MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Fuel Injector Cleaner MSDS NO. 4684 Revision Date: 01/04/2010 Date Printed 01/04/2010 Page 1 of 5 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Johnsens Fuel Injector Cleaner Chemical Family: PETROLEUM DISTILLATE Synonyms: None Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300 Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Solvent naptha (petroleum), light aromatic 64742-95-6 1-10 Not Listed Not Listed Not Listed 1,2,4-trimethylbenzene 95-63-6 1-10 Not Listed Not Listed Not Listed Polyolefin alkylphenol HC1 alkylamine N/A 1-10 Not Listed Not Listed Not Listed Heavy Aliphatic Solvent Naphtha 64742-96-7 90-100 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Solvent naptha (petroleum), light aromatic 64742-95-6 1-10 Not Listed Not Listed Not Listed 1,2,4-trimethylbenzene 95-63-6 1-10 Not Listed Not Listed Not Listed Polyolefin alkylphenol HC1 alkylamine N/A 1-10 Not Listed Not Listed Not Listed Heavy Aliphatic Solvent Naphtha 64742-96-7 90-100 Not Listed Not Listed Not Listed Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Solvent naptha (petroleum), light aromatic 64742-95-6 Not Listed Not Listed Not Listed 1,2,4-trimethylbenzene 95-63-6 Not Listed Not Listed Not Listed Polyolefin alkylphenol HC1 alkylamine N/A Not Listed Not Listed Not Listed Heavy Aliphatic Solvent Naphtha 64742-96-7 Not Listed Not Listed Not Listed 3. HAZARDS IDENTIFICATION MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Fuel Injector Cleaner MSDS NO. 4684 Revision Date: 01/04/2010 Date Printed 01/04/2010 Page 2 of 5 3. HAZARDS IDENTIFICATION Emergency Overview: Warning! Combustible Liquid and Vapor. Harmful if inhaled. May cause delayed lung injury. Exposure to vapors can cause central nervous system depression, drowsiness, weakness, headache, dizziness, and nausea. Avoid breathing vapors. Avoid contact with skin and eyes. Keep away from heat, sparks, and flame. HMIS Classification: Health: 2 Flammability: 2 Physical Hazard: 0 NFPA Rating: Health: 2 Flammability: 2 Reactivity: 0 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Ingestion: If swallowed, do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. If victim is conscious and alert, give 1-2 glasses of water to drink. If vomiting occurs, keep head lower than hips to prevent aspiration. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: Wash with soap and water. Remove contaminated clothing and shoes, and launder before reuse. If irritation or rash develops, obtain medical assistance. 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point ?F(?C): >155 F (>68.3 C) Flash Point Method: TAG Closed Cup Flammable Limits in Air - Lower (%): .7 vol % Flammable Limits in Air - Upper (%): 6 vol % Autoignition Temperature ?F(?C): >550 F (>287.8 C) Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam. Water stream may spread fire. Use water spray to keep containers cool that are exposed to heat or flames. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Hazardous Combustion Products: Fumes and Smoke. Oxides of Carbon. Oxides of Nitrogen. Aerosol Comments: Not Applicable 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Spill Procedures: Sweep or scrape up material and place in a suitable clean, dry containerfor disposal by approved methods. Action to be taken if material is released or spilled: Increase area ventilation. Remove sources of ignition. Leaking containers should be removed to an isolated, well-ventilated area and transferred to other suitable containers. Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. 7. HANDLING AND STORAGE Handling and Storage: Keep away from heat and open flame. Keep containers tightly closed when not in use. Wash thoroughly after handling. Use only with adequate ventilation. Avoid extreme temperatures. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Exhaust ventilation. Showers. Eyewash stations. Eyes: Wear safety glasses or goggles to protect against exposure. Chemical goggles; also wear a face shield if splashing hazard exists. Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Neoprene coated apron or clothing. Nitrile coated apron or clothing. Respiratory Protection: Use an approved NIOSH organic vapor respirator below the TLV. If TLV is exceeded or overexposure is likely, use positive pressure or self contained breathing apparatus. MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Fuel Injector Cleaner MSDS NO. 4684 Revision Date: 01/04/2010 Date Printed 01/04/2010 Page 3 of 5 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colorless to light yellow liquid Odor: KEROSENE pH Value: Not Determined Vapor Pressure: .00386 psia @ 68F Vapor Density (Air=1): 6 Boiling Point (?F): >400F (>204.4 C) Melting/Freezing Point: 25F Solubility in Water: NEGLIGIBLE Bulk Density at 20?C: Not Determined Molecular Weight: Mixture Specific Gravity (H20=1): .79 @ 70F Viscosity: >1.7 cst @ 40C Evaporation Rate: Not Determined VOC Content(%): 5.04 (CARB Method 310) Decomposition Temperature: Not Known 10. STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions of handling, use and transportation. Conditions to Avoid: Keep away from heat,sparks and flame. Do not expose to heat or store at temperatures above 120 F. Materials to Avoid: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide and other asphixiates. Hazardous Polymerization: WILL NOT OCCUR 11. TOXICOLOGICAL INFORMATION Toxicological Data: Component Route Species Dose Solvent naptha (petroleum), light aromatic 64742-95-6 Oral Rats LD50 8400 mg/kg 1,2,4-trimethylbenzene 95-63-6 Inhalation Rats LC50 18 gm/m3/4H Polyolefin alkylphenol HC1 alkylamine N/A NA NA Not known. Heavy Aliphatic Solvent Naphtha 64742-96-7 Inhalation Rats Not known. Carcinogenicity: Component IARC NTP OSHA Solvent naptha (petroleum), light aromatic 64742-95-6 Not Listed Not Listed Not Listed 1,2,4-trimethylbenzene 95-63-6 Not Listed Not Listed Not Listed Polyolefin alkylphenol HC1 alkylamine N/A Not Listed Not Listed Not Listed Heavy Aliphatic Solvent Naphtha 64742-96-7 Not Listed Not Listed Not Listed MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Fuel Injector Cleaner MSDS NO. 4684 Revision Date: 01/04/2010 Date Printed 01/04/2010 Page 4 of 5 12. ECOLOGICAL INFORMATION Remarks: Ecological testing has not been conducted on this product. 13. DISPOSAL CONSIDERATION Waste Classification: Not determined. Waste Management: Recovery and reuse, rather than disposal, should be the ultimate goal of handling efforts. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: Consumer Commodity Hazard Class: ORM D UN/NA Number: Not Applicable DOT Packing Group: Not Applicable IMDG: Proper Shipping Name: Not Regulated Hazard Class: Not Applicable Hazard Subclass: Not Applicable UN No.: Not Applicable Packing Group: Not Applicable Marine Pollutant: No 15. REGULATORY INFORMATION US Federal Regulations: Component SARA 313 SARA 302 TPQ RQ Solvent naptha (petroleum), light aromatic 64742-95-6 Not Listed Not Listed Not Listed Not Listed 1,2,4-trimethylbenzene 95-63-6 Listed. Not Listed Not Listed Not Listed Polyolefin alkylphenol HC1 alkylamine N/A Not Listed Not Listed Not Listed Not Listed Heavy Aliphatic Solvent Naphtha 64742-96-7 Not Listed Not Listed Not Listed Not Listed SARA 311/312 Hazard Catagories: Immediate/Acute, Delayed/Chronic, Fire State Regulations: MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Fuel Injector Cleaner MSDS NO. 4684 Revision Date: 01/04/2010 Date Printed 01/04/2010 Page 5 of 5 Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Solvent naptha (petroleum), light aromatic 64742-95-6 Not Listed Not Listed Not Listed Not Listed 1,2,4-trimethylbenzene 95-63-6 Not Listed Not Listed Not Listed Not Listed Polyolefin alkylphenol HC1 alkylamine N/A Not Listed Not Listed Not Listed Not Listed Heavy Aliphatic Solvent Naphtha 64742-96-7 Not Listed Not Listed Not Listed Not Listed U.S. TSCA: One or more components of this product is not listed on the TSCA Inventory. Canadian Inventory: One or more components of this product is not listed on the Canadian DSL or NDSL Inventory. Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. 16. OTHER INFORMATION General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.