27262 PAG YF Refrigeration Lubricant 46 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 02/29/2016 Revision date: 02/29/2016 Supersedes: 09/11/2014 Version: 2.1 02/29/2016 EN (English US) Page 1 SECTION 1: Identification 1.1. Identification Trade name : 27262 PAG YF Refrigeration Lubricant 46 Product code : 27262 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Polyalkylene Glycol based lubricant for use in air conditioning systems. 1.3. Details of the supplier of the safety data sheet Tire Seal, Inc. 3574 Corona Street Lake Worth, Florida 33461 - USA T 561-582-2245 - F 561-582-1499 www.supercool.ac 1.4. Emergency telephone number Emergency number : USA PHONE:1-800-373-7542, INT?L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS08 GHS09 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H227 - Combustible liquid H302 - Harmful if swallowed H317 - May cause an allergic skin reaction H320 - Causes eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H373 - May cause damage to organs through prolonged or repeated exposure Precautionary statements (GHS-US) : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash hands, forearms and face thoroughly after handling P270 - Do not eat, drink or smoke when using this product P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substance Not applicable 3.2. Mixture 27262 PAG YF Refrigeration Lubricant 46 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/29/2016 EN (English US) 2/6 Name Product identifier % GHS-US classification 2,6-di-tert-butyl-p-cresol (CAS No) 128-37-0 0.1 - 1 Acute Tox. 4 (Oral), H302 2,6-diisopropylphenyl isocyanate (CAS No) 28178-42-9 0.7 - 0.7 Acute Tox. 4 (Oral), H302 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. 27262 PAG YF Refrigeration Lubricant 46 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/29/2016 EN (English US) 3/6 Incompatible materials : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2,6-di-tert-butyl-p-cresol (128-37-0) ACGIH ACGIH TWA (mg/m?) 2 mg/m? (Butylated hydroxytoluene (BHT); USA; Time- weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction and vapor) Not applicable 2,6-diisopropylphenyl isocyanate (28178-42-9) Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : The use of gloves impervious to the specific material handled is advised to prevent skin contact. Suggested protective material: Nitrile, 4.5 mil thickness, tested at 3.5 ml and above with no breakthrough time after 240 minutes. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Where there is potential for airborne exposure above the exposure limit an approved air purifying respirator equipped with Type P2 - Medium efficiency particle filters may be used. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear. Color : Colorless to Yellowish Odor : Characteristic Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : > 200 ?C Calculated Flash point : 174 ?C Closed Cup Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : No data available Explosion limits : No data available Explosive properties : No data available Oxidizing properties : No data available Vapor pressure : No data available Relative density : No data available Relative vapor density at 20 ?C : No data available Solubility : Unknown. Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity, kinematic : 41.4 - 50.6 cSt @40?C Viscosity, dynamic : No data available 9.2. Other information No additional information available 27262 PAG YF Refrigeration Lubricant 46 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/29/2016 EN (English US) 4/6 SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2,6-di-tert-butyl-p-cresol (128-37-0) LD50 oral rat 890 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; >6000 mg/kg bodyweight; Rat) LD50 dermal rat > 2000 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg bodyweight; Rat; Experimental value) ATE US (oral) 890.000 mg/kg body weight 2,6-diisopropylphenyl isocyanate (28178-42-9) LD50 oral rat 1414 mg/kg (Rat) LC50 inhalation rat (mg/l) 0.047 mg/l/4h (Rat) ATE US (oral) 1414.000 mg/kg body weight ATE US (vapors) 0.047 mg/l/4h ATE US (dust, mist) 0.047 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified 2,6-di-tert-butyl-p-cresol (128-37-0) IARC group 3 - Not classifiable Reproductive toxicity : Not classified Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Toxic to aquatic life. 27262 PAG YF Refrigeration Lubricant 46 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/29/2016 EN (English US) 5/6 2,6-di-tert-butyl-p-cresol (128-37-0) LC50 fish 1 >= 0.57 mg/l (LC0; EU Method C.1; 96 h; Brachydanio rerio; Semi-static system; Fresh water; Experimental value) EC50 Daphnia 1 0.48 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) LC50 fish 2 0.199 mg/l (LC50; ECOSAR v1.00; 96 h; Pisces) EC50 Daphnia 2 0.15 mg/l (NOEC; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) 12.2. Persistence and degradability 27262 PAG YF Refrigeration Lubricant 46 Persistence and degradability Not established. 2,6-di-tert-butyl-p-cresol (128-37-0) Persistence and degradability Not readily biodegradable in water. Biodegradable in the soil. Adsorbs into the soil. Low potential for mobility in soil. Photooxidation in the air. Biochemical oxygen demand (BOD) 0.51 g O?/g substance Chemical oxygen demand (COD) 2.27 g O?/g substance ThOD 2.977 g O?/g substance BOD (% of ThOD) 0.17 2,6-diisopropylphenyl isocyanate (28178-42-9) Persistence and degradability Biodegradability in water: no data available. 12.3. Bioaccumulative potential 27262 PAG YF Refrigeration Lubricant 46 Bioaccumulative potential Not established. 2,6-di-tert-butyl-p-cresol (128-37-0) BCF fish 1 230 - 2500 (BCF; OECD 305: Bioconcentration: Flow-Through Fish Test; 56 days; Cyprinus carpio; Flow-through system; Fresh water; Experimental value) Log Pow 5.1 (Experimental value) Bioaccumulative potential Potential for bioaccumulation (500 ? BCF ? 5000). 2,6-diisopropylphenyl isocyanate (28178-42-9) Bioaccumulative potential No bioaccumulation data available. 12.4. Mobility in soil 2,6-di-tert-butyl-p-cresol (128-37-0) Log Koc Koc,PCKOCWIN v1.66; 23030; Calculated value; log Koc; PCKOCWIN v1.66; 4.362; Calculated value Ecology - soil May be harmful to plant growth, blooming and fruit formation. 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport TDG No additional information available 27262 PAG YF Refrigeration Lubricant 46 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 02/29/2016 EN (English US) 6/6 Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations No additional information available 15.2. International regulations CANADA 27262 PAG YF Refrigeration Lubricant 46 WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Revision date : 02/29/2016 Other information : None. Full text of H-phrases: see section 16: ------ H302 Harmful if swallowed NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Tire Seal, Inc. The data on this sheet related only to the specific material designed herein. Tire Seal, Inc. assumes no legal responsibility for the use or reliance upon these data.