INFO Document is encrypted Page 1 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 38.0 1 Identification ? Product identifier ? Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit ? Details of the supplier of the Safety Data Sheet ? Manufacturer/Supplier: CRP Industries 35 Commerce Dr. Cranbury, NJ 08512 (609) 578-4100 ? Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification ? Classification of the substance or mixture GHS07 Eye Irrit. 2A H319 Causes serious eye irritation. ? Label elements ? GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ? Hazard pictograms GHS07 ? Signal word Warning ? Hazard statements H319 Causes serious eye irritation. ? Precautionary statements P280 Wear protective gloves / eye protection. P264 Wash thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. ? Hazard description: ? WHMIS-symbols: D2B - Toxic material causing other toxic effects (Contd. on page 2) Page 2 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 1) 38.0 ? Classification system: ? NFPA ratings (scale 0 - 4) 1 1 0 Health = 1 Fire = 1 Reactivity = 0 ? HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 1 1 0 Health = 1 Fire = 1 Reactivity = 0 ? Other hazards ? Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. 3 Composition/information on ingredients ? Chemical characterization: Mixtures ? Description: Mixture of the substances listed below with nonhazardous additions. ? Dangerous components: Butyl Triglycolether Mixture Eye Dam. 1, H318 < 5.0% 110-97-4 1,1'-iminodipropan-2-ol Eye Irrit. 2A, H319 < 5.0% 4 First-aid measures ? Description of first aid measures ? General information: No special measures required. ? After inhalation: Supply fresh air; consult doctor in case of complaints. ? After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. ? After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ? After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. ? Most important symptoms and effects, both acute and delayed Irritant to eyes. Gastric or intestinal disorders Slight irritant effect on skin and mucous membranes. ? Danger No further relevant information available. (Contd. on page 3) Page 3 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 2) 38.0 ? Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures ? Extinguishing media ? Suitable extinguishing agents: Use fire fighting measures that suit the environment. ? For safety reasons unsuitable extinguishing agents: None. ? Special hazards arising from the substance or mixture No further relevant information available. ? Advice for firefighters ? Protective equipment: Wear self-contained respiatory protective device. Wear fully protective suit. ? Additional information No further relevant information available. 6 Accidental release measures ? Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Ensure adequate ventilation. Wear protective equipment. Keep unprotected persons away. Particular danger of slipping on leaked/spilled product. ? Environmental precautions: Do not allow to enter sewers/ surface or ground water. ? Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. ? Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage ? Precautions for safe handling Prevent formation of aerosols. Use only in well ventilated areas. ? Information about protection against explosions and fires: No special measures required. ? Conditions for safe storage, including any incompatibilities ? Storage: ? Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. Protect from humidity and water. ? Information about storage in one common storage facility: Store away from foodstuffs. Do not store together with oxidizing and acidic materials. (Contd. on page 4) Page 4 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 3) 38.0 ? Further information about storage conditions: Keep receptacle tightly sealed. Protect from humidity and water. This product is hygroscopic. ? Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection ? Additional information about design of technical systems: No further data; see item 7. ? Control parameters ? Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. ? Additional information: The lists that were valid during the creation were used as basis. ? Exposure controls ? Personal protective equipment: ? General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. ? Breathing equipment: Not required under normal conditions of use. For spills, respiratory protection may be advisable. Use suitable respiratory protective device when aerosol or mist is formed. NIOSH or EN approved organic vapor respirator equipped with a dust/mist prefilter should be used. ? Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation ? Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. ? Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 5) Page 5 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 4) 38.0 ? Eye protection: Safety glasses ? Body protection: Protective work clothing ? Limitation and supervision of exposure into the environment No further relevant information available. 9 Physical and chemical properties ? Information on basic physical and chemical properties ? General Information ? Appearance: Form: Fluid Color: Amber colored ? Odor: Characteristic ? Odor threshold: Not determined. ? pH-value: Slightly alkaline ? Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: >509 ?F / >265 ?C (>948 ?F / >509 ?F) ? Flash point: 271 ?F / 136 ?C (520 ?F / 277 ?F) ? Flammability (solid, gaseous): Not applicable. ? Ignition temperature: Not determined. ? Decomposition temperature: Not determined. ? Auto igniting: Product is not self-igniting. ? Danger of explosion: Product does not present an explosion hazard. ? Explosion limits: Lower: Not determined. Upper: Not determined. ? Vapor pressure: Not determined. ? Density at 20 ?C (68 ?F): 1.06 g/cm? (8.846 lbs/gal) ? Relative density Not determined. ? Vapour density Not determined. ? Evaporation rate Not determined. ? Solubility in / Miscibility with Water: Fully miscible. ? Partition coefficient (n-octanol/water): Not determined. (Contd. on page 6) Page 6 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 5) 38.0 ? Viscosity: Dynamic: Not determined. Kinematic at 20 ?C (68 ?F): 12 mm?/s ? Other information No further relevant information available. 10 Stability and reactivity ? Reactivity ? Chemical stability ? Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ? Possibility of hazardous reactions Reacts with strong acids and oxidizing agents. ? Conditions to avoid No further relevant information available. ? Incompatible materials: No further relevant information available. ? Hazardous decomposition products: Possible in traces. 11 Toxicological information ? Information on toxicological effects ? Acute toxicity: ? Primary irritant effect: ? on the skin: Slight irritant effect on skin and mucous membranes. ? on the eye: Irritating effect. ? Sensitization: No sensitizing effects known. ? Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant ? Carcinogenic categories ? NTP (National Toxicology Program) None of the ingredients is listed. 12 Ecological information ? Toxicity ? Aquatic toxicity: The product contains materials that are harmful to the environment. ? Persistence and degradability The product is partially biodegradable. Significant residuals remain. ? Bioaccumulative potential No further relevant information available. ? Mobility in soil No further relevant information available. ? Additional ecological information: ? General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 7) Page 7 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 6) 38.0 Avoid transfer into the environment. ? Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. ? Other adverse effects No further relevant information available. 13 Disposal considerations ? Waste treatment methods ? Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Contact waste processors for recycling information. ? Uncleaned packagings: ? Recommendation: Disposal must be made according to official regulations. ? Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information ? UN-Number ? DOT, ADR, ADN, IMDG, IATA Not Regulated ? UN proper shipping name ? DOT, ADR, ADN, IMDG, IATA Not Regulated ? Transport hazard class(es) ? DOT, ADR, ADN, IMDG, IATA ? Class Not Regulated ? Packing group ? DOT, ADR, IMDG, IATA Not Regulated ? Environmental hazards: ? Marine pollutant: No ? Special precautions for user Not applicable. ? Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. ? UN "Model Regulation": - 15 Regulatory information ? Safety, health and environmental regulations/legislation specific for the substance or mixture ? SARA ? Section 355 (extremely hazardous substances): None of the ingredients is listed. (Contd. on page 8) Page 8 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 7) 38.0 ? Section 313 (Specific toxic chemical listings): None of the ingredients is listed. ? TSCA (Toxic Substances Control Act): All ingredients are listed. ? Proposition 65 (California) ? Chemicals known to cause cancer: None of the ingredients is listed. ? Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ? Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ? Chemicals known to cause developmental toxicity: None of the ingredients is listed. ? Carcinogenic categories ? EPA (Environmental Protection Agency) None of the ingredients is listed. ? IARC (International Agency for Research on Cancer) None of the ingredients is listed. ? TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. ? NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. ? OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. ? State Right to Know Listings None of the ingredients is listed. ? Canada ? Canadian substance listings: ? Canadian Domestic Substances List (DSL) 110-97-4 1,1'-iminodipropan-2-ol ? Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. ? Canadian Ingredient Disclosure list (limit 1%) 110-97-4 1,1'-iminodipropan-2-ol ? Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. (Contd. on page 9) Page 9 of 9 Safety Data Sheet acc. to HCS and GHS Printing date 01/13/2014 Reviewed on 01/13/2014 Trade name: Pentosin DOT 4 LV Bremsfl?ssigkeit (Contd. of page 8) 38.0 ? Date of preparation / last revision 01/13/2014 / - ? Abbreviations and acronyms: ADR: Accord europ?en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) ? Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com