FVP 50% STARTING FLUID Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 07/12/18 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : FVP 50% STARTING FLUID 7.2 OZ. Product code : FVPSF7-12 Other means of identification : This diesel fuel additive complies with federal low sulfur content requirements for us in diesel motor vehicles and non-road engines. 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Starting Fluid 1.3. Details of the supplier of the safety data sheet Factory Motor Parts 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 (866) 387-3343 1.4. Emergency telephone number Emergency number : Infotrac 1-800-535-5053 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Aerosol 1 H222 Compressed gas H280 Skin Irrit. 2 H315 Repr. 2 H361 STOT SE 3 H336 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Hazard pictograms (GHS-US) : GHS02 GHS04 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H222 - Extremely flammable aerosol H280 - Contains gas under pressure; may explode if heated H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat,sparks,open flames,hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing dust,fume,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves,protective clothing,eye protection,face protection P302+P352 - If on skin: Wash with plenty of soap and water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. P321 - Specific treatment: See section 4.1 on SDS P332+P313 - If skin irritation occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P410+P403 - Protect from sunlight. Store in a well-ventilated place P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 05/10/2015 EN (English US) 1/11 05/10/2015 EN (English US) 2/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) No data available : Contains gas under pressure; may explode if heated. None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Diethyl Ether (CAS No) ?60-29-7 50 - 70 Flam. Liq. 1, H224 Acute Tox. 4 (Oral), H302 STOT SE 3, H336 Petroleum Gases, Liquefied, Sweetened (CAS No) ?68476-86-8 10 - 30 Flam. Gas 1, H220 Flam. Liq. 1, H224 Heptane, Branched Cyclic (CAS No) ?426260-76-6 15.264 - 15.9 Flam. Liq. 1, H224 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 n-Heptane (CAS No) ?142-82-5 3.975 - 7.155 Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Carbon Dioxide, Liquefied, Under Pressure (CAS No) ?124-38-9 5 - 10 Compressed gas, H280 Distillates (Petroleum), Hydrotreated Heavy Naphthenic (CAS No) ?64742-52-5 < 1 Not classified Toluene (CAS No) ?108-88-3 0.159 - 0.636 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Cough. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Direct contact with the eyes is likely to be irritating. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/injuries after inhalation : Shortness of breath. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Itching. Red skin. Skin rash/inflammation. Causes skin irritation. Symptoms/injuries after eye contact : May cause slight eye irritation . May cause severe irritation. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. 05/10/2015 EN (English US) 3/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable aerosol. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 05/10/2015 EN (English US) 4/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire reaches explosives. Evacuate area. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : Aerosol level 3. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove ignition sources. Use special care to avoid static electric charges. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not spray on an open flame or other ignition source. Obtain special instructions . Do not handle until all safety precautions have been read and understood. Avoid breathing dust,fume,gas,mist,vapor spray. Use only outdoors or in a well-ventilated area. Hygiene measures : Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Remove contaminated clothes. Always wash hands after handling the product. Separate working clothes from town clothes. Launder separately. