INFO Document is encrypted Page 1/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 38.0 1 Identification of the substance/mixture and of the company/undertaking ? 1.1 Product identifier ? Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit ? 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. ? 1.3 Details of the supplier of the Safety Data Sheet ? Manufacturer/Supplier: CRP Industries 35 Commerce Dr. Cranbury, NJ 08512 (609) 578-4100 ? 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazards identification ? 2.1 Classification of the substance or mixture ? Classification according to Regulation (EC) No 1272/2008 The product is not classified according to the CLP regulation. ? Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. ? Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. ? Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company. ? 2.2 Label elements ? Labelling according to Regulation (EC) No 1272/2008 Not Regulated ? Hazard pictograms Not Regulated ? Signal word Not Regulated ? Hazard statements Not Regulated ? Additional information: Contains bisphenol A. May produce an allergic reaction. Safety data sheet available on request. ? Hazard description: ? WHMIS-symbols: Not hazardous under WHMIS. ? NFPA ratings (scale 0 - 4) 0 1 0 Health = 0 Fire = 1 Reactivity = 0 (Contd. on page 2) Page 2/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 1) 38.0 ? HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 0 1 0 Health = 0 Fire = 1 Reactivity = 0 ? HMIS Long Term Health Hazard Substances None of the ingredients is listed. ? 2.3 Other hazards ? Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. 3 Composition/information on ingredients ? 3.2 Mixtures ? Description: Mixture of substances listed below with nonhazardous additions. ? Dangerous components: CAS: 143-22-6 EINECS: 205-592-6 Index number: 603-183-00-0 2-[2-(2-butoxyethoxy)ethoxy]ethanol Xi R41 Eye Dam. 1, H318 < 10% CAS: 9004-77-7 NLP: 500-012-0 Poly(oxy-1,2-ethanediyl), ?-butyl-?-hydroxy- Xi R38-41 Eye Dam. 1, H318 Skin Irrit. 2, H315 < 10% CAS: 111-46-6 EINECS: 203-872-2 Index number: 603-140-00-6 2,2'-oxybisethanol Xn R22 Acute Tox. 4, H302 < 10% CAS: 110-97-4 EINECS: 203-820-9 Index number: 603-083-00-7 1,1'-iminodipropan-2-ol Xi R36 Eye Irrit. 2, H319 < 2,5% ? Additional information: For the wording of the listed risk phrases refer to section 16. 4 First aid measures ? 4.1 Description of first aid measures ? General information: No special measures required. ? After inhalation: Supply fresh air; consult doctor in case of complaints. ? After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. ? After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. (Contd. on page 3) Page 3/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 2) 38.0 ? After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. ? 4.2 Most important symptoms and effects, both acute and delayed Gastric or intestinal disorders. Slight irritant effect on skin and mucous membranes. Slight irritant effect on eyes. ? Hazards No further relevant information available. ? 4.3 Indication of any immediate medical attention and special treatment needed Contains bisphenol A. May produce an allergic reaction. Treat skin and mucous membrane with antihistamine and corticoid preparations. 5 Firefighting measures ? 5.1 Extinguishing media ? Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. ? For safety reasons unsuitable extinguishing agents: None. ? 5.2 Special hazards arising from the substance or mixture No further relevant information available. ? 5.3 Advice for firefighters ? Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. ? Additional information No further relevant information available. 6 Accidental release measures ? 6.1 Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. Particular danger of slipping on leaked/spilled product. ? 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. ? 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. ? 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage ? 7.1 Precautions for safe handling Prevent formation of aerosols. Use only in well ventilated areas. (Contd. on page 4) Page 4/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 3) 38.0 ? Information about fire - and explosion protection: No special measures required. ? 7.2 Conditions for safe storage, including any incompatibilities ? Storage: ? Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. Protect from humidity and water. ? Information about storage in one common storage facility: Store away from foodstuffs. Do not store together with oxidizing and acidic materials. ? Further information about storage conditions: Keep container tightly sealed. Protect from humidity and water. This product is hygroscopic. ? 7.3 Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection ? Additional information about design of technical facilities: No further data; see item 7. ? 8.1 Control parameters ? Ingredients with limit values that require monitoring at the workplace: 111-46-6 2,2'-oxybisethanol WEEL (USA) Long-term value: 10 mg/m? ? DNELs No further relevant information available. ? PNECs No further relevant information available. ? Additional information: The lists valid during the making were used as basis. ? 8.2 Exposure controls ? Personal protective equipment: ? General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. ? Respiratory protection: Not required under normal conditions of use. For spills, respiratory protection may be advisable. Use suitable respiratory protective device when aerosol or mist is formed. NIOSH or EN approved organic vapor respirator equipped with a dust/mist prefilter should be used. ? Protection of hands: Protective gloves (Contd. on page 5) Page 5/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 4) 38.0 The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. ? Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. ? Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. ? Eye protection: Safety glasses ? Body protection: Protective work clothing ? Limitation and supervision of exposure into the environment No further relevant information available. ? Risk management measures See Section 7 for additional information. No further relevant information available. 9 Physical and chemical properties ? 9.1 Information on basic physical and chemical properties ? General Information ? Appearance: Form: Fluid Colour: Yellow ? Odour: Characteristic ? Odour threshold: Not determined. ? pH-value at 20 ?C: 8,0 ? Change in condition Melting point/Melting range: > -68 ?F / >-50 ?C Boiling point/Boiling range: 509 ?F / 265 ?C ? Flash point: 266 ?F / 130 ?C ? Flammability (solid, gaseous): Not applicable. ? Ignition temperature: >392 ?F / >200 ?C ? Decomposition temperature: Not determined. ? Self-igniting: Product is not self-igniting. ? Danger of explosion: Product does not present an explosion hazard. (Contd. on page 6) Page 6/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 5) 38.0 ? Explosion limits: Lower: 0,7 Vol % Upper: 22 Vol % ? Vapour pressure: Not determined. ? Density at 20 ?C: 1,065 g/cm? ? Relative density Not determined. ? Vapour density Not determined. ? Evaporation rate Not determined. ? Solubility in / Miscibility with water: Fully miscible. ? Partition coefficient (n-octanol/water): Not determined. ? Viscosity: Dynamic: Not determined. Kinematic at 20 ?C: 14,5 mm?/s ? Solvent content: VOC (EC) 3,0 ? 9.2 Other information No further relevant information available. 10 Stability and reactivity ? 10.1 Reactivity ? 10.2 Chemical stability ? Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ? 10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents. ? 10.4 Conditions to avoid No further relevant information available. ? 10.5 Incompatible materials: No further relevant information available. ? 10.6 Hazardous decomposition products: Possible in traces. 11 Toxicological information ? 11.1 Information on toxicological effects ? Acute toxicity: ? Primary irritant effect: ? on the skin: Slight irritant effect on skin and mucous membranes. ? on the eye: Irritating effect. ? Sensitization: No sensitizing effects known. ? Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: (Contd. on page 7) Page 7/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 6) 38.0 Irritant 12 Ecological information ? 12.1 Toxicity ? Aquatic toxicity: The product contains materials that are harmful to the environment. ? 12.2 Persistence and degradability Easily biodegradable ? 12.3 Bioaccumulative potential No further relevant information available. ? 12.4 Mobility in soil No further relevant information available. ? Additional ecological information: ? General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Avoid transfer into the environment. Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water ? 12.5 Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. ? 12.6 Other adverse effects No further relevant information available. 13 Disposal considerations ? 13.1 Waste treatment methods ? Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Contact waste processors for recycling information. ? Uncleaned packaging: ? Recommendation: Disposal must be made according to official regulations. ? Recommended cleansing agents: Water, if necessary together with cleansing agents. 14 Transport information ? 14.1 UN-Number ? DOT, ADR, ADN, IMDG, IATA Not Regulated ? 14.2 UN proper shipping name ? DOT, ADR, ADN, IMDG, IATA Not Regulated ? 14.3 Transport hazard class(es) ? DOT, ADR, ADN, IMDG, IATA ? Class Not Regulated ? 14.4 Packing group ? DOT, ADR, IMDG, IATA Not Regulated (Contd. on page 8) Page 8/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 7) 38.0 ? 14.5 Environmental hazards: ? Marine pollutant: No ? 14.6 Special precautions for user Not applicable. ? 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. ? UN "Model Regulation": - 15 Regulatory information ? 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture ? United States (USA) ? SARA ? Section 355 (extremely hazardous substances): None of the ingredients is listed. ? Section 313 (Specific toxic chemical listings): None of the ingredients is listed. ? TSCA (Toxic Substances Control Act): All ingredients are listed. ? Proposition 65 (California): ? Chemicals known to cause cancer: None of the ingredients is listed. ? Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ? Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ? Chemicals known to cause developmental toxicity: None of the ingredients is listed. ? Carcinogenic Categories ? EPA (Environmental Protection Agency) None of the ingredients is listed. ? IARC (International Agency for Research on Cancer) None of the ingredients is listed. ? TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. ? NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. (Contd. on page 9) Page 9/9 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and GHS Printing date 16.01.2014 Revision: 16.01.2014 Trade name: Pentosin Super DOT 4 Bremsfl?ssigkeit (Contd. of page 8) 38.0 ? OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. ? Canada ? Canadian Domestic Substances List (DSL) 110-97-4 1,1'-iminodipropan-2-ol ? Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. ? Canadian Ingredient Disclosure list (limit 1%) 110-97-4 1,1'-iminodipropan-2-ol ? 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ? Relevant phrases H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. R22 Harmful if swallowed. R36 Irritating to eyes. R38 Irritating to skin. R41 Risk of serious damage to eyes. ? Abbreviations and acronyms: ADR: Accord europ?en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) GHS: Globally Harmonized System of Classification and Labelling of Chemicals DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) ? Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com