SDS Repository

sds

Collection
AC Delco
Description
 
Tags
Search Tag
Filename
10-3012.pdf
Source
 
Full Text
11/09/2015Revision: 11/24/2015Printed: Page: 1 Gas Treatment 1037 SAFETY DATA SHEET 121873-GHS-USProduct Code: Gas Treatment 1037Product Name: Excelda Manufacturing CompanyCompany Name: 12785 Emerson Dr. Brighton, MI 48116 Medical EmergencyEmergency Contact: (888)314-4052 Transportation Emergency (800)424-9300 Information: (248)486-3800 LAB 1034Reference #: (248)486-3800 Phone Number: Fuel AdditiveIntended Use: 1. PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. GHS Precaution Phrases: P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P308+313: IF exposed or concerned: Get medical attention/advice. P331: Do NOT induce vomiting. GHS Response Phrases: P403+235: Store in cool/well-ventilated place. P405: Store locked up. P501: Dispose of contents/container to a properly licensed facility or broker. GHS Storage and Disposal Phrases: H227: Combustible liquid. H304: May be fatal if swallowed and enters airways. H351: Suspected of causing cancer. GHS Hazard Phrases: Carcinogenicity, Category 2 Aspiration Toxicity, Category 1 Flammable Liquids, Category 4 DangerGHS Signal Word: Skin disorders, blood disorders and liver disorders.Medical Conditions Generally Aggravated By Exposure: Contains ingredients suspected of causing cancer. May be harmful if swallowed. Aspiration Hazard- This material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. See routes of entry for detailed information on effects. Potential Health Effects (Acute and Chronic): Contact may cause stinging, watering, redness, and swelling.Eye Contact: Prolonged or repeated contact may cause drying and cracking of the skin and severe skin damage. No harmful effects from skin absorption have been reported. Skin Contact: A component of this material is toxic. May be harmful if swallowed. Aspiration Hazard- This material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. Ingestion: No information available. Studies by other exposure routes suggest a low degree of toxicity. Due to the presence of distillates, this product may cause depression of the central nervous system if inhaled in large amounts at high concentrations. Inhalation: Licensed to Excelda Manufacturing, Inc. GHS format 10-3012, 88865595 -ACDelco Fuel System Treatment Plus-Gasoline 11/09/2015Revision: 11/24/2015Printed: Page: 2 Gas Treatment 1037 SAFETY DATA SHEET CAS # Chemical Name 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration RTECS # Molecular Formula NA Proprietary Mixture 25.427 -38.847 % NA NA 8008-20-6 Kerosine 29.37 % OA5500000 Not applicable. 64742-47-8 Hydrotreated light distillate (petroleum) 21.189 -28.252 % OA5504000 ? 64742-46-7 Hydrotreated Distillate 7.063 -14.126 % JN9379645 ? 64742-94-5 Solvent naphtha (petroleum), Heavy arom. 0.706 -3.532 % WF3100000 ? 91-20-3 Naphthalene 0.083 -0.365 % QJ0525000 C10H8 71-43-2 Benzene 16.951 PPB CY1400000 C6H6 Additional Chemical Information In Case of Inhalation: 4. FIRST AID MEASURES In the event of an exposure to this product, follow the recommended response indicated for the route(s) of exposure. In all cases if symptoms develop or persist, seek medical attention or advice. Emergency and First Aid Procedures: Treat symptomatically.Note to Physician: Eyes: Discomfort. Skin: Discomfort. Inhalation: Signs of central nervous system depression, such as dizziness, headaches, or other discomfort. Ingestion: Nausea other discomfort. Signs and Symptoms Of Exposure: Move victim away from exposure and into fresh air. If irritation or redness develops, flush eyes with clean water and seek medical attention. For direct contact, hold eyelids apart and flush the affected eye(s) with clean water for at least 15 minutes. In Case of Eye Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area thoroughly by washing with mild soap and water. In Case of Skin Contact: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious, place on the left side with the head down. If possible, do not leave victim unattended. In Case of Ingestion: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If victim is not breathing immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. 