Page: 1/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 43.0 1 Identification ? Product identifier ? Trade name: Pentofrost A1 ? Product code: No other identifiers ? Recommended use and restriction on use ? Recommended use: Coolant / Anti-freeze. ? Restrictions on use: No relevant information available. ?Details of the supplier of the Safety Data Sheet ?Manufacturer/Supplier: CRP Industries 35 Commerce Dr. Cranbury, NJ 08512 (609) 578-4100 This email address is being protected from spambots. You need JavaScript enabled to view it. ? Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification ?Classification of the substance or mixture Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. STOT RE 2 H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. ? Label elements ?GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ? Hazard pictograms: GHS07 GHS08 ? Signal word: Warning ? Hazard statements: H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. ? Precautionary statements: P260 Do not breathe mist/vapors/spray. P264 Wash thoroughly after handling. P280 Wear protective gloves and eye protection. (Cont'd. on page 2) Page: 2/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 1) 43.0 P270 Do not eat, drink or smoke when using this product. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 IF ON SKIN: Wash with plenty of water. P314 Get medical advice/attention if you feel unwell. P330 Rinse mouth. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ?Other hazards There are no other hazards not otherwise classified that have been identified. 3 Composition/information on ingredients ? Chemical characterization: Mixtures ? Components: 107-21-1 ethylene glycol STOT RE 2, H373Acute Tox. 4, H302 >80% 111-46-6 2,2'-oxybisethanol STOT RE 2, H373Acute Tox. 4, H302 <5% 1310-73-2 sodium hydroxide Met. Corr.1, H290; Skin Corr. 1A, H314; Eye Dam. 1, H318 <1% ? Additional information: For the listed ingredient(s), the identity and/or exact percentage(s) are being withheld as a trade secret. For the wording of the listed Hazard Statements refer to section 16. 4 First-aid measures ?Description of first aid measures ?General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. ? After inhalation: Supply fresh air; consult doctor in case of complaints. ? After skin contact: Immediately remove any clothing soiled by the product. Immediately rinse with water. If skin irritation continues, consult a doctor. ? After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ? After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. ?Most important symptoms and effects, both acute and delayed: Headache (Cont'd. on page 3) Page: 3/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 2) 43.0 Dizziness Coughing Acidosis Cramp Nausea Irritant to skin and mucous membranes. Irritant to eyes. Disorientation ? Danger: Harmful if swallowed. May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. ? Indication of any immediate medical attention and special treatment needed: Contains ethylene glycol. Consult literature for specific antidotes. If medical advice is needed, have product container or label at hand. 5 Fire-fighting measures ? Extinguishing media ? Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. ? For safety reasons unsuitable extinguishing agents: None. ? Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. ?Advice for firefighters ? Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. 6 Accidental release measures ? Personal precautions, protective equipment and emergency procedures: Ensure adequate ventilation. Wear protective equipment. Keep unprotected persons away. Particular danger of slipping on leaked/spilled product. ? Environmental precautions: Avoid release to the environment. ?Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. ?Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Cont'd. on page 4) Page: 4/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 3) 43.0 7 Handling and storage ?Handling ? Precautions for safe handling: Prevent formation of aerosols. Use only in well ventilated areas. ? Information about protection against explosions and fires: No special measures required. ?Conditions for safe storage, including any incompatibilities ? Storage ? Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. ? Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. ? Further information about storage conditions: Keep containers tightly sealed. ? Specific end use(s): No relevant information available. 8 Exposure controls/personal protection ?Control parameters ? Components with limit values that require monitoring at the workplace: 107-21-1 ethylene glycol TLV (USA) Short-term value: NIC-127* NIC-10** mg/m?, NIC-50* ppm Long-term value: NIC-63.5* mg/m?, NIC-25* ppm Ceiling limit value: (100) mg/m? (H); *inh. fraction + vapor,P:**inh. fraction, H EL (Canada) Short-term value: 20** mg/m? Long-term value: 10** mg/m? Ceiling limit value: 100* mg/m?, 50*** ppm *Aerosol; **Particulate; ***Vapour EV (Canada) Ceiling limit value: 100 mg/m? LMPE (Mexico) Ceiling limit value: 100* mg/m? A4, *solo aerosol 111-46-6 2,2'-oxybisethanol WEEL (USA) Long-term value: 10 mg/m? 1310-73-2 sodium hydroxide PEL (USA) Long-term value: 2 mg/m? REL (USA) Ceiling limit value: 2 mg/m? TLV (USA) Ceiling limit value: 2 mg/m? EL (Canada) Ceiling limit value: 2 mg/m? EV (Canada) Ceiling limit value: 2 mg/m? LMPE (Mexico) Ceiling limit value: 2 mg/m? (Cont'd. on page 5) Page: 5/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 4) 43.0 ? Exposure controls ? Personal protective equipment: ?General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Do not inhale gases / fumes / aerosols. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. ? Engineering controls: No relevant information available. ? Breathing equipment: Not required under normal conditions of use. Use suitable respiratory protective device in case of insufficient ventilation. Use suitable respiratory protective device when aerosol or mist is formed. ? Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. ? Eye protection: Safety glasses ? Body protection: Protective work clothing ? Limitation and supervision of exposure into the environment No relevant information available. ?Risk management measures No relevant information available. 