Page: 1/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 43.0 1 Identification ? Product identifier ? Trade name: Pentosin MTF 2 75W-80 ? Product code: No other identifiers ? Recommended use and restriction on use ? Recommended use: Lubricating oil ? Restrictions on use: No relevant information available. ?Details of the supplier of the Safety Data Sheet ?Manufacturer/Supplier: CRP Industries 35 Commerce Dr. Cranbury, NJ 08512 (609) 578-4100 This email address is being protected from spambots. You need JavaScript enabled to view it. ? Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification ?Classification of the substance or mixture Skin Sens. 1 H317 May cause an allergic skin reaction. ? Label elements ?GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). ? Hazard pictograms: GHS07 ? Signal word: Warning ? Hazard statements: H317 May cause an allergic skin reaction. ? Precautionary statements: P261 Avoid breathing mist, vapors, or spray. P280 Wear protective gloves and eye protection. P272 Contaminated work clothing must not be allowed out of the workplace. P302+P352 IF ON SKIN: Wash with plenty of water. P363 Wash contaminated clothing before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ?Other hazards There are no other hazards not otherwise classified that have been identified. (Cont'd. on page 2) Page: 2/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 1) 43.0 3 Composition/information on ingredients ?Chemical characterization: Substances ? CAS No. Description Lubricating Oil (non-aromatic) (C20-C50) ? Components: 67124-09-8 1-(tert-dodecylthio)-2-propanol Skin Sens. 1, H317 <1% 101-02-0 triphenyl phosphite Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 <1% 4 First-aid measures ?Description of first aid measures ? After inhalation: Supply fresh air; consult doctor in case of complaints. ? After skin contact: Immediately remove any clothing soiled by the product. Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. ? After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ? After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. ?Most important symptoms and effects, both acute and delayed: Cramp Acne Allergic reactions Gastric or intestinal disorders when ingested. Nausea in case of ingestion. ? Indication of any immediate medical attention and special treatment needed: Contains 1-(tert-dodecylthio)-2-propanol. May produce an allergic reaction. Treat skin and mucous membrane with antihistamine and corticoid preparations. 5 Fire-fighting measures ? Extinguishing media ? Suitable extinguishing agents: Foam Fire-extinguishing powder Gaseous extinguishing agents Carbon dioxide ? For safety reasons unsuitable extinguishing agents: Water ? Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. (Cont'd. on page 3) Page: 3/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 2) 43.0 ?Advice for firefighters ? Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. 6 Accidental release measures ? Personal precautions, protective equipment and emergency procedures: Ensure adequate ventilation. Wear protective equipment. Keep unprotected persons away. Particular danger of slipping on leaked/spilled product. For large spills, use respiratory protective device against the effects of fumes/dust/aerosol. ? Environmental precautions: Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. Prevent from spreading (e.g. by damming-in or oil barriers). ?Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Remove from the water surface (e.g. skim or suck off). Send for recovery or disposal in suitable receptacles. ?Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage ?Handling ? Precautions for safe handling: Prevent formation of aerosols. Use only in well ventilated areas. ? Information about protection against explosions and fires: No special measures required. ?Conditions for safe storage, including any incompatibilities ? Storage ? Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. ? Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. ? Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Keep containers tightly sealed. ? Specific end use(s): No relevant information available. (Cont'd. on page 4) Page: 4/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 3) 43.0 8 Exposure controls/personal protection ?Control parameters ? Components with limit values that require monitoring at the workplace: Not required. ? Exposure controls ? Personal protective equipment: ?General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. ? Engineering controls: No relevant information available. ? Breathing equipment: Not required under normal conditions of use. Use suitable respiratory protective device when aerosol or mist is formed. For spills, respiratory protection may be advisable. ? Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. ? Eye protection: Safety glasses ? Body protection: Protective work clothing ? Limitation and supervision of exposure into the environment No relevant information available. ?Risk management measures No relevant information available. 9 Physical and chemical properties ? Information on basic physical and chemical properties ? Appearance: Form: Fluid Color: According to product specification ?Odor: Characteristic ?Odor threshold: Not determined. ? pH-value: Not determined. ?Melting point/Melting range: <-60 ?C (<-76 ?F) ? Boiling point/Boiling range: >200 ?C (>392 ?F) (Cont'd. on page 5) Page: 5/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 4) 43.0 ? Flash point: 228 ?C (442 ?F) ? Flammability (solid, gaseous): Not applicable. ? Auto-ignition temperature: 330 ?C (626 ?F) ? Decomposition temperature: Not determined. ? Danger of explosion: Product does not present an explosion hazard. ? Explosion limits Lower: 1.8 Vol % Upper: 2.4 Vol % ? Vapor pressure at 20 ?C (68 ?F): 0.1 hPa ? Density at 20 ?C (68 ?F): 0.85 g/cm? (7.093 lbs/gal) ? Relative density: Not determined. ? Vapor density: Not determined. ? Evaporation rate: Not determined. ? Solubility in / Miscibility with Water: Not miscible or difficult to mix. ? Partition coefficient (n-octanol/water): Not determined. ? Viscosity Dynamic: Not determined. Kinematic at 20 ?C (68 ?F): 88 mm?