TruFuel 50:1 Mix Not available. Liquid. 24 hr. CHEMTREC 1-800-424-9300 / International 1-703-527-3887 SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details : Calumet Packaging 10411 Highway 1 Shreveport, LA 71115 USA 318-795-3800 TruFuel 50:1 Mix Relevant identified uses of the substance or mixture and uses advised against Identified uses Not available. Uses advised against Reason Consumer products: Fuel. Industrial applications: Fuel. Product code : 0125600 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 1 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A CARCINOGENICITY - Category 1B TOXIC TO REPRODUCTION (Fertility) - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 AQUATIC HAZARD (ACUTE) - Category 3 AQUATIC HAZARD (LONG-TERM) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown hazards to the aquatic environment: 11.8% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 04/02/2015 Version : 0.02 1/16 TruFuel 50:1 Mix Section 2. Hazards identification Hazard statements : Extremely flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause cancer. Suspected of damaging fertility or the unborn child. May be fatal if swallowed and enters airways. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not breathe vapor. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Supplemental label elements : Avoid contact with skin and clothing. Wash thoroughly after handling. Hazards not otherwise classified : Prolonged or repeated contact may dry skin and cause irritation. Section 3. Composition/information on ingredients Naphtha (petroleum), full-range alkylate, butane-contg. ?50 - <75 68527-27-5 pentane ?10 - <25 109-66-0 toluene ?6 - <10 108-88-3 xylene ?5 - <9.8 1330-20-7 ethylbenzene ?1 - <1.8 100-41-4 Naphtha (petroleum), hydrotreated light ?0.3 - <1 64742-49-0 Distillates (petroleum), sweetened middle ?0.1 - <0.3 64741-86-2 n-hexane ?0.1 - <0.3 110-54-3 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture CAS number/other identifiers : Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision : 04/02/2015 Version : 0.02 2/16 TruFuel 50:1 Mix Section 3. Composition/information on ingredients Occupational exposure limits, if available, are listed in Section 8. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Defatting to the skin. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 04/02/2015 Version : 0.02 3/16 TruFuel 50:1 Mix Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Skin contact Ingestion Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness dryness cracking reduced fetal weight increase in fetal deaths skeletal malformations : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel Date of issue/Date of revision : 04/02/2015 Version : 0.02 4/16 TruFuel 50:1 Mix Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision : 04/02/2015 Version : 0.02 5/16 TruFuel 50:1 Mix Naphtha (petroleum), full-range alkylate, butane-contg. ACGIH TLV (United States). TWA: 200 ppm 8 hours. pentane ACGIH TLV (United States, 4/2014). TWA: 1000 ppm 8 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 2950 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 600 ppm 8 hours. TWA: 1800 mg/m? 8 hours. STEL: 750 ppm 15 minutes. STEL: 2250 mg/m? 15 minutes. NIOSH REL (United States, 10/2013). TWA: 120 ppm 10 hours. TWA: 350 mg/m? 10 hours. CEIL: 610 ppm 15 minutes. CEIL: 1800 mg/m? 15 minutes. toluene ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 375 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 375 mg/m? 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. xylene ACGIH TLV (United States, 4/2014). TWA: 100 ppm 8 hours. TWA: 434 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m? 15 minutes. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. STEL: 150 ppm 15 minutes. STEL: 655 mg/m? 15 minutes. ethylbenzene ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision : 04/02/2015 Version : 0.02 6/16 TruFuel 50:1 Mix Section 8. Exposure controls/personal protection TWA: 435 mg/m? 