey Right-to-Know List: Propane 74-98-6 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Substance no. 1594 Butane 106-97-8 Substance no. 0273 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Glycol Ether EB 111-76-2 Substance no. 0275 Ethanol 64-17-5 Substance no. 0844 Methyl Alcohol 67-56-1 Substance no. 2079 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Substance no. 1222 U.S. TSCA: The components of this product are listed on the TSCA Inventory. Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory. Page 5 of 6 MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Glass Cleaner MSDS NO. 4646 Revision Date: 03/27/2007 Date Printed 12/30/2008 Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. 16. OTHER INFORMATION General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. Page 6 of 6