TruFuel 50:1 Mix 0125600 Consumer products: Fuel. Industrial applications: Fuel. Calumet Packaging 10411 Highway 1 Shreveport, LA 71115 USA 318-795-3800 24hr. CHEMTREC 1-800-424-9300 / International 1-703-527-3887 Material Safety Data Sheet Product name Supplier Material uses Product code Validation date In case of emergency 1. Product and company identification TruFuel 50:1 Mix : : : : : : Product type : Liquid. 10/14/2013. Version : 2 Signal word 2. Hazards identification Routes of entry Potential acute health effects Can cause central nervous system (CNS) depression. Severely irritating to eyes. Risk of serious damage to eyes. Harmful if swallowed. Can cause central nervous system (CNS) depression. Aspiration hazard if swallowed. Can enter lungs and cause damage. Irritating to skin. Eyes Skin Inhalation Ingestion Physical state Liquid. [Mobile liquid.] See toxicological information (Section 11) DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE. INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CAN CAUSE CANCER. POSSIBLE REPRODUCTIVE HAZARD - MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS IN FEMALES, BASED ON ANIMAL DATA. : : : : : : : Odor : Characteristic. Hydrocarbon. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Color : Red. Emergency overview Hazard statements : Precautionary measures : Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep away from heat, sparks and flame. Keep container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling. Eyes, Skin, Ingestion, Inhalation 1/1010/14/2013. 0125600 TruFuel 50:1 Mix Naphtha (petroleum), full-range alkylate, butane-contg. 68527-27-5 50 - 60 isopentane 78-78-4 10 - 20 pentane 109-66-0 10 - 20 toluene 108-88-3 5 - 10 xylene 1330-20-7 5 - 10 ethylbenzene 100-41-4 1 - 5 3. Composition/information on ingredients Name CAS number % by weight There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Use dry chemical, CO?, water spray (fog) or foam. 5. Fire-fighting measures Extinguishing media Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : Special exposure hazards : Do not use water jet. Suitable : Not suitable : Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide Flammability of the product : 2/1010/14/2013. 0125600 TruFuel 50:1 Mix No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 6. Accidental release measures : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods for cleaning up Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 7. Handling and storage Handling Storage : : 3/1010/14/2013. 0125600 TruFuel 50:1 Mix Naphtha (petroleum), full-range alkylate, butane- contg. ACGIH TLV (United States). TWA: 200 ppm 8 hours. isopentane ACGIH TLV (United States, 3/2012). TWA: 600 ppm 8 hours. pentane ACGIH TLV (United States, 3/2012). TWA: 600 ppm 8 hours. OSHA PEL (United States, 6/2010). TWA: 1000 ppm 8 hours. TWA: 2950 mg/m? 8 hours. toluene ACGIH TLV (United States, 3/2012). TWA: 20 ppm 8 hours. xylene ACGIH TLV (United States, 3/2012). TWA: 100 ppm 8 hours. TWA: 434 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m? 15 minutes. OSHA PEL (United States, 6/2010). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. ethylbenzene ACGIH TLV (United States, 3/2012). TWA: 20 ppm 8 hours. OSHA PEL (United States, 6/2010). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protection Respiratory : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Ingredient Exposure limits 4/1010/14/2013. 0125600 TruFuel 50:1 Mix 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Eyes Skin : : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 34.444 to 190.56?C (94 to 375?F) Liquid. [Mobile liquid.] 0.72 Insoluble in the following materials: cold water and hot water. Characteristic. Hydrocarbon. Red. Boiling/condensation point Kinematic (40?C (104?F)): <0.01 cm2/s (<1 cSt) 9. Physical and chemical properties Physical state Relative density Viscosity Solubility Odor Color : : : : : : : Flash point : Closed cup: -40?C (-40?F) [Tagliabue.] 65:API Gravity @60?F The product is stable. Highly reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 10. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products : : : : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. 11. Toxicological information Acute toxicity Naphtha (petroleum), full- range alkylate, butane-contg. LD50 Oral Rat >5000 mg/kg - isopentane LC50 Inhalation Vapor Rat 280000 mg/m? 4 hours pentane LC50 Inhalation Vapor Rat 364 g/m? 4 hours xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours LD50 Oral Rat 4300 mg/kg - ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - toluene LC50 Inhalation Vapor Rat 49 g/m? 4 hours LD50 Oral Rat 636 mg/kg - Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Not available. 5/1010/14/2013. 