/s (ISO 3104) ?Other information No relevant information available. 10 Stability and reactivity ?Reactivity: No relevant information available. ? Chemical stability: Stable under normal temperatures and pressures. ? Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ? Possibility of hazardous reactions: Toxic fumes may be released if heated above the decomposition point. Reacts with strong acids and oxidizing agents. ?Conditions to avoid: Excessive heat. ? Incompatible materials: Oxidizers ?Hazardous decomposition products: Carbon monoxide and carbon dioxide Hydrocarbons (Cont'd. on page 6) Page: 6/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 5) 43.0 11 Toxicological information ? Information on toxicological effects ? Acute toxicity: ? LD/LC50 values that are relevant for classification: None. ? Primary irritant effect: ?On the skin: No irritant effect. Slight irritant effect on skin and mucous membranes. ?On the eye: Slight irritant effect on eyes. ? Sensitization: Sensitizing effect by skin contact is possible with prolonged exposure. ? IARC (International Agency for Research on Cancer): Substance is not listed. ? NTP (National Toxicology Program): Substance is not listed. ?OSHA-Ca (Occupational Safety & Health Administration): Substance is not listed. ? Probable route(s) of exposure: Ingestion. Inhalation. Eye contact. Skin contact. ? CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) ? Carcinogenicity: Based on available data, the classification criteria are not met. ? Reproductive toxicity: Based on available data, the classification criteria are not met. ? STOT-single exposure: Based on available data, the classification criteria are not met. ? STOT-repeated exposure: Based on available data, the classification criteria are not met. ? Aspiration hazard: Based on available data, the classification criteria are not met. 12 Ecological information ? Toxicity ? Aquatic toxicity Harmful to aquatic life with long lasting effects. ? Persistence and degradability No relevant information available. ? Bioaccumulative potential: No relevant information available. ?Mobility in soil: No relevant information available. ? Ecotoxical effects: ? Remark: Harmful to fish Due to mechanical actions of the product (e.g. agglutinations), damages may occur. ?Additional ecological information ?General notes: Do not allow product to reach ground water, water course or sewage system. ?Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. (Cont'd. on page 7) Page: 7/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 6) 43.0 ?Other adverse effects: No relevant information available. 13 Disposal considerations ?Waste treatment methods ? Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Product is recyclable as a waste oil. Deliver unused and/or contaminated product to waste oil collectors. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. ?Uncleaned packagings ? Recommendation: Disposal must be made according to official regulations. 14 Transport information ?UN-Number ? DOT, ADR, IMDG, IATA Not regulated. ?UN proper shipping name ? DOT, ADR, IMDG, IATA Not regulated. ? Transport hazard class(es) ? DOT, ADR, IMDG, IATA ? Class Not regulated. ? Packing group ? DOT, ADR, IMDG, IATA Not regulated. ? Environmental hazards ?Marine pollutant: No ? Special precautions for user Not applicable. ? Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 15 Regulatory information ? Safety, health and environmental regulations/legislation specific for the substance or mixture ? United States (USA) ? SARA ? Section 302 (extremely hazardous substances): Substance is not listed. (Cont'd. on page 8) Page: 8/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 7) 43.0 ? Section 355 (extremely hazardous substances): Substance is not listed. ? Section 313 (Specific toxic chemical listings): Substance is not listed. ? TSCA (Toxic Substances Control Act) Substance is listed. ? Proposition 65 (California) ? Chemicals known to cause cancer: Substance is not listed. ? Chemicals known to cause reproductive toxicity for females: Substance is not listed. ? Chemicals known to cause reproductive toxicity for males: Substance is not listed. ? Chemicals known to cause developmental toxicity: Substance is not listed. ? Carcinogenic categories ? EPA (Environmental Protection Agency): Substance is not listed. ? IARC (International Agency for Research on Cancer): Substance is not listed. ? NIOSH-Ca (National Institute for Occupational Safety and Health): Substance is not listed. ? Canadian Domestic Substances List (DSL): Substance is listed. ?Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ? Date of preparation / last revision 06/28/2016 / - ? Abbreviations and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern (Cont'd. on page 9) Page: 9/9 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentosin MTF 2 75W-80 (Cont'd. of page 8) 43.0 vPvB: very Persistent and very Bioaccumulative LDLo: Lowest Lethal Dose Observed Acute Tox. 4: Acute toxicity ? Category 4 Skin Irrit. 2: Skin corrosion/irritation ? Category 2 Eye Irrit. 2: Serious eye damage/eye irritation ? Category 2 Skin Sens. 1: Skin sensitisation ? Category 1 ? Sources Website, European Chemicals Agency (echa.europa.eu) Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/ overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org) Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: ISBN: 978-0-470-07488-6 Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: 978-0-07-176923-5. Safety Data Sheets, Individual Manufacturers SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com