9 Physical and chemical properties ? Information on basic physical and chemical properties ? Appearance: Form: Liquid Color: Red ?Odor: Light ?Odor threshold: Not determined. ? pH-value at 20 ?C (68 ?F): 7.9 (50% solution) ?Melting point/Melting range: Not determined. ? Boiling point/Boiling range: 175 ?C (347 ?F) ? Flash point: 128 ?C (262 ?F) ? Flammability (solid, gaseous): Not applicable. ? Auto-ignition temperature: >260 ?C (>500 ?F) (Cont'd. on page 6) Page: 6/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 5) 43.0 ? Decomposition temperature: Not determined. ? Danger of explosion: Product does not present an explosion hazard. ? Explosion limits Lower: Not determined. Upper: Not determined. ? Vapor pressure at 20 ?C (68 ?F): 0.1 hPa ? Density at 20 ?C (68 ?F): 1.13 g/cm? (9.43 lbs/gal) ? Relative density: Not determined. ? Vapor density: Not determined. ? Evaporation rate: Not determined. ? Solubility in / Miscibility with Water: Fully miscible. ? Partition coefficient (n-octanol/water): Not determined. ? Viscosity Dynamic: Not determined. Kinematic: Not determined. ?Other information No relevant information available. 10 Stability and reactivity ?Reactivity: No relevant information available. ? Chemical stability: Stable under normal temperatures and pressures. ? Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ? Possibility of hazardous reactions: Reacts with strong acids and oxidizing agents. Toxic fumes may be released if heated above the decomposition point. ?Conditions to avoid: Excessive heat. ? Incompatible materials: Oxidizers, strong bases, strong acids ?Hazardous decomposition products: Carbon monoxide and carbon dioxide 11 Toxicological information ? Information on toxicological effects ? Acute toxicity: ? LD/LC50 values that are relevant for classification: None. ? Primary irritant effect: ?On the skin: Irritant to skin and mucous membranes. ?On the eye: Irritating effect. ? Sensitization: No sensitizing effects known. (Cont'd. on page 7) Page: 7/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 6) 43.0 ? IARC (International Agency for Research on Cancer): None of the ingredients are listed. ? NTP (National Toxicology Program): None of the ingredients are listed. ?OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed. ? Probable route(s) of exposure: Ingestion. Inhalation. Eye contact. Skin contact. ? Acute effects (acute toxicity, irritation and corrosivity): Harmful if swallowed. Irritating to eyes and skin. ? Repeated dose toxicity: Possible risk of irreversible effects. ? CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) ?Germ cell mutagenicity: Based on available data, the classification criteria are not met. ? Carcinogenicity: Based on available data, the classification criteria are not met. ? Reproductive toxicity: Based on available data, the classification criteria are not met. ? STOT-single exposure: Based on available data, the classification criteria are not met. ? STOT-repeated exposure: May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. ? Aspiration hazard: Based on available data, the classification criteria are not met. 12 Ecological information ? Toxicity ? Aquatic toxicity No relevant information available. ? Persistence and degradability No relevant information available. ? Bioaccumulative potential: Does not accumulate in organisms ?Mobility in soil: No relevant information available. ?Additional ecological information ?General notes: Avoid release to the environment. ?Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. ?Other adverse effects: No relevant information available. 13 Disposal considerations ?Waste treatment methods ? Recommendation: Contact waste processors for recycling information. (Cont'd. on page 8) Page: 8/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 7) 43.0 The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. ?Uncleaned packagings ? Recommendation: Disposal must be made according to official regulations. ? Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information ?UN-Number ? DOT, ADR, IMDG, IATA Not regulated. ?UN proper shipping name ? DOT, ADR, IMDG, IATA Not regulated. ? Transport hazard class(es) ? DOT, ADR, IMDG, IATA ? Class Not regulated. ? Packing group ? DOT, ADR, IMDG, IATA Not regulated. ? Environmental hazards ?Marine pollutant: No ? Special precautions for user Not applicable. ? Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 15 Regulatory information ? Safety, health and environmental regulations/legislation specific for the substance or mixture ? United States (USA) ? SARA ? Section 302 (extremely hazardous substances): None of the ingredients are listed. ? Section 355 (extremely hazardous substances): None of the ingredients are listed. ? Section 313 (Specific toxic chemical listings): 107-21-1 ethylene glycol ? TSCA (Toxic Substances Control Act) All ingredients are listed. (Cont'd. on page 9) Page: 9/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 8) 43.0 ? Proposition 65 (California) ? Chemicals known to cause cancer: None of the ingredients are listed. ? Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. ? Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. ? Chemicals known to cause developmental toxicity: 107-21-1 ethylene glycol ? Carcinogenic categories ? EPA (Environmental Protection Agency): None of the ingredients are listed. ? IARC (International Agency for Research on Cancer): None of the ingredients are listed. ? NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients are listed. ? Canadian Domestic Substances List (DSL): All ingredients are listed. ?Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ? Date of preparation / last revision 06/28/2016 / - ? Abbreviations and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health Met. Corr.1: Corrosive to metals ? Category 1 Acute Tox. 4: Acute toxicity ? Category 4 Skin Corr. 1A: Skin corrosion/irritation ? Category 1A Skin Irrit. 2: Skin corrosion/irritation ? Category 2 Eye Dam. 1: Serious eye damage/eye irritation ? Category 1 Eye Irrit. 2A: Serious eye damage/eye irritation ? Category 2A (Cont'd. on page 10) Page: 10/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) and WHMIS 2015 regulations Printing date: 06/28/2016 Revision: 06/28/2016 Trade name: Pentofrost A1 (Cont'd. of page 9) 43.0 STOT RE 2: Specific target organ toxicity (repeated exposure) ? Category 2 ? Sources Website, European Chemicals Agency (echa.europa.eu) Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/ overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org) Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: ISBN: 978-0-470-07488-6 Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: 978-0-07-176923-5. Safety Data Sheets, Individual Manufacturers SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com