0125600 TruFuel 50:1 Mix 11. Toxicological information Chronic toxicity Conclusion/Summary : Not available. Carcinogenicity Conclusion/Summary : Animal tumorigen. May cause tumors. Mutagenicity Conclusion/Summary : Not available. Teratogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Reproductive toxicant - female Suspected of damaging the unborn child if inhaled. Classification toluene A4 3 - - - - xylene A4 3 - - - - ethylbenzene A3 2B - - - - Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA 12. Ecological information Ecotoxicity : No known significant effects or critical hazards. Aquatic ecotoxicity xylene Acute LC50 8500 ?g/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 3300 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours ethylbenzene Acute EC50 4600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 6530 ?g/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2930 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours toluene Acute EC50 12500 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 ?g/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 ?g/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 ?g/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours Chronic NOEC 1000 ?g/l Fresh water Daphnia - Daphnia magna 21 days Product/ingredient name SpeciesResult Exposure Conclusion/Summary : Not available. Persistence/degradability Conclusion/Summary : Not available. 6/1010/14/2013. 0125600 TruFuel 50:1 Mix The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 13. Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. : RCRA classification : D001 [Flammable] Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. 14. Transport information 3 Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 5 L Cargo aircraft Quantity limitation: 60 L Special provisions 144, 177, B1, B33, IB2, T8 Remarks May be classed as a Consumer Commodity, ORM-D for Small Packages, see 49CFR 173.150 DOT Classification Gasoline II IMDG Class GASOLINE. Marine pollutant (pentane, toluene) 3 II Regulatory information UN number Proper shipping name Classes PG* Label Additional information UN1203 Emergency schedules (EmS) F-E, S-E UN1203 7/1010/14/2013. 0125600 TruFuel 50:1 Mix 14. Transport information GasolineUN1203IATA-DGR Class 3 II Passenger and Cargo Aircraft Quantity limitation: 5 L Packaging instructions: 353 Cargo Aircraft Only Quantity limitation: 60 L Packaging instructions: 364 Limited Quantities - Passenger Aircraft Quantity limitation: 1 L Packaging instructions: Y341 PG* : Packing group Flammable liquid Irritating material Carcinogen Target organ effects HCS Classification 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 307: ethylbenzene; toluene Clean Water Act (CWA) 311: xylene; ethylbenzene; toluene Clean Air Act (CAA) 112 regulated flammable substances: isopentane; pentane SARA 302/304: No products were found. SARA 311/312 Hazards identification: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard : SARA 313 : Product name CAS number Concentration toluene 108-88-3 5 - 10 xylene 1330-20-7 5 - 10 ethylbenzene 100-41-4 1 - 5 toluene 108-88-3 5 - 10 xylene 1330-20-7 5 - 10 ethylbenzene 100-41-4 1 - 5 Form R - Reporting requirements Supplier notification Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Listed TSCA 8(a) PAIR: pentane TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. 8/1010/14/2013. 0125600 TruFuel 50:1 Mix 15. Regulatory information The following components are listed: XYLENE; ETHYL BENZENE; TOLUENE; ISOPENTANE; PENTANE WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Massachusetts The following components are listed: Xylene (all isomers); Ethylbenzene; Toluene; Pentane (all isomers); Pentane (all isomers) Australia inventory (AICS): All components are listed or exempted. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: All components are listed or exempted. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. WHMIS (Canada) Class B-2: Flammable liquid Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). International regulations International lists : : Canada SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. toluene No. Yes. No. 7000 ?g/day (ingestion) ethylbenzene Yes. No. 41 ?g/day (ingestion) 54 ?g/day (inhalation) No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level Canadian NPRI California Prop. 65 Canada inventory : All components are listed or exempted. Chemical Weapons Convention List Schedule I Chemicals : Not listed Chemical Weapons Convention List Schedule II Chemicals : Not listed Chemical Weapons Convention List Schedule III Chemicals : Not listed New York : The following components are listed: Xylene (mixed); Ethylbenzene; Toluene New Jersey : The following components are listed: XYLENES; BENZENE, DIMETHYL-; ETHYL BENZENE; BENZENE, ETHYL-; TOLUENE; BENZENE, METHYL-; ISOPENTANE; BUTANE, 2-METHYL-; PENTANE Pennsylvania : The following components are listed: BENZENE, DIMETHYL-; BENZENE, ETHYL-; BENZENE, METHYL-; BUTANE, 2-METHYL-; PENTANE State regulations CEPA Toxic substances None of the components are listed. Canadian lists Europe inventory : All components are listed or exempted. 9/1010/14/2013. 0125600 TruFuel 50:1 Mix 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 Health Flammability Physical hazards EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE. INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CAN CAUSE CANCER. POSSIBLE REPRODUCTIVE HAZARD - MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS IN FEMALES, BASED ON ANIMAL DATA. Label requirements : Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Date of previous issue Version : : : : Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Indicates information that has changed from previously issued version. 10/14/2013. 9/18/2013. 2 Prepared by : Technical Department 10/1010/14/2013. 0125600