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. Naphtha (petroleum), hydrotreated light OSHA PEL (United States). TWA: 500 ppm 8 hours. TWA: 1800 mg/m? 8 hours. ACGIH TLV (United States). TWA: 50 ppm 8 hours. Distillates (petroleum), sweetened middle ACGIH TLV (United States). TWA: 200 ppm 8 hours. n-hexane ACGIH TLV (United States, 4/2014). Absorbed through skin. TWA: 50 ppm 8 hours. OSHA PEL (United States, 2/2013). TWA: 500 ppm 8 hours. TWA: 1800 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 180 mg/m? 8 hours. NIOSH REL (United States, 10/2013). TWA: 50 ppm 10 hours. TWA: 180 mg/m? 10 hours. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision : 04/02/2015 Version : 0.02 7/16 TruFuel 50:1 Mix Section 8. Exposure controls/personal protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. [Mobile liquid.] Not available. 0.72 Not available. Not available. Insoluble in the following materials: cold water and hot water. Characteristic. Hydrocarbon.Odor pH Red.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: -40?C (-40?F) [Tagliabue.] Not available. Not available. Viscosity Kinematic (40?C (104?F)): <0.01 cm2/s (<1 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : 34.444 to 190.56?C (94 to 375?F) Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Decomposition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 04/02/2015 Version : 0.02 8/16 TruFuel 50:1 Mix Section 11. Toxicological information Acute toxicity Naphtha (petroleum), full- range alkylate, butane-contg. LD50 Oral Rat >5000 mg/kg - pentane LC50 Inhalation Vapor Rat 364 g/m? 4 hours toluene LC50 Inhalation Vapor Rat 49 g/m? 4 hours LD50 Oral Rat 636 mg/kg - xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours LD50 Oral Rat 4300 mg/kg - ethylbenzene LC50 Inhalation Gas. Rat 4000 ppm 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - Naphtha (petroleum), hydrotreated light LC50 Inhalation Vapor Rat >5.2 mg/l 4 hours LD50 Dermal Rat >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - Distillates (petroleum), sweetened middle LC50 Inhalation Dusts and mists Rat 4.6 mg/l 4 hours LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - n-hexane LC50 Inhalation Gas. Rat 48000 ppm 4 hours LD50 Oral Rat 15840 mg/kg - Product/ingredient name Result Species Dose Exposure Mutagenicity Irritation/Corrosion toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams - Eyes - Mild irritant Rabbit - 870 Micrograms - Eyes - Severe irritant Rabbit - 24 hours 2 milligrams - Skin - Mild irritant Pig - 24 hours 250 microliters - Skin - Mild irritant Rabbit - 435 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Skin - Moderate irritant Rabbit - 500 milligrams - xylene Eyes - Mild irritant Rabbit - 87 milligrams - Eyes - Severe irritant Rabbit - 24 hours 5 milligrams - Skin - Mild irritant Rat - 8 hours 60 microliters - Skin - Moderate irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 100 Percent - ethylbenzene Eyes - Severe irritant Rabbit - 500 milligrams - Skin - Mild irritant Rabbit - 24 hours 15 milligrams - Naphtha (petroleum), hydrotreated light Eyes - Mild irritant Rabbit - 10 milligrams - n-hexane Eyes - Mild irritant Rabbit - 10 milligrams - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision : 04/02/2015 Version : 0.02 9/16 TruFuel 50:1 Mix Section 11. Toxicological information Carcinogenicity Not available. Conclusion/Summary : Animal tumorigen. May cause tumors. Not available. Teratogenicity Not available. Reproductive toxicity Conclusion/Summary : Reproductive toxicant - female Suspected of damaging the unborn child if inhaled. Not available. Information on the likely routes of exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Naphtha (petroleum), full-range alkylate, butane-contg. Category 3 Not applicable. Narcotic effects pentane Category 3 Not applicable. Narcotic effects toluene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects xylene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects ethylbenzene Category 3 Not applicable. Narcotic effects Naphtha (petroleum), hydrotreated light Category 3 Not applicable. Narcotic effects n-hexane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category toluene Category 2 Not determined kidneys and liver ethylbenzene Category 2 Not