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Diethyl Ether (60-29-7) USA ACGIH ACGIH TWA (mg/m?) 1200 USA ACGIH ACGIH TWA (ppm) 400 ppm (Ethyl ether; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) 05/10/2015 EN (English US) 5/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations USA ACGIH ACGIH STEL (mg/m?) 1500 mg/m? USA ACGIH ACGIH STEL (ppm) 500 ppm 05/10/2015 EN (English US) 6/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Diethyl Ether (60-29-7) USA OSHA OSHA PEL (TWA) (mg/m?) 1200 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 400 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (mg/m?) 75 mg/m? USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm n-Heptane (142-82-5) USA ACGIH ACGIH TWA (ppm) 400 ppm (Heptane, all isomers; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) USA ACGIH ACGIH STEL (ppm) 500 ppm (Heptane, all isomers; USA; Short time value; TLV - Adopted Value) Heptane, Branched Cyclic (426260-76-6) USA ACGIH ACGIH TWA (ppm) 400 ppm USA ACGIH ACGIH STEL (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? MIST 8 HOURS USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? MIST 8 HOURS Petroleum Gases, Liquefied, Sweetened (68476-86-8) USA ACGIH ACGIH TWA (ppm) 1000 ppm Listed under Aliphatic hydrocarbon gases alkane C1-C4 USA OSHA OSHA PEL (TWA) (mg/m?) 1800 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Carbon Dioxide, Liquefied, Under Pressure (124-38-9) USA ACGIH ACGIH TWA (mg/m?) 9000 mg/m? USA ACGIH ACGIH TWA (ppm) 5000 ppm (Carbon dioxide; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) USA ACGIH ACGIH STEL (mg/m?) 54000 USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Other information : Do not eat, drink or smoke during use. 05/10/2015 EN (English US) 7/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid. Color : Colourless to light yellow. Odor : Ether-like odour. Odor threshold : No data available 05/10/2015 EN (English US) 8/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : -31.1 ?C (Lowest Component) Flash point : -96.23 ?C (Lowest Component) Auto-ignition temperature : 180 ?C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Solubility : Poorly soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : Heating may cause a fire or explosion. Oxidizing properties : No data available Explosion limits : No data available 9.2. Other information VOC content : 93.3 % Gas group : Compressed gas SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Diethyl Ether (60-29-7) LD50 oral rat 1215 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Experimental value; 1600 mg/kg bodyweight; Rat) LD50 dermal rabbit > 14200 mg/kg (Rabbit) LC50 inhalation rat (mg/l) 99 mg/l/4h (Rat) LC50 inhalation rat (ppm) 32000 ppm/4h (Rat) Toluene (108-88-3) LD50 oral rat 5580 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Literature study; 5580 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 5000 mg/kg body weight LD50 quoted as 14.1 mL/kg (12267 mg/kg using density of 0.87) 05/10/2015 EN (English US) 9/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations LC50 inhalation rat (mg/l) > 28.1 mg/l/4h (Rat; Air, Literature study) n-Heptane (142-82-5) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) 05/10/2015 EN (English US) 10/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations n-Heptane (142-82-5) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) Heptane, Branched Cyclic (426260-76-6) LD50 oral rat > 15000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg bodyweight; Rat; Read-across) LD50 dermal rabbit > 3160 mg/kg (Rabbit; Literature study; Equivalent or similar to OECD 402; >2000 mg/kg bodyweight; Rabbit; Read-across) LC50 inhalation rat (mg/l) 103 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) 25000 ppm/4h (Rat; Literature study) Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg body weight LD50 dermal rabbit > 2000 mg/kg body weight LC50 inhalation rat (mg/l) > 5.2 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Toluene (108-88-3) IARC group 3 Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) IARC group 3 Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Shortness of breath. May cause drowsiness or dizziness. Symptoms/injuries after skin contact : Itching. Red skin. Skin rash/inflammation. Causes skin irritation. Symptoms/injuries after eye contact : May cause slight eye irritation . May cause severe irritation. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity Diethyl Ether (60-29-7) LC50 fish 2 2560 mg/l (LC50; 96 h; Pimephales promelas) EC50 Daphnia 2 1380 mg/l (EC50; 48 h) n-Heptane (142-82-5) EC50 Daphnia 1 0.2 mg/l (LC50; Other; 96 h; Chaetogammarus marinus; Semi-static system; Salt water; Experimental value) Carbon Dioxide, Liquefied, Under Pressure (124-38-9) LC50 fish 1 35 mg/l (LC50; 96 h; Salmo gairdneri) 12.2. Persistence and degradability JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Persistence and degradability Not established. Diethyl Ether (60-29-7) 05/10/2015 EN (English US) 11/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Persistence and degradability Not readily biodegradable in water. No (test)data on mobility of the substance available. Reacts with air. Biochemical oxygen demand (BOD) 0.03 g O?? ?