5. FIRE FIGHTING MEASURES Flash Pt: > 150.00 F (65.6 C) Method Used: Pensky-Marten Closed Cup Emergency responders in the danger area should wear bunker gear and self-containedFire Fighting Instructions: Autoignition Pt: No data. Explosive Limits: LEL: No data. UEL: No data. Foam, CO2, Dry chemical or halon is recommended. Use water spray to cool fire exposed surfaces and to protect personnel. Halon may decompose into toxic material. Carbon Dioxide can displace oxygen. Use caution when applying halon or carbon dioxide in confined spaces. Suitable Extinguishing Media: Water may be ineffective for extinguishment, unless under favorable conditions by experienced fire fighters. Unsuitable Extinguishing Media: Licensed to Excelda Manufacturing, Inc. GHS format 11/09/2015Revision: 11/24/2015Printed: Page: 3 Gas Treatment 1037 SAFETY DATA SHEET breathing apparatus for fires beyond the incipient stage. In addition, wear other appropriate protective equipment as conditions warrant. Move undamaged containers from danger area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. Some of the combustible vapors emitted by this product may be heavier than air and travel a distance posing a flashback hazard. Flammable Properties and Hazards: 6. ACCIDENTAL RELEASE MEASURES Ventilate the area. Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal. Steps To Be Taken In Case Material Is Released Or Spilled: Wear PPE appropriate for size and nature of release. See Section 8 of this SDS for recommended PPE. Protective Precautions, Protective Equipment and Emergency Procedures: Prevent spilled material form entering sewers, storm drains, other unauthorized treatment drainage systems, and natural waterways. Environmental Precautions: 7. HANDLING AND STORAGE Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Use in well ventilated areas only. Keep away from sources of heat, sparks and open flame. Bond containers when appropriate. Precautions To Be Taken in Handling: Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Keep away from incompatible materials including oxidizing agents and strongly acidic or alkaline materials. Keep away from food, drink and animal feeding stuffs. Precautions To Be Taken in Storing: Empty containers retain residue (liquid and/or vapor) and may be dangerous.Other Precautions: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data. No data. NA Proprietary Mixture No data. No data. TLV: 200 mg/m3 8008-20-6 Kerosine No data. No data. TLV: 200 mg/m3 64742-47-8 Hydrotreated light distillate (petroleum) No data. No data. No data. 64742-46-7 Hydrotreated Distillate No data. No data. No data. 64742-94-5 Solvent naphtha (petroleum), Heavy arom. No data. PEL: 10 ppm TLV: 10 ppm STEL: 15 ppm 91-20-3 Naphthalene No data. PEL: 10 ppm STEL: 50 ppm/(10min) CEIL: 25 ppm TLV: 0.5 ppm STEL: 2.5 ppm 71-43-2 Benzene No data. Licensed to Excelda Manufacturing, Inc. GHS format 11/09/2015Revision: 11/24/2015Printed: Page: 4 Gas Treatment 1037 SAFETY DATA SHEET The use of respiratory protection is advised when concentrations are expected to exceed the established exposure limits. Depending on the airborne concentration, use a respirator with appropriate cartridges (organic mist/vapor) or supplied-air equipment. Respiratory Equipment (Specify Type): Safety glasses and face shield.Eye Protection: Impervious gloves such as nitrile.Protective Gloves: Impervious clothing be worn.Other Protective Clothing: Provide adequate ventilation. General ventilation should be adequate, however if application results in the generation of spray, mists, fumes or vapors, or if application is performed in a poorly ventilated area such as a confined space, additional mechanical ventilation may be required. Engineering Controls (Ventilation etc.): Follow good industrial hygienic practices. When using do not eat, drink or smoke. Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re-use. Provide for quick drenching and eye washing when using this product. Work/Hygienic/Maintenance Practices: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: No data. Autoignition Pt: No data. Flash Pt: > 150.00 F (65.6 C) Method Used: Pensky-Marten Closed Cup Explosive Limits: LEL: No data. UEL: No data. Specific Gravity (Water = 1): 0.83 - 0.89 at 20.0 C (68.0 F) Clear yellow fluid with a strong solvent odor.Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 1): No data. Evaporation Rate: No data. Solubility in Water: No data. Percent Volatile: N.D. VOC / Volume: > 50.0000 WT% Viscosity: < 10 CPS at 40.0 C (104.0 F) 10. STABILITY AND REACTIVITY Stable under normal conditions of storage and handling. Flammable liquid and vapor. Vapor can cause flash fire. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong acids and strong oxidizing agents.Incompatibility - Materials To Avoid: Ammonia. Propylamine, polyalkylglycols and aliphatic alcohols may also be released.Hazardous Decomposition or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: None knownConditions To Avoid - Hazardous Reactions: Licensed to Excelda Manufacturing, Inc. GHS format 11/09/2015Revision: 11/24/2015Printed: Page: 5 Gas Treatment 1037 SAFETY DATA SHEET 11. TOXICOLOGICAL INFORMATION This product has not been tested as a whole. The information contained below pertains to the hazardous components of the mixture. Expected routes of entry when used as intended include: Eye and skin contact Inhalation Toxicological Information: Prolonged or repeated contact may cause drying and cracking of the skin and severe skin damage. Chronic Toxicological Effects: Application of kerosine to mouse skin, twice a week for 12 months, resulted in an increased incidence of skin tumors. Contains less than 1% naphthalene which has been classified by the IARC as a possible human carcinogen (Group 2B) on the basis of sufficient evidence of carcinogenicity in experimental animals but inadequate evidence in exposed humans. Ingestion of naphthalene has caused hemolysis in humans deficient in Carcinogenicity/Other Information: Not expected to cause irritation or corrosion. Irritation or Corrosion: Inhalation: Signs of central nervous system depression, such as dizziness, headaches, or other discomfort. Ingestion: Nausea other discomfort. Symptoms related to Toxicological Characteristics: This product is not known to contain any known sensitizers at concentrations that may be expected to cause an allergic reaction in the general population. Sensitization: CAS# 8008-20-6: Kerosine: Acute toxicity, LD (Lethal dose), Oral, Rat, > 5.000 GM/KG. Result: Behavioral: Somnolence (general depressed activity). Gastrointestinal:Hypermotility, diarrhea. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,30, 1990 CAS# 64742-94-5: Solvent naphtha (petroleum), Heavy arom.: Acute toxicity, LDLO, Oral, Rat, 5.000 ML/KG. Result: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Olfaction:Other changes. Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Other. Skin and Appendages: Other: Hair. - National Technical Information Service, Vol/p/yr: OTS05, 4724 Acute toxicity, LC50, Inhalation, Rat, > 590.0 MG/M3, 4 H. Result: Behavioral: Somnolence (general depressed activity). - National Technical Information Service, Vol/p/yr: OTS05, 4724 Standard Draize Test, Skin, Species: Rabbit, 500.0 UL, 24 H, Mild. Result: Kidney, Ureter, Bladder:Changes in tubules (including acute renal failure, acute tubular necrosis). Blood:Other changes. - National Technical Information Service, Vol/p/yr: OTS05, 4724 Licensed to Excelda Manufacturing, Inc. GHS format 11/09/2015Revision: 11/24/2015Printed: Page: 6 Gas Treatment 1037 SAFETY DATA SHEET CAS # Chemical Name NTP glucose-6-phosphate dehydrogenase. Limited evidence of cataract formation and liver damage has been reported in laboratory animals. IARC ACGIH OSHA NA Proprietary Mixture n.a. n.a. n.a. n.a. 8008-20-6 Kerosine n.a. n.a. A4 n.a. 64742-47-8 Hydrotreated light distillate (petroleum) n.a. n.a. A4 n.a. 64742-46-7 Hydrotreated Distillate n.a. n.a. n.a. n.a. 64742-94-5 Solvent naphtha (petroleum), Heavy arom. n.a. n.a. n.a. n.a. 91-20-3 Naphthalene Possible 2B A4 n.a. 71-43-2 Benzene Known 1 A1 Yes No data available.General Ecological Information: 12. ECOLOGICAL INFORMATION Dispose in accordance with all Federal, State/Provincial and local laws and regulations. As packaged, this product exhibits the following RCRA hazardous characteristic(s): none. Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Not RegulatedDOT Proper Shipping Name: DOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): The information in Section 14 pertains to the product when shipped via domestic ground transportation in non-bulk containers. If this material is shipped internationally, via other modes of transportation, or in bulk packaging, other regulations may apply. Additional Transport Information: CAS # Chemical Name 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists NA Proprietary Mixture No No No 8008-20-6 Kerosine No No No 64742-47-8 Hydrotreated light distillate (petroleum) No No No 64742-46-7 Hydrotreated Distillate No No No 64742-94-5 Solvent naphtha (petroleum), Heavy arom. No No No 91-20-3 Naphthalene No Yes 100 LB Yes 71-43-2 Benzene No Yes 10 LB Yes [X] Yes [ ] No Acute (immediate) Health Hazard [X] Yes [ ] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: Licensed to Excelda Manufacturing, Inc. GHS format 11/09/2015Revision: 11/24/2015Printed: Page: 7 Gas Treatment 1037 SAFETY DATA SHEET CAS # Chemical Name Other US EPA or State Lists NA Proprietary Mixture CAA HAP,ODC: No; CWA NPDES: No; TSCA: No; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 8008-20-6 Kerosine CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS: Yes - 1091; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: No 64742-47-8 Hydrotreated light distillate (petroleum) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 64742-46-7 Hydrotreated Distillate CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 64742-94-5 Solvent naphtha (petroleum), Heavy arom. CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 91-20-3 Naphthalene CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory, 4 Test, 8A PAIR; CA PROP.65: Yes; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: Part 5; NC TAP: Yes; NJ EHS: Yes - 1322; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: Yes; WI Air: Yes 71-43-2 Benzene CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory, 8A CAIR; CA PROP.65: Yes; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: CMR, Part 5; NC TAP: Yes; NJ EHS: Yes - 0197; NY Part 597: Yes; PA HSL: Yes - B; SC TAP: Yes; WI Air: Yes CAS # Chemical Name International Regulatory Lists NA Proprietary Mixture Canadian DSL: No; Canadian NDSL: No; China IECSC: No; Japan ENCS: No; Korea ECL: No; REACH: No 8008-20-6 Kerosine Canadian DSL: Yes; Canadian NDSL: No; China IECSC: Yes; Japan ENCS: Yes - (3)-8; Korea ECL: Yes - KE-21778; REACH: Yes - (R), (P) 64742-47-8 Hydrotreated light distillate (petroleum) Canadian DSL: Yes; Canadian NDSL: No; China IECSC: Yes; Japan ENCS: Yes - (2)-10; Korea ECL: Yes - KE-12550; REACH: Yes - (R), (P) 64742-46-7 Hydrotreated Distillate Canadian DSL: Yes; Canadian NDSL: No; China IECSC: Yes; Japan ENCS: Yes - (9)-1689; Korea ECL: Yes - KE-12554; REACH: Yes - (R), (P), C2 64742-94-5 Solvent naphtha (petroleum), Heavy arom. Canadian DSL: Yes; Canadian NDSL: No; China IECSC: Yes; Japan ENCS: Yes - (7)-710; Korea ECL: Yes - KE-31656; REACH: Yes - (R), (P) 91-20-3 Naphthalene Canadian DSL: Yes; Canadian NDSL: No; China IECSC: Yes; Japan ENCS: Yes - (4)-311; Korea ECL: Yes - KE-25545; REACH: Yes - (R), (P) 71-43-2 Benzene Canadian DSL: Yes; Canadian NDSL: No; China IECSC: Yes; Japan ENCS: Yes - (3)-1; Korea ECL: Yes - KE-02150; Licensed to Excelda Manufacturing, Inc. GHS format 11/09/2015Revision: 11/24/2015Printed: Page: 8 Gas Treatment 1037 SAFETY DATA SHEET REACH: Yes - (R), (P), C1, M2 TSCA: All ingredients in this product are listed on the TSCA Inventory or are otherwise exempt. CA Prop 65: This product is known to contain chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Regulatory Information: The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes all risk in use of the material. Regulatory Information Statement: 16. OTHER INFORMATION No data available.Additional Information About This Product: The ingredient information provided in this SDS is considered confidential by Excelda Manufacturing and as a result, this entire SDS is to be treated as confidential in the form provided. The SDS has been provided in accordance with one or more agreements between Excelda Manufacturing and the recipient(s), and may be used and/or disclosed only as permitted by the terms and conditions of such agreements. Any distribution, release, disclosure or use of this information beyond those listed here is strictly prohibited by Excelda Manufacturing, except as required by law. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA MANUFACTURING. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. EXCELDA MANUFACTURING ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS DATA. Company Policy or Disclaimer: 11/09/2015Revision Date: GSPreparer Name: Licensed to Excelda Manufacturing, Inc. GHS format