determined ears Distillates (petroleum), sweetened middle Category 2 Not determined blood system, liver and thymus n-hexane Category 2 Not determined peripheral nervous system Aspiration hazard Name Result Naphtha (petroleum), full-range alkylate, butane-contg. ASPIRATION HAZARD - Category 1 pentane ASPIRATION HAZARD - Category 1 toluene ASPIRATION HAZARD - Category 1 xylene ASPIRATION HAZARD - Category 1 ethylbenzene ASPIRATION HAZARD - Category 1 Naphtha (petroleum), hydrotreated light ASPIRATION HAZARD - Category 1 Distillates (petroleum), sweetened middle ASPIRATION HAZARD - Category 1 n-hexane ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs : Not available. Classification toluene - 3 - xylene - 3 - ethylbenzene - 2B - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 04/02/2015 Version : 0.02 10/16 TruFuel 50:1 Mix Section 11. Toxicological information Not available. Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Defatting to the skin. Causes serious eye irritation.:Eye contact May cause damage to organs through prolonged or repeated exposure. Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness dryness cracking reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 04/02/2015 Version : 0.02 11/16 TruFuel 50:1 Mix Section 11. Toxicological information Numerical measures of toxicity Oral 5728.6 mg/kg Dermal 11934.8 mg/kg Inhalation (gases) 44920.8 ppm Route ATE value Acute toxicity estimates Section 12. Ecological information Product/ingredient name Aquatic half-life Photolysis Biodegradability toluene - - Readily xylene - - Readily ethylbenzene - - Readily Naphtha (petroleum), hydrotreated light - - Inherent Distillates (petroleum), sweetened middle - - Not readily Toxicity toluene Acute EC50 12500 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 11600 ?g/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 ?g/l Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 48 hours Acute LC50 5500 ?g/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours Chronic NOEC 1000 ?g/l Fresh water Daphnia - Daphnia magna 21 days xylene Acute LC50 8500 ?g/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 ?g/l Fresh water Fish - Pimephales promelas 96 hours ethylbenzene Acute EC50 4600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 3600 ?g/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 6530 ?g/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours Acute EC50 2930 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 4200 ?g/l Fresh water Fish - Oncorhynchus mykiss 96 hours Naphtha (petroleum), hydrotreated light Acute EC50 1 to 10 mg/l Algae 72 hours Acute EC50 1 to 10 mg/l Daphnia 48 hours Acute LC50 1 to 10 mg/l Fish 96 hours Distillates (petroleum), sweetened middle Chronic EC50 2 to 100 mg/l Algae 72 hours Chronic EC50 2 to 100 mg/l Crustaceans 48 hours n-hexane Acute LC50 2500 ?g/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability ethylbenzene 301B Ready Biodegradability - CO? Evolution Test 70 to 80 % - 28 days - - Product/ingredient name Test DoseResult Inoculum Date of issue/Date of revision : 04/02/2015 Version : 0.02 12/16 TruFuel 50:1 Mix Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Naphtha (petroleum), full- range alkylate, butane-contg. - 10 to 2500 high pentane 3.45 171 low toluene 2.73 90 low xylene 3.12 8.1 to 25.9 low ethylbenzene 3.6 - low Naphtha (petroleum), hydrotreated light 2.2 to 5.2 10 to 2500 high Distillates (petroleum), sweetened middle ?4 - high n-hexane 4 501.187 high Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods RCRA classification : D001 [Flammable] United States - RCRA Toxic hazardous waste "U" List Xylene 1330-20-7 Listed U239 Toluene; Benzene, methyl- 108-88-3 Listed U220 Ingredient CAS # Status Reference number Section 14. Transport information Gasoline 3 GASOLINE 3 Gasoline UN1203 3 UN1203 UN1203 DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) TDG Classification UN1203 Gasoline 3 Date of issue/Date of revision : 04/02/2015 Version : 0.02 13/16 TruFuel 50:1 Mix Section 14. Transport information II II II Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 5 L