/g substance Chemical oxygen demand (COD) 0.026 g O?? ?/g substance (KMnO4) ThOD 2.60 g O?? ?/g substance BOD (% of ThOD) 0.012 05/10/2015 EN (English US) 12/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Toluene (108-88-3) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Low potential for adsorption in soil. Biochemical oxygen demand (BOD) 2.15 g O?? ?/g substance Chemical oxygen demand (COD) 2.52 g O?? ?/g substance ThOD 3.13 g O?? ?/g substance BOD (% of ThOD) 0.69 n-Heptane (142-82-5) Persistence and degradability Readily biodegradable in water. Forming sediments in water. Biodegradable in the soil. Low potential for adsorption in soil. Photolysis in the air. Biochemical oxygen demand (BOD) 1.92 g O?? ?/g substance Chemical oxygen demand (COD) 0.06 g O?? ?/g substance ThOD 3.52 g O?? ?/g substance BOD (% of ThOD) > 0.5 (5 days; Literature study) Heptane, Branched Cyclic (426260-76-6) Persistence and degradability May cause long-term adverse effects in the environment. Petroleum Gases, Liquefied, Sweetened (68476-86-8) Persistence and degradability Not established. Carbon Dioxide, Liquefied, Under Pressure (124-38-9) Persistence and degradability Biodegradability: not applicable. Not applicable (gas). Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable 12.3. Bioaccumulative potential JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Bioaccumulative potential Not established. Diethyl Ether (60-29-7) BCF fish 1 0.9 - 9.1 (BCF) Log Pow 0.82 - 0.89 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Toluene (108-88-3) BCF fish 2 90 (BCF; 72 h; Leuciscus idus; Static system; Fresh water) Log Pow 2.73 (Experimental value; Other; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). n-Heptane (142-82-5) BCF other aquatic organisms 1 552 (BCF; BCFBAF v3.00) Log Pow 4.66 (Experimental value; 4.5; Literature study) Bioaccumulative potential Potential for bioaccumulation (4 ? Log Kow ? 5). Heptane, Branched Cyclic (426260-76-6) Bioaccumulative potential Not established. Petroleum Gases, Liquefied, Sweetened (68476-86-8) Bioaccumulative potential Not established. Carbon Dioxide, Liquefied, Under Pressure (124-38-9) Log Pow 0.83 (Experimental value) Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil Diethyl Ether (60-29-7) Surface tension 0.017 N/m (20 ?C) Toluene (108-88-3) Surface tension 0.03 N/m (20 ?C) n-Heptane (142-82-5) Surface tension 0.019 N/m (25 ?C; 0.020 N/m; 20 ?C) Log Koc log Koc,SRC PCKOCWIN v2.0; 2.38; Calculated value 12.5. Other adverse effects Other information : Avoid release to the environment. 05/10/2015 EN (English US) 13/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information : Flammable vapors may accumulate in the container. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1950, Aerosols, 2.1, Limited Quantity ICAO/IATA (air): UN1950, Aerosols, 2.1 , Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.1 (Marine Pollutant-Heptane), Limited Quantity Special Provisions: N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols. 14.2. UN proper shipping name Proper Shipping Name (DOT) : Aerosols flammable, n.o.s. (engine starting fluid) (each not exceeding 1 L capacity) Transport hazard class(es) (DOT) : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 Hazard labels (DOT) : 2.1 - Flammable gas DOT Special Provisions (49 CFR 172.102) : N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : 304 DOT Packaging Bulk (49 CFR 173.xxx) : None 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 48 - Stow ??away from?? sources of heat,87 - Stow ??separated from?? Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials Subsidiary risks (IMDG) : Marine Pollutant-Heptane Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : Forbidden : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations 05/10/2015 EN (English US) 14/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations JOHNSEN'S 50% STARTING FLUID 7.2 ?OZ. SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Sudden release of pressure hazard Diethyl Ether (60-29-7) SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard 05/10/2015 EN (English US) 15/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Toluene (108-88-3) Subject to reporting requirements of United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Heptane, Branched Cyclic (426260-76-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard Distillates (Petroleum), Hydrotreated Heavy ?Naphthenic ?(64742-52-5) SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Petroleum Gases, Liquefied, Sweetened (68476-86-8) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard Sudden release of pressure hazard Carbon Dioxide, Liquefied, Under Pressure (124-38-9) SARA Section 311/312 Hazard Classes Sudden release of pressure hazard Immediate (acute) health hazard 15.2. International regulations CANADA JOHNSEN'S 50% STARTING FLUID 7.2 ?OZ. WHMIS Classification Class B Division 5 - Flammable Aerosol Toluene (108-88-3) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Heptane, Branched Cyclic (426260-76-6) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations Toluene (108-88-3) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Heptane, Branched Cyclic (426260-76-6) Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.1; R45 Muta.Cat.2; R46 F+; R12 Xn; R22 Xi; R38 R19 Full text of R-phrases: see section 16 15.2.2. National regulations Heptane, Branched Cyclic (426260-76-6) All components are either listed on the US TSCA Inventory, or are not regulated under TSCA under 40 CFR 720.30. 15.3. US State regulations JOHNSEN'S 50% STARTING FLUID 7.2 ?OZ. U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive No 05/10/2015 EN (English US) 16/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Toxicity - Female U.S. - California - Proposition 65 - Reproductive No 05/10/2015 EN (English US) 17/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations JOHNSEN'S 50% STARTING FLUID 7.2 ?OZ. Toxicity - Male State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Diethyl Ether (60-29-7) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Toluene (108-88-3) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No Yes Yes No n-Heptane (142-82-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Heptane, Branched Cyclic (426260-76-6) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Distillates (Petroleum), Hydrotreated Heavy ?Naphthenic ?(64742-52-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Petroleum Gases, Liquefied, Sweetened (68476-86-8) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Carbon Dioxide, Liquefied, Under Pressure (124-38-9) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Diethyl Ether (60-29-7) State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Toluene (108-88-3) State or local regulations U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) U.S. - New Jersey - Special Health Hazards Substances List New Jersey Right-to-Know U.S. - Massachusetts - Right To Know List Rhode Island Right to Know U.S. - Michigan - Critical Materials List U.S. - New Jersey - Environmental Hazardous Substances List U.S. - Illinois - Toxic Air Contaminants U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List 05/10/2015 EN (English US) 18/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Petroleum Gases, Liquefied, Sweetened (68476-86-8) State or local regulations New Jersey Right-to-Know Minnesota Right-to-Know Rhode Island Right to Know U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Massachusetts - Right To Know List SECTION 16: Other information Other information : None. Full text of H-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3 Asp. Tox. 1 Aspiration hazard Category 1 Compressed gas Gases under pressure Compressed gas Flam. Aerosol 1 Flammable aerosol Category 1 Flam. Gas 1 Flammable gases Category 1 Flam. Liq. 1 Flammable liquids Category 1 Flam. Liq. 2 Flammable liquids Category 2 Repr. 2 Reproductive toxicity Category 2 Skin Irrit. 2 Skin corrosion/irritation Category 2 STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H220 Extremely flammable gas H222 Extremely flammable aerosol H224 Extremely flammable liquid and vapor H225 Highly flammable liquid and vapor H280 Contains gas under pressure; may explode if heated H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H336 May cause drowsiness or dizziness H361 Suspected of damaging fertility or the unborn child H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given.NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating 05/10/2015 EN (English US) 19/11 JOHNSEN'S 50% STARTING FLUID 7.2 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 4 Severe Hazard Physical : 1 Slight Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Comm ission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. 05/10/2015 EN (English US) 20/11