Cargo aircraft Quantity limitation: 60 L Special provisions 144, 177, B1, B33, IB2, T8 Remarks May be classed as a Consumer Commodity, ORM-D for Small Packages, see 49CFR 173.150 Emergency schedules (EmS) F-E, S-E Special provisions 243 Passenger and Cargo AircraftQuantity limitation: 5 L Packaging instructions: 353 Cargo Aircraft Only Quantity limitation: 60 L Packaging instructions: 364 Limited Quantities - Passenger Aircraft Quantity limitation: 1 L Packaging instructions: Y341 Special provisions A100 Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : I No. - Section 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 307: ethylbenzene; toluene Clean Water Act (CWA) 311: xylene; ethylbenzene; toluene Clean Air Act (CAA) 112 regulated flammable substances: isopentane; pentane : Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Listed TSCA 8(a) PAIR: pentane TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted. SARA 302/304 No products were found. Composition/information on ingredients Date of issue/Date of revision : 04/02/2015 Version : 0.02 14/16 TruFuel 50:1 Mix Section 15. Regulatory information The following components are listed: XYLENE; ETHYL BENZENE; TOLUENE; ISOPENTANE; PENTANE WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Massachusetts : SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. toluene No. Yes. No. 7000 ?g/day (ingestion) ethylbenzene Yes. No. 41 ?g/day (ingestion) No. 54 ?g/day (inhalation) Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level toluene 108-88-3 ?6 - <10 xylene 1330-20-7 ?5 - <9.8 ethylbenzene 100-41-4 ?1 - <1.8 toluene 108-88-3 ?6 - <10 xylene 1330-20-7 ?5 - <9.8 ethylbenzene 100-41-4 ?1 - <1.8 Form R - Reporting requirements Supplier notification California Prop. 65 New York : The following components are listed: Xylene (mixed); Ethylbenzene; Toluene New Jersey : The following components are listed: XYLENES; BENZENE, DIMETHYL-; ETHYL BENZENE; BENZENE, ETHYL-; TOLUENE; BENZENE, METHYL-; ISOPENTANE; BUTANE, 2-METHYL-; PENTANE Pennsylvania : The following components are listed: BENZENE, DIMETHYL-; BENZENE, ETHYL-; BENZENE, METHYL-; BUTANE, 2-METHYL-; PENTANE State regulations SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard Naphtha (petroleum), full-range alkylate, butane-contg. ?50 - <75 Yes. No. No. Yes. No. pentane ?10 - <25 Yes. No. No. Yes. No. toluene ?6 - <10 Yes. No. No. Yes. Yes. xylene ?5 - <9.8 Yes. No. No. Yes. Yes. ethylbenzene ?1 - <1.8 Yes. No. No. Yes. Yes. Naphtha (petroleum), hydrotreated light ?0.3 - <1 Yes. No. No. Yes. Yes. Distillates (petroleum), sweetened middle ?0.1 - <0.3 Yes. No. No. Yes. Yes. n-hexane ?0.1 - <0.3 Yes. No. No. Yes. Yes. Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients International lists National inventory Australia : All components are listed or exempted. Date of issue/Date of revision : 04/02/2015 Version : 0.02 15/16 TruFuel 50:1 Mix Section 15. Regulatory information Canada : All components are listed or exempted. China : Not determined. Europe : All components are listed or exempted. Japan : Not determined. Republic of Korea : All components are listed or exempted. Malaysia : Not determined. New Zealand : Not determined. Philippines : Not determined. Taiwan : All components are listed or exempted. Section 16. Other information History Date of issue/Date of revision Version To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader : : Indicates information that has changed from previously issued version. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 04/02/2015 0.02 Procedure used to derive the classification Classification Justification Flam. Liq. 1, H224 On basis of test data Skin Irrit. 2, H315 Calculation method Eye Irrit. 2A, H319 Calculation method Carc. 1B, H350 Calculation method Repr. 2, H361 (Fertility) Calculation method Repr. 2, H361 (Unborn child) Calculation method STOT SE 3, H336 Calculation method STOT RE 2, H373 Calculation method Asp. Tox. 1, H304 Calculation method Aquatic Acute 3, H402 Calculation method Aquatic Chronic 3, H412 Calculation method Date of issue/Date of revision : 04/02/2015 Version : 0.02 16/16